Star Polymers Confined in a Nanoslit: A Simulation Test of Scaling and Self-Consistent Field Theories

The free energy cost of confining a star polymer where $f$ flexible polymer chains containing $N$ monomeric units are tethered to a central unit in a slit with two parallel repulsive walls a distance $D$ apart is considered, for good solvent conditions. Also the parallel and perpendicular components of the gyration radius of the star polymer, and the monomer density profile across the slit are obtained. Theoretical descriptions via Flory theory and scaling treatments are outlined, and compared to numerical self-consistent field calculations (applying the Scheutjens-Fleer lattice theory) and to Molecular Dynamics results for a bead-spring model. It is shown that Flory theory and self-consistent field (SCF) theory yield the correct scaling of the parallel linear dimension of the star with $N$, $f$ and $D$, but cannot be used for estimating the free energy cost reliably. We demonstrate that the same problem occurs already for the confinement of chains in cylindrical tubes. We also briefly discuss the problem of a free or grafted star polymer interacting with a single wall, and show that the dependence of confining force on the functionality of the star is different for a star confined in a nanoslit and a star interacting with a single wall, which is due to the absence of a symmetry plane in the latter case.Comment: 15 pages, 9 figures, LaTeX, to appear in Soft Matte

Compton scattering sequence reconstruction algorithm for the liquid xenon gamma-ray imaging telescope (LXeGRIT)

The Liquid Xenon Gamma-Ray Imaging Telescope (LXeGRIT) is a balloon born experiment sensitive to \g -rays in the energy band of 0.2-20 MeV. The main detector is a time projection chamber filled with high purity liquid xenon (LXeTPC), in which the three-dimensional location and energy deposit of individual \g -ray interactions are accurately measured in one homogeneous volume. To determine the \g -ray initial direction (Compton imaging), as well as to reject background, the correct sequence of interactions has to be determined. Here we report the development and optimization of an algorithm to reconstruct the Compton scattering sequence and show its performance on Monte Carlo events and LXeGRIT data.Comment: To appear in: Hard X-Ray, Gamma-Ray, and Neutron Detector Physics II, 2000; Proc. SPIE, vol. 4141; R.B. James & R.C. Schirato, ed

Spin-dependent electron dynamics and recombination in GaAs(1-x)N(x) alloys at room temperature

We report on both experimental and theoretical study of conduction-electron spin polarization dynamics achieved by pulsed optical pumping at room temperature in GaAs(1-x)N(x) alloys with a small nitrogen content (x = 2.1, 2.7, 3.4%). It is found that the photoluminescence circular polarization determined by the mean spin of free electrons reaches 40-45% and this giant value persists within 2 ns. Simultaneously, the total free-electron spin decays rapidly with the characteristic time ~150 ps. The results are explained by spin-dependent capture of free conduction electrons on deep paramagnetic centers resulting in dynamical polarization of bound electrons. We have developed a nonlinear theory of spin dynamics in the coupled system of spin-polarized free and localized carriers which describes the experimental dependencies, in particular, electron spin quantum beats observed in a transverse magnetic field.Comment: 5 pages, 4 figures, Submitted to JETP Letter

Spectroscopy and Imaging Performance of the Liquid Xenon Gamma-Ray Imaging Telescope (LXeGRIT)

LXeGRIT is a balloon-borne Compton telescope based on a liquid xenon time projection chamber (LXeTPC) for imaging cosmic \g-rays in the energy band of 0.2-20 MeV. The detector, with 400 cm$^2$ area and 7 cm drift gap, is filled with high purity LXe. Both ionization and scintillation light signals are detected to measure the energy deposits and the three spatial coordinates of individual \g -ray interactions within the sensitive volume. The TPC has been characterized with repeated measurements of its spectral and Compton imaging response to \g -rays from radioactive sources such as \na, \cs, \yt and Am-Be. The detector shows a linear response to \g -rays in the energy range 511 keV -4.4 MeV, with an energy resolution (FWHM) of \Delta E/E=8.8% \: \sqrt{1\MeV /E}. Compton imaging of \yt \g -ray events with two detected interactions is consistent with an angular resolution of $\sim$ 3 degrees (RMS) at 1.8 MeV.Comment: To appear in: Hard X-Ray, Gamma-Ray and Neutron Detector Physics XI, 2000; Proc. SPIE, vol. 4140; K.A. Flanagan & O.H. Siegmund, ed

Search for Sterile Neutrinos with a Radioactive Source at Daya Bay

The far site detector complex of the Daya Bay reactor experiment is proposed as a location to search for sterile neutrinos with > eV mass. Antineutrinos from a 500 kCi 144Ce-144Pr beta-decay source (DeltaQ=2.996 MeV) would be detected by four identical 20-ton antineutrino targets. The site layout allows flexible source placement; several specific source locations are discussed. In one year, the 3+1 sterile neutrino hypothesis can be tested at essentially the full suggested range of the parameters Delta m^2_{new} and sin^22theta_{new} (90% C.L.). The backgrounds from six nuclear reactors at >1.6 km distance are shown to be manageable. Advantages of performing the experiment at the Daya Bay far site are described