The preparation, identification and properties of chlorophyll derivatives

In the investigation of 10-hydroxy chlorophylls a and b novel techniques included modification of chromatography and the use of fully-deuterated compounds isolated from fully-deuterated autotropic algae to determine the molecular structure of the chlorophylls

Development of a magneforming process for the fabrication of thin-wall tungsten cylinders final report

Magneforming process - high energy rate metal forming technique for fabrication of thin wall tungsten cylinder

Intergalactic Helium Absorption in Cold Dark Matter Models

Observations from the HUT and the HST have recently detected HeII absorption along the lines of sight to two high redshift quasars. We use cosmological simulations with gas dynamics to investigate HeII absorption in the cold dark matter (CDM) theory of structure formation. We consider two Omega=1 CDM models with different normalizations and one Omega_0=0.4 CDM model, all incorporating the photoionizing UV background spectrum computed by Haardt & Madau (1996). The simulated gas distribution, combined with the H&M spectral shape, accounts for the relative observed values of taubar_HI and taubar_HeII, the effective mean optical depths for HI and HeII absorption. If the background intensity is as high as H&M predict, then matching the absolute values of taubar_HI and taubar_HeII requires a baryon abundance larger (by factors between 1.5 and 3 for the various CDM models) than our assumed value of Omega_b h^2=0.0125. The simulations reproduce the evolution of taubar_heII over the observed redshift range, 2.2 < z < 3.3, if the HeII photoionization rate remains roughly constant. HeII absorption in the CDM simulations is produced by a diffuse, fluctuating, intergalactic medium, which also gives rise to the HI ly-alpha forest. Much of the HeII opacity arises in underdense regions where the HI optical depth is very low. We compute statistical properties of the HeII and HI absorption that can be used to test the CDM models and distinguish them from an alternative scenario in which the HeII absorption is caused by discrete, compact clouds. The CDM scenario predicts that a substantial amount of baryonic material resides in underdense regions at high redshift. HeII absorption is the only sensitive probe of such extremely diffuse, intergalactic gas, so it can provide a vital test of this fundamental prediction.Comment: Accepted for publication in ApJ, 36 pages, LaTeX (aaspp4), 12 figures. Changes include addition of more information on statistical uncertainties and on the adopted UV background. Also available at http://www-astronomy.mps.ohio-state.edu/~racc

Industrial Relations and Productivity in the U.S. Automobile Industry

macroeconomics, Automobile, industrial relations, productivity

Gravitational energy

Observers at rest in a stationary spacetime flat at infinity can measure small amounts of rest-mass+internal energies+kinetic energies+pressure energy in a small volume of fluid attached to a local inertial frame. The sum of these small amounts is the total "matter energy" for those observers. The total mass-energy minus the matter energy is the binding gravitational energy. Misner, Thorne and Wheeler evaluated the gravitational energy of a spherically symmetric static spacetime. Here we show how to calculate gravitational energy in any static and stationary spacetime for isolated sources with a set of observers at rest. The result of MTW is recovered and we find that electromagnetic and gravitational 3-covariant energy densities in conformastatic spacetimes are of opposite signs. Various examples suggest that gravitational energy is negative in spacetimes with special symmetries or when the energy-momentum tensor satisfies usual energy conditions.Comment: 12 pages. Accepted for publication in Class. Quantum Gra

Characterization of Lyman Alpha Spectra and Predictions of Structure Formation Models: A Flux Statistics Approach

In gravitational instability models, \lya absorption arises from a continuous fluctuating medium, so that spectra provide a non-linear one-dimensional ``map'' of the underlying density field. We characterise this continuous absorption using statistical measures applied to the distribution of absorbed flux. We describe two simple members of a family of statistics which we apply to simulated spectra in order to show their sensitivity as probes of cosmological parameters (H$_{0}$, $\Omega$, the initial power spectrum of matter fluctuations) and the physical state of the IGM. We make use of SPH simulation results to test the flux statistics, as well as presenting a preliminary application to Keck HIRES data.Comment: Contribution to proceedings of the 18th Texas Symposium on Relativistic Astrophysics (eds A. Olinto, J. Frieman and D. Schramm, World Scientific),Chicago, December 1996, 3 pages, LaTeX (sprocl), 2 figures. Also available at http://www-astronomy.mps.ohio-state.edu/~racc

Accurate determination of the Lagrangian bias for the dark matter halos

We use a new method, the cross power spectrum between the linear density field and the halo number density field, to measure the Lagrangian bias for dark matter halos. The method has several important advantages over the conventional correlation function analysis. By applying this method to a set of high-resolution simulations of 256^3 particles, we have accurately determined the Lagrangian bias, over 4 magnitudes in halo mass, for four scale-free models with the index n=-0.5, -1.0, -1.5 and -2.0 and three typical CDM models. Our result for massive halos with $M \ge M_*$ ($M_*$ is a characteristic non-linear mass) is in very good agreement with the analytical formula of Mo & White for the Lagrangian bias, but the analytical formula significantly underestimates the Lagrangian clustering for the less massive halos $M < M_*. Our simulation result however can be satisfactorily described, with an accuracy better than 15%, by the fitting formula of Jing for Eulerian bias under the assumption that the Lagrangian clustering and the Eulerian clustering are related with a linear mapping. It implies that it is the failure of the Press-Schechter theories for describing the formation of small halos that leads to the inaccuracy of the Mo & White formula for the Eulerian bias. The non-linear mapping between the Lagrangian clustering and the Eulerian clustering, which was speculated as another possible cause for the inaccuracy of the Mo & White formula, must at most have a second-order effect. Our result indicates that the halo formation model adopted by the Press-Schechter theories must be improved.Comment: Minor changes; accepted for publication in ApJ (Letters) ; 11 pages with 2 figures include

On the mass of a Kerr-anti-de Sitter spacetime in D dimensions

We show how to compute the mass of a Kerr-anti-de Sitter spacetime with respect to the anti-de Sitter background in any dimension, using a superpotential which has been derived from standard Noether identities. The calculation takes no account of the source of the curvature and confirms results obtained for black holes via the first law of thermodynamics.Comment: minor changes; accepted by CQ

The growth of galaxies in cosmological simulations of structure formation

We use hydrodynamic simulations to examine how the baryonic components of galaxies are assembled, focusing on the relative importance of mergers and smooth accretion in the formation of ~L_* systems. In our primary simulation, which models a (50\hmpc)^3 comoving volume of a Lambda-dominated cold dark matter universe, the space density of objects at our (64-particle) baryon mass resolution threshold, M_c=5.4e10 M_sun, corresponds to that of observed galaxies with L~L_*/4. Galaxies above this threshold gain most of their mass by accretion rather than by mergers. At the redshift of peak mass growth, z~2, accretion dominates over merging by about 4:1. The mean accretion rate per galaxy declines from ~40 M_sun/yr at z=2 to ~10 M_sun/yr at z=0, while the merging rate peaks later (z~1) and declines more slowly, so by z=0 the ratio is about 2:1. We cannot distinguish truly smooth accretion from merging with objects below our mass resolution threshold, but extrapolating our measured mass spectrum of merging objects, dP/dM ~ M^a with a ~ -1, implies that sub-resolution mergers would add relatively little mass. The global star formation history in these simulations tracks the mass accretion rate rather than the merger rate. At low redshift, destruction of galaxies by mergers is approximately balanced by the growth of new systems, so the comoving space density of resolved galaxies stays nearly constant despite significant mass evolution at the galaxy-by-galaxy level. The predicted merger rate at z<~1 agrees with recent estimates from close pairs in the CFRS and CNOC2 redshift surveys.Comment: Submitted to ApJ, 35 pp including 15 fig

Hydrolysis of Rare Earth Sulfates.

n/