3,573 research outputs found
Microstructure and superconducting properties of hot isostatically pressed MgB2
Bulk samples of MgB2 have been formed by hot isostatic pressing (HIPping) of
commercial powder at 100MPa and 950=B0C. The resulting material is 100% dense
with a sharp superconducting transition at 37.5K. Microstructural studies have
indicated the presence of small amounts of second phases within the material,
namely MgO and B rich compositions, probably MgB4. Magnetisation measurements
performed at 20K have revealed values of Jc=1.3 x 106A/cm2 at zero field, and
9.3 x 105A/cm2 at 1T. Magneto optical (MO) studies have shown direct evidence
for the superconducting homogeneity and strong intergranular current flow in
the material.Comment: 3 pages, 6 figures, text updated, new references included and
discussed. Submitted to Superconductor Science and Technolog
Resonant inelastic x-ray scattering study of hole-doped manganites La1-xSrxMnO3 (x=0.2 and 0.4)
Electronic excitations near the Fermi energy in the hole doped manganese
oxides (La1-xSrxMnO3, x=0.2 and 0.4) have been elucidated by using the resonant
inelastic x-ray scattering (RIXS) method. A doping effect in the strongly
correlated electron systems has been observed for the first time. The
scattering spectra show that a salient peak appears in low energies indicating
the persistence of the Mott gap. At the same time, the energy gap is partly
filled by doping holes and the energy of the spectral weight shifts toward
lower energies. The excitation spectra show little change in the momentum space
as is in undoped LaMnO3, but the scattering intensities in the low energy
excitations of x=0.2 are anisotropic as well as temperature dependent, which
indicates a reminiscence of the orbital nature
Dispersive Gap Mode of Phonons in Anisotropic Superconductors
We estimate the effect of the superconducting gap anisotropy in the
dispersive gap mode of phonons, which is observed by the neutron scattering on
borocarbide superconductors. We numerically analyze the phonon spectrum
considering the electron-phonon coupling, and examine contributions coming from
the gap suppression and the sign change of the pairing function on the Fermi
surface. When the sign of the pairing function is changed by the nesting
translation, the gap mode does not appear. We also discuss the suppression of
the phonon softening of the Kohn anomaly due to the onset of superconductivity.
We demonstrate that observation of the gap dispersive mode is useful for
sorting out the underlying superconducting pairing function.Comment: 7 pages, 12 figures, to be published in J. Phys. Soc. Jp
Copper-catalyzed α-selective hydrostannylation of alkynes for the synthesis of branched alkenylstannanes
A variety of branched alkenylstannanes can directly be synthesized with excellent α-selectivity by the copper-catalyzed hydrostannylation using a distannane or a silylstannane, irrespective of the electronic and steric characteristics of terminal alkynes employed. Synthetic utility of the resulting branched alkenylstannane has been demonstrated by the total synthesis of bexarotene
Incommensurate spin fluctuations in hole-overdoped superconductor KFe2As2
A neutron scattering study of heavily hole-overdoped superconducting
KFeAs revealed a well-defined low-energy incommensurate spin
fluctuation at [),0] with = 0.16. The incommensurate
structure differs from the previously observed commensurate peaks in
electron-doped FeAs ( = Ba, Ca, or Sr) at low energies. The
direction of the peak splitting is perpendicular to that observed in Fe(Te,Se)
or in Ba(Fe,Co)As at high energies. A band structure calculation
suggests interband scattering between bands around the and X points as
an origin of this incommensurate peak. The perpendicular direction of the peak
splitting can be understood within the framework of multiorbital band
structure. The results suggest that spin fluctuation is more robust in
hole-doped than in electron-doped samples, which can be responsible for the
appearance of superconductivity in the heavily hole-doped samples.Comment: 4 pages, 4 figure
Interplay of charge and orbital ordering in manganese perovskites
A model of localized classical electrons coupled to lattice degrees of
freedom and, via the Coulomb interaction, to each other, has been studied to
gain insight into the charge and orbital ordering observed in lightly doped
manganese perovskites. Expressions are obtained for the minimum energy and
ionic displacements caused by given hole and electron orbital configurations.
The expressions are analyzed for several hole configurations, including that
experimentally observed by Yamada et al. in La_{7/8}Sr_{1/8}MnO_3. We find
that, although the preferred charge and orbital ordering depend sensitively on
parameters, there are ranges of the parameters in which the experimentally
observed hole configuration has the lowest energy. For these parameter values
we also find that the energy differences between different hole configurations
are on the order of the observed charge ordering transition temperature. The
effects of additional strains are also studied. Some results for
La_{1/2}Ca_{1/2}MnO_3 are presented, although our model may not adequately
describe this material because the high temperature phase is metallic.Comment: 12 pages in RevTex, 5 figures in PS files, to appear in Phys. Rev. B
(New paragraphs and references added, typos corrected
Conceptual Investigation and Component Testing of Polarimetric and Interferometric Systems for High Density and Large Nuclear Fusion Devices
Interplay of the CE-type charge ordering and the A-type spin ordering in a half-doped bilayer manganite La{1}Sr{2}Mn{2}O{7}
We demonstrate that the half-doped bilayer manganite La_{1}Sr_{2}Mn_{2}O_{7}
exhibits CE-type charge-ordered and spin-ordered states below K and below K, respectively. However, the volume
fraction of the CE-type ordering is relatively small, and the system is
dominated by the A-type spin ordering. The coexistence of the two types of
ordering is essential to understand its transport properties, and we argue that
it can be viewed as an effective phase separation between the metallic
orbital ordering and the charge-localized
orbital ordering.Comment: 5 pages, 4 figures, submitted to Phys. Rev.
Development of Advanced Catalyst for Oxidation of Tritium and Quantification of Mass Transfer Coefficient
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