Hydrological Response of Alpine Wetlands to ClimateWarming in the Eastern Tibetan Plateau

Alpine wetlands in the Tibetan Plateau (TP) play a crucial role in the regional hydrological cycle due to their strong influence on surface ecohydrological processes; therefore, understanding how TP wetlands respond to climate change is essential for projecting their future condition and potential vulnerability. We investigated the hydrological responses of a large TP wetland complex to recent climate change, by combining multiple satellite observations and in-situ hydro-meteorological records. We found different responses of runoff production to regional warming trends among three basins with similar climate, topography and vegetation cover but different wetland proportions. The basin with larger wetland proportion (40.1%) had a lower mean runoff coefficient (0.173 ± 0.006), and also showed increasingly lower runoff level (−3.9% year−1, p = 0.002) than the two adjacent basins. The satellite-based observations showed an increasing trend of annual non-frozen period, especially in the wetland-dominated region (2.64 day·year−1, p \u3c 0.10), and a strong extension of vegetation growing-season (0.26–0.41 day·year−1, p \u3c 0.10). Relatively strong increasing trends in evapotranspiration (ET) (~1.00 mm·year−1, p \u3c 0.01) and the vertical temperature gradient above ground surface (0.043 °C·year−1, p \u3c 0.05) in wetland-dominant areas were documented from satellite-based ET observations and weather station records. These results indicate recent surface drying and runoff reduction of alpine wetlands, and their potential vulnerability to degradation with continued climate warming

Climatic Controls on Spring Onset of the Tibetan Plateau Grasslands from 1982 to 2008

Understanding environmental controls on vegetation spring onset (SO) in the Tibetan Plateau (TP) is crucial to diagnosing regional ecosystem responses to climate change. We investigated environmental controls on the SO of the TP grasslands using satellite vegetation index (VI) from the 3rd Global Inventory Modeling and Mapping Studies (GIMMS3g) product, with in situ air temperature (Ta) and precipitation (Prcp) measurement records from 1982 to 2008. The SO was determined using a dynamic threshold method based on a 25% threshold of seasonal VI amplitude. We find that SO shows overall close associations with spring Ta, but is also subject to regulation from spring precipitation. In relatively dry but increasingly wetting (0.50 mm·year−1, p \u3c 0.10) grasslands (mean spring Prcp = 22.8 mm; Ta = −3.27 °C), more precipitation tends to advance SO (−0.146 day·mm−1, p = 0.150) before the mid-1990s, but delays SO (0.110 day·mm−1, p = 0.108) over the latter record attributed to lower solar radiation and cooler temperatures associated with Prcp increases in recent years. In contrast, in relatively humid TP grasslands (73.0 mm; −3.51 °C), more precipitation delays SO (0.036 day·mm−1, p = 0.165) despite regional warming (0.045 °C·year−1, p \u3c 0.05); the SO also shows a delaying response to a standardized drought index (mean R = 0.266), indicating a low energy constraint to vegetation onset. Our results highlight the importance of surface moisture status in regulating the phenological response of alpine grasslands to climate warming

Interface design for high energy density polymer nanocomposites

This review provides a detailed overview on the latest developments in the design and control of the interface in polymer based composite dielectrics for energy storage applications. The methods employed for interface design in composite systems are described for a variety of filler types and morphologies, along with novel approaches employed to build hierarchical interfaces for multi-scale control of properties. Efforts to achieve a close control of interfacial properties and geometry are then described, which includes the creation of either flexible or rigid polymer interfaces, the use of liquid crystals and developing ceramic and carbon-based interfaces with tailored electrical properties. The impact of the variety of interface structures on composite polarization and energy storage capability are described, along with an overview of existing models to understand the polarization mechanisms and quantitatively assess the potential benefits of different structures for energy storage. The applications and properties of such interface-controlled materials are then explored, along with an overview of existing challenges and practical limitations. Finally, a summary and future perspectives are provided to highlight future directions of research in this growing and important area

Evaluation of the pore morphologies for piezoelectric energy harvesting application

Piezoelectric energy harvesting has attracted significant attention in recent years due to their high-power density and potential applications for self-powered sensor networks. In comparison to dense piezoelectric ceramics, porous piezoelectric ceramics exhibit superiority due to an enhancement of piezoelectric energy harvesting figure of merit. This paper provides a detailed examination of the effect of pore morphology on the piezoelectric energy harvesting performance of porous barium calcium zirconate titanate 0.5Ba(Zr0.2 Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 (BCZT) ceramics. Three different pore morphologies of spherical, elliptical, and aligned lamellar pores were created via the burnt-out polymer spheres method and freeze casting. The relative permittivity decreased with increasing porosity volume fraction for all porous BCZT ceramics. Both experimental and simulation results demonstrate that porous BCZT ceramics with aligned lamellar pores exhibit a higher remanent polarization. The longitudinal d33 piezoelectric charge coefficient decreased with increasing porosity volume fraction for the porous ceramics with three different pore morphologies; however, the rate of decrease in d33 with porosity is slower for aligned lamellar pores, leading to the highest piezoelectric energy harvesting figure of merit. Moreover, the peak power density of porous BCZT ceramics with aligned lamellar pores is shown to reach up to 38 μW cm-2 when used as an energy harvester, which is significantly higher than that of porous BCZT ceramics with spherical or elliptical pores. This work is beneficial for the design and manufacture of porous ferroelectric materials in devices for piezoelectric energy harvesting applications.</p

Significantly enhanced permittivity and energy density in dielectric composites with aligned BaTiO3 lamellar structures

A significant improvement of permittivity and energy density will enable the miniaturization of dielectric capacitors and promote integration for applications in electrical power and defense systems. In this work, lamellar composite architectures are fabricated from aligned barium titanate (BaTiO3) in an epoxy resin using the freeze casting method. Due to the continuous coupling effect originating from the interconnected and highly oriented BaTiO3 particles, these composites exhibit an extremely high permittivity (εr = 1408) at 1 kHz, which is the highest value achieved in BaTiO3/polymer composites reported so far and fits well to the parallel mode of the mixing rule. A finite element model is used to investigate the local electric field distributions in the BaTiO3 lamellae under the applied electric field parallel and perpendicular to the freezing direction, respectively. A high ratio value of discharge energy density per electric field, Udis/E, ∼0.033, is achieved due to a high electric displacement of D = 15.11 μC cm−2 and a discharge energy density of Udis = 19.6 × 10−2 J cm−3 is achieved at a low electric field (6 kV mm−1). This work provides an effective strategy of designing a ceramic–polymer composite to realize high permittivity and energy density of capacitors for modern electrical and electronic industries

High Performance Capacitors Using BaTiO₃ Nanowires Engineered by Rigid Liquid-crystalline Polymers

Capacitors that provide high power density have attracted scientific and commercial interest, while often suffering from low energy density. Preparing a core-shell structured ceramic is regarded as a kind of effective method to improve the energy density, which is largely determined by the shell in the interfacial region. However, the current state-of-the-art of interfacial layer modification is predominantly based on utilizing flexible polymers, which are random polymer coils that collapse on the surface of any modified ceramic nanoparticles. Because of the characteristic properties of rigidity and orientation, the liquid-crystalline polymer poly{2,5-bis[(4-methoxyphenyl)oxycarbonyl]styrene} (PMPCS) is utilized to engineer the interfacial layer thickness on BaTiO3 nanowire surfaces via surface-initiated reversible addition-fragmentation chain transfer polymerization (RAFT) method, in this paper. As a result, a high discharged energy density of 7.5 J/cm3 and an energy efficiency of 55.1% at 300 MV/m are achieved, respectively. The findings proved that rigid liquid-crystalline polymer is a promising modifier to prepare high performance capacitors and to explore the interfacial effect in dielectric nanocomposites.</p

Quantum Image Processing and Its Application to Edge Detection: Theory and Experiment

Processing of digital images is continuously gaining in volume and relevance, with concomitant demands on data storage, transmission and processing power. Encoding the image information in quantum-mechanical systems instead of classical ones and replacing classical with quantum information processing may alleviate some of these challenges. By encoding and processing the image information in quantum-mechanical systems, we here demonstrate the framework of quantum image processing, where a pure quantum state encodes the image information: we encode the pixel values in the probability amplitudes and the pixel positions in the computational basis states. Our quantum image representation reduces the required number of qubits compared to existing implementations, and we present image processing algorithms that provide exponential speed-up over their classical counterparts. For the commonly used task of detecting the edge of an image, we propose and implement a quantum algorithm that completes the task with only one single-qubit operation, independent of the size of the image. This demonstrates the potential of quantum image processing for highly efficient image and video processing in the big data era.Comment: 13 pages, including 9 figures and 5 appendixe

Flexible PVDF-TrFE Nanocomposites with Ag-decorated BCZT Heterostructures for Piezoelectric Nanogenerator Applications

Flexible piezoelectric nanogenerators are playing an important role in delivering power to next-generation wearable electronic devices due to their high-power density and potential to create self-powered sensors for the Internet of Things. Among the range of available piezoelectric materials, poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE)-based piezoelectric composites exhibit significant potential for flexible piezoelectric nanogenerator applications. However, the high electric fields that are required for poling cannot be readily applied to polymer composites containing piezoelectric fillers due to the high permittivity contrast between the filler and matrix, which reduces the dielectric strength. In this paper, novel Ag-decorated BCZT heterostructures were synthesized via a photoreduction method, which were introduced at a low level (3 wt %) into the matrix of PVDF-TrFE to fabricate piezoelectric composite films. The effect of Ag nanoparticle loading content on the dielectric, ferroelectric, and piezoelectric properties was investigated in detail, where a maximum piezoelectric energy-harvesting figure of merit of 5.68 × 10-12 m2/N was obtained in a 0.04Ag-BCZT NWs/PVDF-TrFE composite film, where 0.04 represents the concentration of the AgNO3 solution. Modeling showed that an optimum performance was achieved by tailoring the fraction and distribution of the conductive silver nanoparticles to achieve a careful balance between generating electric field concentrations to increase the level of polarization, while not degrading the dielectric strength. This work therefore provides a strategy for the design and manufacture of highly polarized piezoelectric composite films for piezoelectric nanogenerator applications.</p

Enhanced energy harvesting performance in lead-free multi-layer piezoelectric composites with a highly aligned pore structure

The harvesting of mechanical energy from our living environment via piezoelectric energy harvesters to provide power for next generation wearable electronic devices and sensors has attracted significant interest in recent years. Among the range of available piezoelectric materials, porous piezoelectric ceramics exhibit potential for both sensing and energy harvesting applications due to their reduced relative permittivity and enhanced piezoelectric sensing and energy harvesting figures of merit. Despite these developments, the low output power density and the lack of optimized structural design continues to restrict their application. Here, to overcome these challenges, a lead-free multi-layer porous piezoelectric composite energy harvester with a highly aligned pore structure and three-dimensional intercalation electrodes is proposed, fabricated and characterized. The effect of material structure and multi-layer configuration of the porous piezoelectric ceramic on the dielectric properties, piezoelectric response and energy harvesting performance was investigated in detail. Since the relative permittivity is significantly reduced due to the introduction of aligned porosity within the multi-layer structure, the piezoelectric voltage coefficient, energy harvesting figure of merit and output power are greatly enhanced. The multi-layer porous piezoelectric composite energy harvester is shown to generate a maximum output current of 80 μA, with a peak power density of 209 μW cm−2, which is significantly higher than other porous piezoelectric materials reported to date. Moreover, the generated power can charge a 10 μF capacitor from 0 V to 4.0 V in 150 s. This work therefore provides a new strategy for the design and manufacture of porous piezoelectric materials for piezoelectric sensing and energy harvesting applications.</p