Controlling Silver Nanoparticle Size and Morphology with Photostimulated Synthesis

Photo-induced synthesis and control over the size and shape of colloidal silver nanoparticles is investigated in contrast to photo-stimulated aggregation of small nanoparticles into large fractal-type structures. The feasibility of light-driven nanoengineering which enables manipulation of the sizes and shapes of the isolated nanoparticles is studied by varying the amount and type of the stabilizing agent and the type of optical irradiation.Comment: 10 pages, 7 figures, 11 image

Relative abundance and size composition of subtidal abalone, Haliotis spp., sea urchin, Strongylocentrotus spp., and abundance of sea stars off Fitzgerald marine reserve, September 1993

Data were collected at twenty-six dive stations at seven discrete latitudes along Fitzgerald Marine Reserve (FMR). Dive stations were targeted at three stratified depth zones: shallow (6.1 m), medium (10.7 m), and deep (16.8 m) in six of the seven locations. Two types of line transects, emergent and invasive, were completed by separate dive teams at each dive station. The area surveyed totalled 1,510 m2 for emergent and 560 m2 for invasive transects. Reef habitat dominated all depth zones, with moveable boulder and cobble increasing at medium and shallow depths. Encrusting coraline and surface algae dominated (49%), followed by turf (37%), sub-canopy (11.2%), and rare canopy (0.2%). Canopy was found only at shallow depths. Turf and sub-canopy decreased with depth. Only two species of abalone, red, Haliotis rufescens, and flat, H. walallensis, were found. Flat abalone were extremely rare with only two found on invasive transects (0.004 abalone m-2). Red abalone densities were low at both emergent (0.02 abalone m-2, s.e.=O.Ol) and invasive (0.07 abalone m-2, s.e.=0.03 ) transects. Red abalone concentrations differed significantly by depth and location. No abalone were found at deep depths and only one sport-legal (178 mm shell length) abalone was found at medium depth. One commercial legal (198 mm shell length) abalone was found on the entire survey. Most sport-legal abalone were located in cryptic habitat in shallow invasive transects (38%), compared to 7% on emergent transects. The only evidence of recruitment was found on invasive transects where three young-of-the-year (<=31 mm shell length) red abalone were found. Evidence from our survey and other sources suggests that sport and commercial fisheries are not sustainable off the San Mateo coast. Red urchin, Stongylocentrotus franciscanus, were more abundant than purple urchin, S. purpuratus, or red abalone. Red urchin densities were lower in emergent (1.08 urchin m-2,s.e.=0.04) than invasive (1.52, s.e.=0.06 m-2) transects. Densities of red urchin at deep stations in areas of lower algal abundance and potentially greater commercial fishing pressure were about one-half the densities at medium and shallow depths. ANOVA showed significant differences by depth and location. Mean Test Diameter (MTD) increased from deep to medium to shallow depths, while juvenile (<=50 mm) MTD showed an inverse relationship with depth. Shallow-depth invasive transects revealed a missing mode of 83 mm red urchin. This size mode was not found in emergent transects, probably due to cryptic habitat. Purple urchin were found at low densities at all three depth strata. Purple urchin densities were comparable in emergent (0.11 urchin m-2, s.e.=0.02 ) and invasive (0.09 urchin m-2,s.e.=0.03) transects. ANOVA showed densities varied significantly by location but not depth. 'Juvenile' purple urchin abundance showed an inverse relation to juvenile red urchin, increasing from deep to shallow depths. Purple urchin MTD of 84 mm (s.d.=23) was larger than reported for intertidal areas off FMR. Sea stars were found in high abundance off FMR. Bat stars, Asterina minata, had the highest densities (0.79 sea stars m-2, s.e.=0.03) followed by Pisaster sp. (0.47 sea stars m-2,s.e.=0.03 ), and sunflower stars, Pycnopodia helianthoides, (0.11 sea stars m-2, s.e.=0.04). Pisaster sp. was the only group of sea stars where differences in density were significant by depth or location. (30pp.

Spectroscopic studies of fractal aggregates of silver nanospheres undergoing local restructuring

We present an experimental spectroscopic study of large random colloidal aggregates of silver nanoparticles undergoing local restructuring. We argue that such well-known phenomena as strong fluctuation of local electromagnetic fields, appearance of "hot spots" and enhancement of nonlinear optical responses depend on the local structure on the scales of several nanosphere diameters, rather that the large-scale fractal geometry of the sample.Comment: 3.5 pages, submitted to J. Chem. Phy

Semiorthogonal decompositions of derived categories of equivariant coherent sheaves

Let X be an algebraic variety with an action of an algebraic group G. Suppose X has a full exceptional collection of sheaves, and these sheaves are invariant under the action of the group. We construct a semiorthogonal decomposition of bounded derived category of G-equivariant coherent sheaves on X into components, equivalent to derived categories of twisted representations of the group. If the group is finite or reductive over the algebraically closed field of zero characteristic, this gives a full exceptional collection in the derived equivariant category. We apply our results to particular varieties such as projective spaces, quadrics, Grassmanians and Del Pezzo surfaces.Comment: 28 pages, uses XY-pi

Curvature Correction in the Strutinsky's Method

Mass calculations carried out by Strutinsky's shell correction method are based on the notion of smooth single particle level density. The smoothing procedure is always performed using curvature correction. In the presence of curvature correction a smooth function remains unchanged if smoothing is applied. Two new curvature correction methods are introduced. The performance of the standard and new methods are investigated using harmonic oscillator and realistic potentials.Comment: 4 figures, submitted to Journal of Physics G: Nuclear and Particle Physic