One-Step Holographic Photoalignment for Twisted Nematic Liquid Crystal Gratings

Liquid crystal gratings, in which liquid crystal molecules are periodically aligned, are fabricated by highly efficient and practical one-step holographic photoalignment method using a photocrosslinkable polymer liquid crystal (PCLC). This method is an innovative fabrication technique for liquid crystal grating containing a twisted nematic alignment, which does not require a conventional complex fabrication process. In this chapter, three types of liquid crystal gratings with twisted nematic alignment are fabricated. Periodic director distributions of these liquid crystal gratings are analyzed based on the elastic continuum theory and observed experimentally using a polarized light optical microscope. Furthermore, the polarization diffraction properties were measured by illumination with a visible laser beam. The resultant liquid crystal gratings exhibit various polarization diffraction properties depending on the director distributions and the polarization states of the incident beams. These polarization diffraction properties are well explained by theoretical analysis based on Jones calculus. These resultant liquid crystal gratings exhibit great potential for application as a diffractive optical element that can simultaneously control the various parameters of the light wave, such as amplitude, polarization states, and propagation direction

微小光学素子のための新規有機光学材料の合成

京都大学0048新制・論文博士博士(工学)乙第8656号論工博第2897号新制||工||969(附属図書館)UT51-94-R415(主査)教授 齋藤 烈, 教授 山本 雅英, 教授 清水 剛夫学位規則第4条第2項該当Doctor of EngineeringKyoto UniversityDFA

Blue-Shifting Mechanofluorochromic Luminescent Behavior of Polymer Composite Films Using Gelable Mechanoresponsive Compound

Mechanochromic luminescent dyes change their luminescence color upon exposure to external mechanical stimuli. In this study, we synthesized a liquid crystalline mechanochromic luminescent dye containing a terminal cholesterol molecule. The dissolution of the dye in 1,4-dioxane resulted in the formation of a gel. The luminescence of the xerogel obtained from the dioxane solution changed from green to blue upon grinding, indicating mechanochromic luminescence behavior. The anisotropic patterning of short-wavelength-shifted luminescence color change by directional handwriting on surface layer of liquid crystal was successfully demonstrated. Furthermore, blue-shifting mechanoresponsive polymer composite surface was fabricated by using the luminophore