15 research outputs found

    A facile intramolecular tertiary amine displacement reaction

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    Structure of a novel neutral lead(II) complex with dipropyldithiocarbamate

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    The synthesis and X-ray structure of a novel tetramer of Pb(II) with the dipropyldithiocarbamato ligand is described. The compound crystallizes in the triclinic space group P ̅1with a=9.576(2), b= 14.151(4), c=16.175(4) Å , α =104.84(2), β = 102.26(2), γ =90.62(2)ۥ , V=2065(1) Å 3. Unit cell dimensions and data collection were done at 130(1) K using graphite-monochromated Mo Kα radiation. The conventional R factor is 0.030 for 5323 unique observed reflections with the goodness- of-fit parameter = 1.35. The structure consists of a sulfur-bridged neutral tetrameric species where each Pb(II) ion is pentacoordinated
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