Etude de la corrosion d'alliages metalliques amorphes

SIGLET 55145 / INIST-CNRS - Institut de l'Information Scientifique et TechniqueFRFranc

Effect of surface treatment by sandblasting on the quality and electrochemical corrosion properties of a C-1020 carbon steel used by an Algerian oil company

The purpose of the different operations under the term surface preparation is to get a clean surface able to be coated. It is essential to adapt this preparation in terms of the metallurgical nature of the substrate, cleanliness, its shape and roughness. Surface preparations especially the operations of sandblasting, polishing, or grinding prove of capital importance. It allows to modify the superficial properties of these materials, after these treatments the surface becomes very active. This paper evaluates the mechanical surface treatments effect by sandblasting (Sa 1.5 and Sa 2.5) on the electrochemical corrosion characteristics of C-1020 carbon steel in 3% NaCl solution electrolyte simulating aggressive sea atmosphere. Investigations are conducted using stationary (free potential "E-t, polarization curves "E-i", the Tafel rights and the Rp) and nonstationary electrochemical tools such as electrochemical impedance. The results obtained allowed us to highlight that sandblasted carbon steel degrades with immersion time because of the roughness of the surface. These results were confirmed by the plot of the electrochemical impedance diagrams, confirming that the process governing kinetics is under charge transfer control. Good protection against corrosion cannot be obtained only with a good surface preparation of the adapted steel

Étude comparative de l’adsorption d’un colorant de cuve sur différents adsorbants à base d’un matériau inorganique la Bentonite et l’argile de la région de M’sila

International audienceThe present work aims to reduce the impact of vat dyes by a natural and activated Algerian clay using the adsorption technique. The adsorption experiments show that the clay used is very effective in removing the vat dye at relatively low concentrations in an aqueous medium. The adsorption isotherms of the vat dye on the raw clay are satisfactorily described by the Langmuir model. Adsorption capacities in the range of 55.25 mg. g(-1) for crude bentonite (BB), 55.20 mg. g(-1) for sodium bentonite (BS), 51.78 mg. g(-1) for red clay (AR) and 48.24 mg. g(-1) for Madadid clay (AM) were determined from the Langmuir isotherm. These values show that the raw bentonite has a better adsorption capacity because it contains a large percentage of clay fraction

The Corrosion Protection Behaviour of Zinc Rich Epoxy Paint in 3% NaCl Solution

Electrochemical impedance spectroscopy (EIS) in the l00 kHz-10 mHz frequency range was employed as the main electrochemical technique to study the corrosion protection behaviour of zinc rich epoxy paint in 3% NaCl solution. The EIS results obtained at the open-circuit corrosion potential have been interpreted using a model involving the impedance of particle to particle contact to account for the increasing resistance between zinc particles with immersion period, in addition to the impedance due to the zinc surface oxide layer and the electrical resistivity of the binder. Galvanic current and dc potential measurements allowed us to conclude that the cathodic protection effect of the paint takes some time to be achieved. The loss of cathodic protection is due to a double effect: the decrease of the Zn/Fe area ratio due to Zn corrosion and the loss of electric contact between Zn to Zn particles. Even when the cathodic protection effect by Zn dust become weak, the substrate steel is still protected against corrosion due to the barrier nature of the ZRP film reinforced by Zn

Étude de l’effet du temps de traitement alcalin de fibres palmier sur le comportement mécanique des matériaux à base d’argile rouge de la région de M’sila

Ce travail s’inscrit dans le développement de matériaux locaux, telle que la fibre végétale (fibre de palmier) et l’argile rouge du sud Algérien, largement utilisées dans la préparation des briques, comme matériaux de construction rurale. Les fibres végétales possèdent des propriétés très intéressantes, elles sont : renouvelables, biodégradables et le rapport coût/légèreté faible. Leurs propriétés mécaniques sont très importantes. Cependant, le problème prédominant dans ce type de matériaux composites est la faible adhésion de l’interface matrice-fibre, attribuée probablement, à la nature de la surface et au caractère hydrophobe des fibres naturelles, conduisant ainsi, à des propriétés mécaniques faibles pour le composite envisagé. Le but de cette étude consiste à traiter la fibre de palmier par une solution basique d’hydroxyde de sodium (NaOH 4 % [m/v]) durant des périodes variables : 3, 7, 24 et 48 heures, afin d’améliorer l’adhésion interfaciale. Les résultats obtenus à partir des essais réalisés sur le composite renforcé par les fibres de palmier traitées durant 7 h ont montré une nette augmentation quant à la résistance, à la flexion et à la compression ; cette croissance est respectivement de l’ordre de 57 et 60 %, comparativement au composite renforcé par les fibres non traitées. On peut déduire que les fibres de palmier peuvent être considérées comme l’un des matériaux appropriés pour le renforcement de l’argile

The effect of chemical treatment on the mechanical and thermal properties of composite materials based on clay reinforced with sawdust

This study investigates the effect of the chemical treatment of sawdust on the mechanical and thermal properties of a clay composite reinforced with sawdust in variable mass proportions: 0.5, 1, 1.5, 2 and 2.5%, intended for use as brick in rural houses in desert areas. The sawdust was chemically treated with 5 wt% NaOH and 0.01 wt% KMnO4 solutions. The mechanical test results of the reinforced composite with alkali-treated sawdust show an increase in flexural and compression strength, reaching a maximum value of 0.89 and 4.85 MPa, respectively. However, the thermal test results show a significant decrease in the thermal conductivity of the sawdust-reinforced composite. The best result recorded is that of untreated sawdust, which has a value of 0.37 (W.m−1.K−1) compared to the one reinforced with treated sawdust