5 research outputs found

    Novel energy bandgap formation of organic solution doped graphene membrane for semiconductor applications

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    In this work, the electrolyte nano fibrous solution is prepared using corn husk through a chemical process. This study explores the new aspect of producing sizeable and tunable bandgap in graphene by doping organic nanoporous solution as a membrane. The energy bandgap of organic doped graphene membrane varies from 2.313 eV to 2.502 eV.  It is noted that the organic nanoporous solution as a membrane also has a bandgap under with (2.665 eV) and without PVA (3.761 eV).  The membrane is produced by the phase inversion process. The incorporation of graphene in green solution also exhibits conductive properties like organic nanoporous solution which in terns used as electrolytes to produce electricity. It is the first successful attempt to create a direct graphene bandgap with organic doping but it still requires more research for a better understanding of the properties for future applications. This concept can also be used where bandgap is a very concerning issue. The physical properties of with and without a graphene-based organic membrane are examined by Scanning Electron Microscope Test (SEM), Fourier Transform Infrared Spectroscopy Test (FTIR), and Ultra Violate Test (UV). Sample 4 has a superior surface morphology, which means the particle dispersion is more homogeneous than the others. There are porosities in all the samples

    Synthesis and characterization of novel banana-graphene nanofibrous membrane from viscous liquid for bandgap formation

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    Organic semiconductors with wide bandgaps have potential applications in organic light-emitting diode displays, organic photovoltaic devices, organic field-effect transistors and solar cells. However, organic semiconductors are not good conductors of electricity. This study synthesizes the banana-graphene nanofibrous membrane using an electric spin process to form a tunable bandgap to enhance conductivity. The chemical process was followed to prepare liquid viscous from banana stalks. Different percentages of graphene (1.2 wt.%, 2.4 wt.% and 3.6 wt.%) were used with the liquid viscous to form sizeable and tunable bandgaps in the composites and enhance the conductivity of the materials. The results showed 5.67 %, 24.5 %, and 27.8 % lower bandgap for 1.2 wt.%, 2.4 %, and 3.6 wt.% graphene-contained samples, respectively, as compared to the polyvinyl alcohol (PVA) viscous fibre (3.35 eV). With the addition of graphene with PVA viscous fibre, the properties of electrospun nanofibrous graphene were changed from insulator to semiconductor. The band gap property was controlled by incorporating graphene with various percentages. The morphology of the surfaces showed that nanofibers are bonded with each other, and graphene nanoparticles are uniformly distributed. The results of this work can be considered to further progress in manufacturing nanocomposites for organic semiconductor applications
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