314 research outputs found
Bis(1,10-phenanthroline-κ2 N,N′)(sulfato-O)copper(II) ethane-1,2-diol monosolvate
In the title compound, [Cu(SO4)(C12H8N2)2]·C2H6O2, the CuII ion is five-coordinated in a distorted square-pyramidal manner by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and one O atom from a monodentate sulfate anion. The four N atoms comprise a square and the one O atom the apex of a square pyramid. The two chelating N2C2 groups are oriented at 71.1 (2)°. In the crystal, the components are connected by intermolecular O—H⋯O hydrogen bonding. The presence of pseudosymmetry in the structure suggests the higher symmetry space group C2/c, but attempts to refine the structure in this space group resulted in an unsatisfactory model
Bis(1,10-phenanthroline-κ2 N,N′)(sulfato-κ2 O,O′)cobalt(II) butane-2,3-diol monosolvate
In the title compound, [Co(SO4)(C12H8N2)2]·C4H10O2, the Co2+ ion has a distorted octahedral coordination environment composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate anion. The dihedral angle between the two chelating N2C2 groups is 83.48 (1)°. The Co2+ ion, the S atom and the mid-point of the central C—C bond of the butane-2,3-diol solvent molecule are situated on twofold rotation axes. The molecules of the complex and the solvent molecules are held together by pairs of symmetry-related O—H⋯O hydrogen bonds with the uncoordinated O atoms of the sulfate ions as acceptors. The solvent molecule is disordered over two sets of sites with site occupancies of 0.40 and 0.60
Bis(1,10-phenanthroline-κ2 N,N′)(sulfato-κ2 O,O′)zinc(II) propane-1,3-diol solvate
In the title compound, [Zn(SO4)(C12H8N2)2]·C3H8O2, the Zn2+ ion (site symmetry 2) is coordinated by two chelating 1,10-phenanthroline ligands and an O,O′-bidentate sulfate ion (S site symmetry 2), resulting in a distorted cis-ZnO2N4 octahedral geometry for the metal ion. The complete propane-1,3-diol molecule is generated by crystallographic twofold symmetry and two O—H⋯O hydrogen bonds are formed with the uncoordinated O atoms of the sulfate group
Bis(1,10-phenanthroline-κ2 N,N′)(sulfato-κ2 O,O′)nickel(II) propane-1,3-diol solvate
In the structure of the title compound, [Ni(SO4)(C12H8N2)2]·C3H8O2, the NiII ion (site symmetry 2) is six-coordinated in a distorted octahedral manner by four N atoms from two chelating 1,10-phenanthroline (phen) ligands and two O atoms from a bidentate sulfate ligand (2 symmetry). The dihedral angle between the two chelating NCCN groups is 80.9 (1)°. The central C atom of the propane-1,3-diol solvent molecule is likewise located on a twofold rotation axis. In the crystal structure, the [Ni(SO4)(C12H8N2)2] and C3H8O2 entities are connected through intermolecular O—H⋯O hydrogen bonding
Bis(1,10-phenanthroline-κ2 N,N′)(sulfato-κ2 O,O′)cadmium(II) propane-1,3-diol solvate
In the title compound, [Cd(SO4)(C12H8N2)2]·C3H8O2, the CdII atom has a distorted octahedral coordination composed of four N atoms from two chelating 1,10-phenanthroline ligands and two O atoms from an O,O′-bidentate sulfate group. The two chelating NCCN groups subtend a dihedral angle of 82.21 (9)°. The CdII ion, the S atom and the middle C atom of the propane-1,3-diol solvent molecule are located on special positions, site symmetry 2. The solvate features a pair of O—H⋯O hydrogen bonds with the uncoordinated O atoms of the sulfate ion. The OH group of the propane-1,3-diol solvent is disordered over two positions of equal occupancy
Bis(2,2′-bipyridyl-κ2 N,N′)(sulfato-κ2 O,O′)zinc(II) ethane-1,2-diol solvate
The title compound, [Zn(SO4)(C10H8N2)2]·C2H6O2, is a six-coordinate zinc(II) complex with a distorted octahedral coordination geometry. The ZnII atom is bonded by two O atoms of the bidentate chelating sulfate ligand and four N atoms of the two chelating 2,2′-bipyridine ligands. The Zn—N bond distances range from 2.1287 (17) to 2.1452 (17) Å and the Zn—O bond distance is 2.1811 (15) Å. The two chelating NCCN groups subtend a dihedral angle of 81.1 (1)°. In the crystal structure, the [ZnSO4(C10H8N2)2] and C2H6O2 units are connected by intermolecular O—H⋯O hydrogen bonding, which leads to additional stabilization of the structure
Tris(1,10-phenanthroline-κ2 N,N′)nickel(II) bis(2,4,5-tricarboxybenzoate) monohydrate
In the title compound, [Ni(C12H8N2)3](C10H5O8)2·H2O, the NiII cation is coordinated by six N atoms of the three bidentate chelating 1,10-phenanthroline ligands in a slightly distorted octahedral coordination geometry. The Ni—N bond lengths range from 2.074 (2) to 2.094 (2) Å. The dihedral angles between the three chelating NCCN groups to each other are 85.71 (3), 73.75 (2) and 85.71 (3)°, respectively. The Ni cation, the phenyl ring of the 1,10-phenanthroline ligand and the lattice water molecule are located on special positions (site symmetry 2). In the crystal, the uncoordinated 2,4,5-tricarboxybenzenoate anions join with each other through O—H⋯O hydrogen bonds, forming a two-dimensional hydrogen-bonded layer structure along the bc plane. The layers are further linked via additional O—H⋯O interactions between water and carboxyl groups, resulting in a three-dimensional supramolecular network
Bis(1,10-phenanthroline-κ2 N,N′)(sulfato-κ2 O,O′)nickel(II) ethane-1,2-diol solvate
In the title compound, [Ni(SO4)(C12H8N2)2]·C2H6O2, the coordination polyhedron around the Ni2+ ion is a distorted octahedron, with four N atoms from two phenanthroline groups and two O atoms from a bidentate sulfate ligand. The Ni2+ ion lies on a special position of site symmetry 2. Intermolecular O—H⋯O hydrogen bonds help to stabilize the structure. The OH group of the ethane-1,2-diol solvent is disordered over two positions with equal occupancy
Bis(1,10-phenanthroline-κ2 N,N′)(sulfato-κ2 O,O′)cobalt(II) propane-1,3-diol solvate
The title compound, [Co(SO4)(C12H8N2)2]·C3H8O2, was obtained unexpectedly as a by-product during an attempt to synthesize a mixed-ligand complex of CoII with 1,10-phenanthroline (phen) and melamine via a solvothermal reaction. The CoII metal ions are in a distorted octahedral coordination environment formed by four N atoms from two chelating phen ligands and two O atoms from a bidentate sulfate ligand. The two chelating N2C2 groups are almost perpendicular to each other [dihedral angle = 80.06 (8)°]. A twofold rotation axis passes through the Co and S atoms, and also through the central C atom of the propane-1,3-diol solvent molecule. Intermolecular O—H⋯O hydrogen bonds help to stabilize the structure
Bis(2,2′-bipyridyl-κ2 N,N′)(sulfato-κ2 O,O′)cobalt(II) ethane-1,2-diol monosolvate
The title compound, [Co(SO4)(C10H8N2)2]·C2H6O2, has the Co2+ ion in a distorted octahedral CoN4O2 coordination geometry. A twofold rotation axis passes through the Co and S atoms, and through the mid-point of the C—C bond of the ethanediol molecule. In the crystal, the [CoSO4(C10H8N2)2] and C2H6O2 units are held together by a pair of O—H⋯O hydrogen bonds
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