40 research outputs found

    Glass transition under confinement-what can be learned from calorimetry

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    Calorimetry is an effective analytical tool to characterize the glass transition and phase transitions under confinement. Calorimetry offers a broad dynamic range regarding heating and cooling rates, including isothermal and temperature modulated operation. Today 12 orders of magnitude in scanning rate can be covered by combining different types of calorimeters. The broad dynamic range, comparable to dielectric spectroscopy, is especially of interest for the study of kinetically controlled processes like crystallization or glass transition. Accuracy of calorimetric measurements is not very high. Commonly it does not reach 0.1% and often accuracy is only a few percent. Nevertheless, calorimetry can reach high sensitivity and reproducibility. Both are of particular interest for the study of confined systems. Low addenda heat capacity chip calorimeters are capable to measure the step in heat capacity at the glass transition in nanometer thin films. The good reproducibility is used for the study of glass forming materials confined by nanometer sized structures, like porous glasses, semicrystalline structures, nanocomposites, phase separated block copolymers, etc. Calorimetry allows also for the frequency dependent measurement of complex heat capacity in a frequency range covering several orders of magnitude. Here I exclusively consider calorimetry and its application to glass transition in confined materials. In most cases calorimetry reveals only a weak dependence of the glass transition temperature on confinement as long as the confining dimensions are above 10 nm. Why these findings contradict many other studies applying other techniques to similar systems is still an unsolved problem of glass transition in confinement

    The mbuna cichlids of Lake Malawi: a model for rapid speciation and adaptive radiation

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    Glass transition under confinement-what can be learned from calorimetry

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    Prostate Disease in the Aging Male

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    Measurements of azimuthal anisotropy and charged-particle multiplicity in dd++Au collisions at sNN=\sqrt{s_{_{NN}}}=200, 62.4, 39, and 19.6 GeV

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    International audienceWe present measurements of the elliptic flow (v2) as a function of transverse momentum (pT), pseudorapidity (η), and centrality in d+Au collisions at sNN=200, 62.4, 39, and 19.6 GeV. The beam-energy scan of d+Au collisions provides a testing ground for the onset of flow signatures in small collision systems. We measure a nonzero v2 signal at all four collision energies, which, at midrapidity and low pT, is consistent with predictions from viscous hydrodynamic models. Comparisons with calculations from parton transport models (based on the ampt Monte Carlo generator) show good agreement with the data at midrapidity to forward (d-going) rapidities and low pT. At backward (Au-going) rapidities and pT>1.5GeV/c, the data diverges from ampt calculations of v2 relative to the initial geometry, indicating the possible dominance of nongeometry related correlations, referred to as nonflow. We also present measurements of the charged-particle multiplicity (dNch/dη) as a function of η in central d+Au collisions at the same energies. We find that in d+Au collisions at sNN=200 GeV the v2 scales with dNch/dη over all η in the PHENIX acceptance. At sNN=62.4, and 39 GeV, v2 scales with dNch/dη at midrapidity and forward rapidity, but falls off at backward rapidity. This departure from the dNch/dη scaling may be a further indication of nonflow effects dominating at backward rapidity

    Disentangling centrality bias and final-state effects in the production of high-pTp_Tπ0\pi^0 using direct γ\gamma in dd++Au collisions at sNN=200\sqrt{s_{_{NN}}}=200 GeV

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    International audiencePHENIX presents a simultaneous measurement of the production of direct γ\gamma and π0\pi^0 in dd++Au collisions at sNN=200\sqrt{s_{_{NN}}}=200 GeV over a pTp_T range of 7.5 to 18 GeV/cc for different event samples selected by event activity, i.e. charged-particle multiplicity detected at forward rapidity. Direct-photon yields are used to empirically estimate the contribution of hard-scattering processes in the different event samples. Using this estimate, the average nuclear-modification factor RdAu,EXPγdirR_{d\rm Au,EXP}^{\gamma^{\rm dir}} is 0.925±0.023(stat)±0.15(scale)0.925{\pm}0.023({\rm stat}){\pm}0.15^{\rm (scale)}, consistent with unity for minimum-bias (MB) dd++Au events. For event classes with moderate event activity, RdAu,EXPγdirR_{d\rm Au,EXP}^{\gamma^{\rm dir}} is consistent with the MB value within 5% uncertainty. These results confirm that the previously observed enhancement of high-pTp_Tπ0\pi^0 production found in small-system collisions with low event activity is a result of a bias in interpreting event activity within the Glauber framework. In contrast, for the top 5% of events with the highest event activity, RdAu,EXPγdirR_{d\rm Au,EXP}^{\gamma^{\rm dir}} is suppressed by 20% relative to the MB value with a significance of 4.5σ4.5\sigma, which may be due to final-state effects

    Transverse single-spin asymmetries of midrapidity π0\pi^0 and η\eta mesons in polarized p+pp+p collisions at s=200\sqrt{s}=200 GeV

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    International audienceWe present a measurement of the transverse single-spin asymmetry for π0\pi^0 and η\eta mesons in pp^\uparrow ++ pp collisions in the pseudorapidity range η<0.35|\eta|<0.35 and at a center-of-mass energy of 200 GeV with the PHENIX detector at the Relativistic Heavy Ion Collider. In comparison with previous measurements in this kinematic region, these results have a factor of 3 smaller uncertainties. As hadrons, π0\pi^0 and η\eta mesons are sensitive to both initial- and final-state nonperturbative effects for a mix of parton flavors. Comparisons of the differences in their transverse single-spin asymmetries have the potential to disentangle the possible effects of strangeness, isospin, or mass. These results can constrain the twist-3 trigluon collinear correlation function as well as the gluon Sivers function

    Measurement of ψ(2S)\psi(2S) nuclear modification at backward and forward rapidity in pp++pp, pp++Al, and pp++Au collisions at sNN=200\sqrt{s_{_{NN}}}=200 GeV

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    International audienceSuppression of the J/ψJ/\psi nuclear-modification factor has been seen as a trademark signature of final-state effects in large collision systems for decades. In small systems, the nuclear modification was attributed to cold-nuclear-matter effects until the observation of strong differential suppression of the ψ(2S)\psi(2S) state in p/dp/d ++ AA collisions suggested the presence of final-state effects. Results of J/ψJ/\psi and ψ(2S)\psi(2S) measurements in the dimuon decay channel are presented here for pp ++ pp, pp ++Al, and pp ++Au collision systems at sNN=200\sqrt{s_{_{NN}}}=200 GeV. The results are predominantly shown in the form of the nuclear-modification factor, RpAR_{pA}, the ratio of the ψ(2S)\psi(2S) invariant yield per nucleon-nucleon collision in collisions of proton on target nucleus to that in pp ++ pp collisions. Measurements of the J/ψJ/\psi and ψ(2S)\psi(2S) nuclear-modification factor are compared with shadowing and transport-model predictions, as well as to complementary measurements at Large-Hadron-Collider energies

    Improving constraints on gluon spin-momentum correlations in transversely polarized protons via midrapidity open-heavy-flavor electrons in p+pp^{\uparrow}+p collisions at s=200\sqrt{s}=200 GeV

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    Polarized proton-proton collisions provide leading-order access to gluons, presenting an opportunity to constrain gluon spin-momentum correlations within transversely polarized protons and enhance our understanding of the three-dimensional structure of the proton. Midrapidity open-heavy-flavor production at s=200\sqrt{s}=200 GeV is dominated by gluon-gluon fusion, providing heightened sensitivity to gluon dynamics relative to other production channels. Transverse single-spin asymmetries of electrons and positrons from heavy-flavor hadron decays are measured at midrapidity using the PHENIX detector at the Relativistic Heavy Ion Collider. These charge-separated measurements are sensitive to gluon correlators that can in principle be related to gluon orbital angular momentum via model calculations. Explicit constraints on gluon correlators are extracted for two separate models, one of which had not been constrained previously
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