Simulating a White Dwarf-dominated Galactic Halo

Observational evidence has suggested the possibility of a Galactic halo which is dominated by white dwarfs (WDs). While debate continues concerning the interpretation of this evidence, it is clear that an initial mass function (IMF) biased heavily toward WD precursors (1 < m/Msol < 8), at least in the early Universe, would be necessary in generating such a halo. Within the framework of homogeneous, closed-box models of Galaxy formation, such biased IMFs lead to an unavoidable overproduction of carbon and nitrogen relative to oxygen (as measured against the abundance patterns in the oldest stars of the Milky Way). Using a three-dimensional Tree N-body smoothed particle hydrodynamics code, we study the dynamics and chemical evolution of a galaxy with different IMFs. Both invariant and metallicity-dependent IMFs are considered. Our variable IMF model invokes a WD-precursor-dominated IMF for metallicities less than 5% solar (primarily the Galactic halo), and the canonical Salpeter IMF otherwise (primarily the disk). Halo WD density distributions and C,N/O abundance patterns are presented. While Galactic haloes comprised of ~5% (by mass) of WDs are not supported by our simulations, mass fractions of ~1-2% cannot be ruled out. This conclusion is consistent with the present-day observational constraints.Comment: accepted for publication in MNRA

Volatiles in interplanetary dust particles and aerogels

Volatiles measured in 25 interplanetary dust particles (IDPs) are a mixture of both indigenous materials and contaminants associated with the collection and processing of the ODPs prior to analysis. Most IDPs have been collected in the stratosphere using a silicone oil/freon mixture (20:1 ratio) coated on collector plates. Studies have shown that silicone oil, freon and hexane residues remain with the ODPs, despite attempts to clean the IDPs. Analysis of the IDPs with the LMMS-technique produces spectra with a mixture of indigeneous and contaminants components. The contamination signal can be identified and removed; however, the contamination signal may obscure some of the indigeneous component's signal. Employing spectra stripping techniques, the indigenous volatile constituents associated with the IDPs can be identified. Volatiles are similar to those measured in CI or CM carbonaceous chondrites. Collection of IDPs in low-Earth orbit utilizing a Cosmic Dust Collection Facility attached to Space Station Freedom has been proposed. The low-density material aerogel has been proposed as a collection substrate for IDPs. Our studies have concentrated on identifying volatile contaminants that are associated with aerogel. We have found that solvents used for the preparation of aerogel remain in aerogel and methods must be developed for removing the entrapped solvents before aerogels can be used for an IDP collection substrate

Galactic Archaeology and Minimum Spanning Trees

Chemical tagging of stellar debris from disrupted open clusters and associations underpins the science cases for next-generation multi-object spectroscopic surveys. As part of the Galactic Archaeology project TraCD (Tracking Cluster Debris), a preliminary attempt at reconstructing the birth clouds of now phase-mixed thin disk debris is undertaken using a parametric minimum spanning tree (MST) approach. Empirically-motivated chemical abundance pattern uncertainties (for a 10-dimensional chemistry-space) are applied to NBODY6-realised stellar associations dissolved into a background sea of field stars, all evolving in a Milky Way potential. We demonstrate that significant population reconstruction degeneracies appear when the abundance uncertainties approach 0.1 dex and the parameterised MST approach is employed; more sophisticated methodologies will be required to ameliorate these degeneracies.Comment: To appear in "Multi-Object Spectroscopy in the Next Decade: Big Questions, Large Surveys and Wide Fields"; Held: Santa Cruz de La Palma, Canary Islands, Spain, 2-6 Mar 2015; ed. I Skillen & S. Trager; ASP Conference Series (Figures now optimised for B&W printing

Weighing the galactic disc using the Jeans equation: lessons from simulations

Using three-dimensional stellar kinematic data from simulated galaxies, we examine the efficacy of a Jeans equation analysis in reconstructing the total disk surface density, including the dark matter, at the ‘Solar’ radius. Our simulation data set includes galaxies formed in a cosmological context using state-of-the-art high-resolution cosmological zoom simulations, and other idealized models. The cosmologically formed galaxies have been demonstrated to lie on many of the observed scaling relations for late-type spirals, and thus offer an interesting surrogate for real galaxies with the obvious advantage that all the kinematical data are known perfectly. We show that the vertical velocity dispersion is typically the dominant kinematic quantity in the analysis, and that the traditional method of using only the vertical force is reasonably effective at low heights above the disk plane. At higher heights the inclusion of the radial force becomes increasingly important. We also show that the method is sensitive to uncertainties in the measured disk parameters, particularly the scalelengths of the assumed double exponential density distribution, and the scalelength of the radial velocity dispersion. In addition, we show that disk structure and low number statistics can lead to significant errors in the calculated surface densities. Finally, we examine the implications of our results for previous studies of this sort, suggesting that more accurate measurements of the scalelengths may help reconcile conflicting estimates of the local dark matter density in the literature

Are Antidepressants Overprescribed? Patients’ Experiences of the Prescribing Process

An online survey was completed by 1829 New Zealand adults prescribed antidepressants. Only 43% were experiencing self-reported “severe” depression when first prescribed antidepressants. Thus, most prescriptions were for depression that was self-reported as mild or moderate, despite studies suggesting that antidepressants are no more effective than placebo at these levels. General practitioners (GPs) prescribed at lower depression levels than psychiatrists and spent less time with patients. 35% of GPs and 42% of psychiatrists reportedly gave no information about adverse effects. Almost no prescribers gave information about adverse effects in the personal and interpersonal domains, or about withdrawal effects. Closer adherence to evidence-based prescribing and to the principle of informed consent may lead to a reduction in unnecessary, ineffective, and potentially harmful prescribing

A Model for Star Formation, Gas Flows and Chemical Evolution in Galaxies at High Redshifts

Motivated by the increasing use of the Kennicutt-Schmidt (K-S) star formation law to interpret observations of high redshift galaxies, the importance of gas accretion to galaxy formation, and the recent observations of chemical abundances in galaxies at z~2-3, I use simple analytical models to assess the consistency of these processes of galaxy evolution with observations and with each other. I derive the time dependence of star formation implied by the K-S law, and show that the sustained high star formation rates observed in galaxies at z~2-3 require the accretion of additional gas. A model in which the gas accretion rate is approximately equal to the combined star formation and outflow rates broadly reproduces the observed trends of star formation rate with galaxy age. Using an analytical description of chemical evolution, I also show that this model, further constrained to have an outflow rate roughly equal to the star formation rate, reproduces the observed mass-metallicity relation at z~2.Comment: 7 pages, 3 figures. Accepted for publication in Ap

On the Physical Origin of OVI Absorption-Line Systems

We present a unified analysis of the O{\sc vi} absorption-lines seen in the disk and halo of the Milky Way, high velocity clouds, the Magellanic Clouds, starburst galaxies, and the intergalactic medium. We show that these disparate systems define a simple relationship between the O{\sc vi} column density and absorption-line width that is independent of the Oxygen abundance over the range O/H $\sim$ 10% to twice solar. We show that this relation is exactly that predicted theoretically as a radiatively cooling flow of hot gas passes through the coronal temperature regime - independent of its density or metallicity (for O/H $\gtrsim$ 0.1 solar). Since most of the intregalactic O{\sc vi} clouds obey this relation, we infer that they can not have metallicities less than a few percent solar. In order to be able to cool radiatively in less than a Hubble time, the intergalactic clouds must be smaller than $\sim$1 Mpc in size. We show that the cooling column densities for the O{\sc iv}, O{\sc v}, Ne{\sc v}, and Ne{\sc vi} ions are comparable to those seen in O{\sc vi}. This is also true for the Li-like ions Ne{\sc viii}, Mg{\sc x}, and Si{\sc xii} (if the gas is cooling from $T \gtrsim 10^6$ K). All these ions have strong resonance lines in the extreme-ultraviolet spectral range, and would be accessible to $FUSE$ at $z \gtrsim$ 0.2 to 0.8. We also show that the Li-like ions can be used to probe radiatively cooling gas at temperatures an order-of-magnitude higher than where their ionic fraction peaks. We calculate that the H-like (He-like) O, Ne, Mg, Si, and S ions have cooling columns of $\sim10^{17}$ cm$^{-2}$. The O{\sc vii}, O{\sc viii}, and Ne{\sc ix} X-ray absorption-lines towards PKS 2155-304 may arise in radiatively cooling gas in the Galactic disk or halo.Comment: 25 pages, 5 figure

CO2 conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes.

Uranium(vi) trans-bis(imido) complexes [U(κ4-{(tBu2ArO)2Me2-cyclam})(NPh)(NPhR)] react with CO2 to eliminate phenyl isocyanates and afford uranium(vi) trans-[O[double bond, length as m-dash]U[double bond, length as m-dash]NR]2+ complexes, including [U(κ4-{(tBu2ArO)2Me2-cyclam})(NPh)(O)] that was crystallographically characterized. DFT studies indicate that the reaction proceeds by endergonic formation of a cycloaddition intermediate; the secondary reaction to form a dioxo uranyl complex is both thermodynamically and kinetically hindered