Collective Dipole Oscillations in Atomic Nuclei and Small Metal Particles

(The systematics of photon absorption cross sections in nuclei and small metal particles are examined as a function of the number of constituent fermions $A$. It is pointed out that the shell-structure-linked oscillations in the full width at half maximum (FWHM) of the photoneutron cross section in nuclei, earlier recognized for $A > 63$, in fact persist down to the lightest nuclei. Averaging over the oscillations or focusing on the lower envelope of the oscillating curve (magic nuclei), the FWHM is seen to generally decrease with increasing $A$, consistent with $A^{-1/3}$, a dependence which was earlier known to hold in metal particle systems. If the FWHMs are scaled by the respective Fermi energies and the inverse radii by the Fermi wave vectors, the two data sets become comparable in magnitude. A schematic theoretical description of the systematics is presented.)Comment: 21 pages, 2 figs. (not included), TIFR/TH/92-4

Photochemical incorporation of silver quantum dots in monodisperse silica colloids for photonic crystal applications

We developed a novel method to fabricate nanocomposite monodisperse SiO2 spheres (∼ 100 nm) containing homogeneously dispersed Ag quantum dots (2∼5 nm). The inclusion morphology is controlled through the timing of the photochemical reduction of silver ions during hydrolysis of tetraethoxysilane in a microemulsion. Depending on the timing, Ag quantum dots can be directed to different annuli within the SiO2 spheres, as well as onto the SiO2 sphere surfaces. The embedded Ag quantum dots show a plasmon resonance absorption band at 438 nm. These Ag@SiO2 particles have significant surface charge and readily self-assemble into crystalline colloidal array (CCA) photonic crystals which Bragg-diffract light in the visible region. The magnitude of the plasmon resonance absorption depends on the CCA Bragg diffraction condition. The negative dielectric constant of the silver nanoparticles may be decreasing the silica-silver nanodot composite refractive index below that of the water medium. We may be observing an analogue of the Borrmann effect previously observed in X-ray scattering, where the incident and diffracted electric field standing wave becomes localized in regions of small CCA crystal absorption

Organic-soluble antimicrobial silver nanoparticle-polymer composites in gram scale by one-pot synthesis

10.1021/am9005034ACS Applied Materials and Interfaces1112413-241