Micropatterned 2D Hybrid Perovskite Thin Films with Enhanced Photoluminescence Lifetimes

The application of luminescent materials in display screens and devices requires micropatterned structures. In this work, we have successfully printed microstructures of a two-dimensional (2D), orange-colored organic/inorganic hybrid perovskite ((C6H5CH2NH3)2PbI4) using two different soft lithography techniques. Notably, both techniques yield microstructures with very high aspect ratios in the range of 1.5-1.8. X-ray diffraction reveals a strong preferential orientation of the crystallites along the c-axis in both patterned structures, when compared to nonpatterned, drop-casted thin films. Furthermore, (time-resolved) photoluminescence (PL) measurements reveal that the optical properties of (C6H5CH2NH3)2PbI4 are conserved upon patterning. We find that the larger grain sizes of the patterned films with respect to the nonpatterned film give rise to an enhanced PL lifetime. Thus, our results demonstrate easy and cost-effective ways to manufacture patterns of 2D organic/inorganic hybrid perovskites, while even improving their optical properties. This demonstrates the potential use of color-tunable 2D hybrids in optoelectronic devices

The Springbank Island Archaeological Project

This paper presents the results of recentarchaeological investigations carried out on the3.64ha Springbank Island, located within the West Basin of Lake Burley Grifn. This was the location for 'Springbank Homestead', the earliest owner occupiedhomestead in present day Canberra. It was also in a region of signicance for Traditional Owners. The following sections provide historical and archaeologicalinformation about a site that continues to be a popularmeeting place for the Canberra community