15 research outputs found
A 1,1-dithiocarboxylate ligand with an easily derivatizable group. Synthesis and structure of tris[2-(ethylamino)cyclopent-1-ene-1-dithiocarboxylato]bismuth(III)
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Ruthenium(II) chloride complexes of the mesocyclic ligand 1,5-dithiacyclooctane 1-oxide. Preparation and structure of the "all-trans" complex
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Structure of a novel neutral lead(II) complex with dipropyldithiocarbamate
The synthesis and X-ray structure of a novel tetramer of Pb(II) with the dipropyldithiocarbamato ligand is described. The compound crystallizes in the triclinic space group P ̅1with a=9.576(2), b= 14.151(4), c=16.175(4) Å , α =104.84(2), β = 102.26(2), γ =90.62(2)ۥ , V=2065(1) Å 3. Unit cell dimensions and data collection were done at 130(1) K using graphite-monochromated Mo Kα radiation. The conventional R factor is 0.030 for 5323 unique observed reflections with the goodness- of-fit parameter = 1.35. The structure consists of a sulfur-bridged neutral tetrameric species where each Pb(II) ion is pentacoordinated
Neighboring group participation in organic redox reactions. 12. Effect of the transannular amide on thioether oxidation. Structure of the 6-oxo-1-thionia-5-azabicyclo[4.3.0]nonane cation
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