Phase diagram and magnetocaloric effect of CoMnGe_{1-x}Sn_{x} alloys

We propose the phase diagram of a new pseudo-ternary compound, CoMnGe_{1-x}Sn_{x}, in the range x less than or equal to 0.1. Our phase diagram is a result of magnetic and calometric measurements. We demonstrate the appearance of a hysteretic magnetostructural phase transition in the range x=0.04 to x=0.055, similar to that observed in CoMnGe under hydrostatic pressure. From magnetisation measurements, we show that the isothermal entropy change associated with the magnetostructural transition can be as high as 4.5 J/(K kg) in a field of 1 Tesla. However, the large thermal hysteresis in this transition (~20 K) will limit its straightforward use in a magnetocaloric device.Comment: 12 pages, 5 figure

Reducing extrinsic hysteresis in first-order la (Fe,Co,Si)13 magnetocaloric systems

Reducing extrinsic hysteresis in first-order la (Fe,Co,Si)13 magnetocaloric system

Spontaneous magnetization above TC in polycrystalline La0.7 Ca0.3 MnO3 and La0.7 Ba0.3 MnO3

In the present work, spontaneous magnetization is observed in the inverse magnetic susceptibility of La0.7Ca0.3MnO3 and La0.7Ba0.3MnO3 compounds above TC up to a temperature T*. From information gathered from neutron diffraction, dilatometry, and high-field magnetization data, we suggest that T* is related to the transition temperature of the low-temperature (high magnetic field) magnetic phase. In the temperature region between T* and TC, the application of a magnetic field drives the system from the high-temperature to low-temperature magnetic phases, the latter possessing a higher magnetization. © 2014 American Physical Society

Evaluation of the reliability of the measurement of key magnetocaloric properties: a round robin study of La(Fe,Si,Mn)Hδ conducted by the SSEEC consortium of European laboratories

Managing refrigeration of our homes, our food and our work environments in energy efficient ways is of increasing importance. Refrigeration using solid state magnetic cooling is one of a number of technologies that may make a significant contribution to addressing this problem. In order to develop materials that may enable commercial development of this increasingly relevant field it is important to review the reliability of methods used to extract key physical properties, so that as the field matures the community can develop recognised standards of measurement. Here we measure key physical properties in one composition taken from a series of La(Fe,Si,Mn)Hδ 1:13‐type samples grown by a source laboratory and measured independently in a consortium of European laboratories using both commercial and bespoke facilities

Split transition in ferromagnetic superconductors

The split superconducting transition of up-spin and down-spin electrons on the background of ferromagnetism is studied within the framework of a recent model that describes the coexistence of ferromagnetism and superconductivity induced by magnetic fluctuations. It is shown that one generically expects the two transitions to be close to one another. This conclusion is discussed in relation to experimental results on URhGe. It is also shown that the magnetic Goldstone modes acquire an interesting structure in the superconducting phase, which can be used as an experimental tool to probe the origin of the superconductivity.Comment: REVTeX4, 15 pp, 7 eps fig

Impurity and strain effects on the magnetotransport of La1.85Sr0.15Cu(1-y)Zn(y)O4 films

The influence of zinc doping and strain related effects on the normal state transport properties(the resistivity, the Hall angle and the orbital magneto- resistance(OMR) is studied in a series of La1.85Sr0.15Cu(1-y)Zn(y)O4 films with values of y between 0 and 0.12 and various degrees of strain induced by the mismatch between the films and the substrate. The zinc doping affects only the constant term in the temperature dependence of cotangent theta but the strain affects both the slope and the constant term, while their ratio remains constant.OMR is decreased by zinc doping but is unaffected by strain. The ratio delta rho/(rho*tan^2 theta) is T-independent but decreases with impurity doping. These results put strong constraints on theories of the normal state of high- temperature superconductors

Heat-capacity anomalies at TscT_{sc} and T∗T^{*} in the ferromagnetic superconductor UGe2_2

The heat-capacity and magnetization measurements under high pressure have been carried out in a ferromagnetic superconductor UGe$_2$. Both measurements were done using a same pressure cell in order to obtain both data for one pressure. Contrary to the heat capacity at ambient pressure, an anomaly is found in the heat capacity at the characteristic temperature $T^{*}$ where the magnetization shows an anomalous enhancement under high pressure where the superconductivity appears. This suggests that a thermodynamic phase transition takes place at $T^{*}$ at least under high pressure slightly below $P_{c}^{*}$ where $T^{*}$ becomes zero. The heat-capacity anomaly associated with the superconducting transition is also investigated, where a clear peak of $C/T$ is observed in a narrow pressure region ($\Delta P \sim 0.1$ GPa) around $P_{c}^{*}$ contrary to the previous results of the resistivity measurement. Present results suggest the importance of the thermodynamic critical point $P_{c}^{*}$ for the appearance of the superconductivity.Comment: 4 pages, 4 figures, to appear in Phys. Rev. B, Rapid Communication

Overview of the Characteristic Features of the Magnetic Phase Transition with Regards to the Magnetocaloric Effect: the Hidden Relationship Between Hysteresis and Latent Heat

This article was published in the journal, Metallurgical and Materials Transactions E [Springer / © The Minerals, Metals & Materials Society and ASM International]. The final publication is available at Springer via http://dx.doi.org/10.1007/s40553-014-0015-8The magnetocaloric effect has seen a resurgence in interest over the last 20 years as a means towards an alternative energy efficient cooling method. This has resulted in a concerted effort to develop the so-called “giant” magnetocaloric materials with large entropy changes that often come at the expense of hysteretic behavior. But do the gains offset the disadvantages? In this paper, we review the relationship between the latent heat of several giant magnetocaloric systems and the associated magnetic field hysteresis. We quantify this relationship by the parameter Δμ 0 H/ΔS L, which describes the linear relationship between field hysteresis, Δμ 0 H, and entropy change due to latent heat, ΔS L. The general trends observed in these systems suggest that itinerant magnets appear to consistently show large ΔS L accompanied by small Δμ 0 H (Δμ 0 H/ΔS L = 0.02 ± 0.01 T/(J K−1 kg−1)), compared to local moment systems, which show significantly larger Δμ 0 H as ΔS L increases (Δμ 0 H/ΔS L = 0.14 ± 0.06 T/(J K−1 kg−1))

Optical Sum Rule in Finite Bands

In a single finite electronic band the total optical spectral weight or optical sum carries information on the interactions involved between the charge carriers as well as on their band structure. It varies with temperature as well as with impurity scattering. The single band optical sum also bears some relationship to the charge carrier kinetic energy and, thus, can potentially provide useful information, particularly on its change as the charge carriers go from normal to superconducting state. Here we review the considerable advances that have recently been made in the context of high $T_c$ oxides, both theoretical and experimental.Comment: Review article accepted for publication in J. Low Temp. Phys. 29 pages, 33 figure