Nanoscale Quantum Solvation of para-H2_2 around the Linear OCS Molecule inside 4^4He Droplets

We present a microscopic analysis of the quantum solvation structures of para-H$_2$ around the OCS molecule when embedded in low temperature $^4$He droplets. The structures of clusters containing M=5 and 6 para-H$_2$ molecules are compared with corresponding structures for M=1 (OCS-H$_2$ complex) and M=17 (a full solvation shell), as well as with the clusters in the absence of helium. We find that the helium has negligible effect on the structures for the small and large OCS(H$_2$)$_M$ clusters, but that it modifies the cluster structure for M=6. We discuss implications of these results for the onset of superfluidity in the solvating hydrogen shell and for spectroscopic measurements.Comment: 4 pages, 2 figures, accepted for publication in J. Low Temp. Phy

Macroscopicity of quantum superpositions on a one-parameter unitary path in Hilbert space

We analyze quantum states formed as superpositions of an initial pure product state and its image under local unitary evolution, using two measurement-based measures of superposition size: one based on the optimal quantum binary distinguishability of the branches of the superposition and another based on the ratio of the maximal quantum Fisher information of the superposition to that of its branches, i.e., the relative metrological usefulness of the superposition. A general formula for the effective sizes of these states according to the branch distinguishability measure is obtained and applied to superposition states of $N$ quantum harmonic oscillators composed of Gaussian branches. Considering optimal distinguishability of pure states on a time-evolution path leads naturally to a notion of distinguishability time that generalizes the well known orthogonalization times of Mandelstam and Tamm and Margolus and Levitin. We further show that the distinguishability time provides a compact operational expression for the superposition size measure based on the relative quantum Fisher information. By restricting the maximization procedure in the definition of this measure to an appropriate algebra of observables, we show that the superposition size of, e.g., N00N states and hierarchical cat states, can scale linearly with the number of elementary particles comprising the superposition state, implying precision scaling inversely with the total number of photons when these states are employed as probes in quantum parameter estimation of a 1-local Hamiltonian in this algebra

Distinguishability times and asymmetry monotone-based quantum speed limits in the Bloch ball

For both unitary and open qubit dynamics, we compare asymmetry monotone-based bounds on the minimal time required for an initial qubit state to evolve to a final qubit state from which it is probabilistically distinguishable with fixed minimal error probability (i.e., the minimal error distinguishability time). For the case of unitary dynamics generated by a time-independent Hamiltonian, we derive a necessary and sufficient condition on two asymmetry monotones that guarantees that an arbitrary state of a two-level quantum system or a separable state of $N$ two-level quantum systems will unitarily evolve to another state from which it can be distinguished with a fixed minimal error probability $\delta \in [0,1/2]$. This condition is used to order the set of qubit states based on their distinguishability time, and to derive an optimal release time for driven two-level systems such as those that occur, e.g., in the Landau-Zener problem. For the case of non-unitary dynamics, we compare three lower bounds to the distinguishability time, including a new type of lower bound which is formulated in terms of the asymmetry of the uniformly time-twirled initial system-plus-environment state with respect to the generator $H_{SE}$ of the Stinespring isometry corresponding to the dynamics, specifically, in terms of $\Vert [H_{SE},\rho_{\text{av}}(\tau)]\Vert_{1}$, where $\rho_{\text{av}}(\tau):={1\over \tau}\int_{0}^{\tau}dt\, e^{-iH_{SE}t}\rho \otimes \vert 0\rangle_{E}\langle 0\vert_{E} e^{iH_{SE}t}$.Comment: 13 pages, 4 figure