1,586 research outputs found
Electrochemical synthesis and properties of CoO2, the x = 0 phase of the AxCoO2 systems (A = Li, Na)
Single-phase bulk samples of the "exotic" CoO2, the x = 0 phase of the AxCoO2
systems (A = Li, Na), were successfully synthesized through electrochemical
de-intercalation of Li from pristine LiCoO2 samples. The samples of pure CoO2
were found to be essentially oxygen stoichiometric and possess a hexagonal
structure consisting of stacked triangular-lattice CoO2 layers only. The
magnetism of CoO2 is featured with a temperature-independent susceptibility of
the magnitude of 10-3 emu/mol Oe, being essentially identical to that of a
Li-doped phase, Li0.12CoO2. It is most likely that the CoO2 phase is a
Pauli-paramagnetic metal with itinerant electrons.Comment: 12 pages, 3 figure
Half-ordered state in the anisotropic Haldane-gap antiferromagnet NDMAP
Neutron diffraction experiments performed on the Haldane gap material NDMAP
in high magnetic fields applied at an angle to the principal anisotropy axes
reveal two consecutive field-induced phase transitions. The low-field phase is
the gapped Haldane state, while at high fields the system exhibits
3-dimensional long-range Neel order. In a peculiar phase found at intermediate
fields only half of all the spin chains participate in the long-range ordering,
while the other half remains disordered and gapped.Comment: 4 pages, 2 figures, submitted to Phys. Rev.
Field induced long-range-ordering in an S=1 quasi-one-dimensional Heisenberg antiferromagnet
We have measured the heat capacity and magnetization of the spin one
one-dimensional Heisenberg antiferromagnet NDMAP and constructed a magnetic
field versus temperature phase diagram. We found a field induced long-range
magnetic ordering. We have been successful in explaining the phase diagram
theoretically.Comment: 6 pages, 18 figure
Structural, mechanical, and tribological properties of electrospun poly(hexamethylene adipamide) fiber mats
The mechanical and tribological properties of electrospun fiber mats are of paramount importance to their utility in a large number of applications. In this work, mats of electrospun fibers of poly(hexamethylene adipamide) (PA 6,6) with average fiber diameter of 238±22 nm are characterized for their crystal structure as well as their mechanical and tribological properties. Post-spin thermal annealing was used to modify the fiber morphology and crystallinity within the fibers. Morphological changes, in-plane tensile response, friction coefficient and wear rate were characterized as functions of the annealing temperature. The mechanical and tribological properties of the thermally annealed PA 6,6 fiber mats exhibited significant improvements through the Brill transition temperature, comparable to the improvements observed for amorphous polyamide electrospun mats annealed near the glass transition temperature. The effective wear rate of the electrospun fiber mats is well-described by a previously proposed modification of the Ratner-Lancaster relationship that relates wear to the yield behavior of these nonwoven mats.Massachusetts Institute of Technology. Institute for Soldier Nanotechnologies (AROW911NF-07-D-0004
Molecular Design of Polymer Coatings Capable of Photo-Triggered Stress Relaxation via Dynamic Covalent Bond Exchange
Polymer coatings are frequently used to modify surface properties of inorganic substrates. However, the disparity in physical properties between polymer film and substrate often leads to residual stress development, which can be deleterious to the overall performance of coated materials. This work reports the molecular design of polymer films that dissipate stress upon irradiation with ultraviolet (UV) light. These polymers are synthesized by post-polymerization modification of the reactive polymer, poly(2-vinyl-4,4-dimethyl azlactone), to introduce dynamic crosslinks capable of light-initiated addition transfer fragmentation chemistry. Using a custom-built optical cantilever, contrasting film stress responses are observed between films containing dynamic bonds and analogous control films after UV light irradiation, which indicate successful stress relaxation. Further experiments demonstrate the complete relaxation of residual stress in dynamic films after an extended exposure, thereby generating a “stress-free” film. Films fabricated using this approach can be easily tailored to incorporate additional moieties to introduce desired surface properties for future application in a wide array of coatings
Field-induced commensurate long-range order in the Haldane-gap system NDMAZ
High-field neutron diffraction studies of the new quantum-disordered S=1
linear-chain antiferromagnet Ni(CHN)N(ClO) (NDMAZ)
are reported. At T=70 mK, at a critical field T applied along the
(013) direction, a phase transition to a commensurate N\'{e}el-like ordered
state is observed. The results are discussed in the context of existing
theories of quantum phase transitions in Haldane-gap antiferromagnets, and in
comparions with previous studies of the related system
Ni(CHN)N(PF)
Nanoscale Defect Formation on InP(111) Surfaces after MeV Sb Implantation
We have studied the surface modifications as well as the surface roughness of
the InP(111) surfaces after 1.5 MeV Sb ion implantations. Scanning Probe
Microscope (SPM) has been utilized to investigate the ion implanted InP(111)
surfaces. We observe the formation of nanoscale defect structures on the InP
surface. The density, height and size of the nanostructures have been
investigated here as a function of ion fluence. The rms surface roughness, of
the ion implanted InP surfaces, demonstrates two varied behaviors as a function
of Sb ion fluence. Initially, the roughness increases with increasing fluence.
However, after a critical fluence the roughness decreases with increasing
fluence. We have further applied the technique of Raman scattering to
investigate the implantation induced modifications and disorder in InP. Raman
Scattering results demonstrate that at the critical fluence, where the decrease
in surface roughness occurs, InP lattice becomes amorphous.Comment: 18 pages, 9 figure
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