UV-enhanced sacrificial layer stabilised graphene oxide hollow fibre membranes for nanofiltration

Graphene oxide (GO) membranes have demonstrated great potential in gas separation and liquid filtration. For upscale applications, GO membranes in a hollow fibre geometry are of particular interest due to the high-efficiency and easy-assembly features at module level. However, GO membranes were found unstable in dry state on ceramic hollow fibre substrates, mainly due to the drying-related shrinkage, which has limited the applications and post-treatments of GO membranes. We demonstrate here that GO hollow fibre membranes can be stabilised by using a porous poly(methyl methacrylate) (PMMA) sacrificial layer, which creates a space between the hollow fibre substrate and the GO membrane thus allowing stress-free shrinkage. Defect-free GO hollow fibre membrane was successfully determined and the membrane was stable in a long term (1200 hours) gas-tight stability test. Post-treatment of the GO membranes with UV light was also successfully accomplished in air, which induced the creation of controlled microstructural defects in the membrane and increased the roughness factor of the membrane surface. The permeability of the UV-treated GO membranes was greatly enhanced from 0.07 to 2.8 L m(−2) h(−1) bar(−1) for water, and 0.14 to 7.5 L m(−2) h(−1) bar(−1) for acetone, with an unchanged low molecular weight cut off (~250 Da)

Perceived usefulness of expert systems for MBA advisement: A discriminant model

Based on questionnaire data collected from 123 AACSB-accredited business schools, a discriminant model was developed to generate a descriptive profile of MBA Advisors in regard to their perceived usefulness of expert systems (ESs) for advising MBA students. Characteristics related to organization, advisee, advisor, and job/task structures were considered in formulating the model. Stepwise discriminant analysis resulted in 8 out of 15 independent variables entering the model

Multiscale Technicolor and the Zbb-bar Vertex

We estimate the correction to the Zbb-bar vertex arising from the exchanges of the sideways extended technicolor (ETC) boson and the flavor-diagonal ETC boson in the multiscale walking technicolor model. The obtained result is too large to explain the present data. However, if we introduce a new self- interaction for the top quark to induce the top quark condensate serving as the origin of the large top quark mass, the corrected R_b=Gamma_b/Gamma_h can be consistent with the recent LEP data. The corresponding correction to R_c=Gamma_c/Gamma_h is shown to be negligibly small.Comment: 9-page LaTex fil

A detailed postprocess analysis of an argon gas puff Z-pinch plasma using SPEC2D

A postprocess analysis of a single time frame hydrodynamic profile from the PRISM two-dimensional MHD simulation of an argon gas puff Z-pinch plasma experiment on Double-Eagle generator at Physics Internationals, Co. is presented. In addition, spatially resolved emission spectra and filtered (K- and L-shell radiation) x-ray pinhole images, generated using the SPEC2D code, are examined toward the understanding of the emission characteristics of the hot spots and the formation of the Rayleigh-Taylor instability in the plasma. © 1997 American Institute of Physics.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/87687/2/283_1.pd

AXSTRAN: A non-LTE radiation transport and ionization dynamics code in axisymmetric two-dimensional geometry

A description of AXSTRAN, a fully coupled time-dependent non-LTE radiation ionization dynamics code with the nonlocal opacity effects and the radiation transport for axisymmetric 2-D geometry, is presented. A demonstration of the capability of the code is made through an examination of the radiation field and the ionization state in a finite uniform argon Z-pinch plasma. © 1997 American Institute of Physics.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/87686/2/277_1.pd

Improvement of dielectric loss of doped Ba0.5Sr0.5TiO3 thin films for tunable microwave devices

Al2O3-Ba0.5Sr0.5TiO3 (Al2O3-BST) thin films, with different Al2O3 contents, were deposited on (100) LaAlO3 substrate by pulsed laser deposition (PLD) technique. The Al2O3-BST films was demosnstrated to be a suitable systems to fabricate ferroelectric thin films with low dielectric loss and higher figure of merit for tunable microwave devices. Pure BST thin films were also fabricated for comparison purpose. The films' structure and morphology were analyzed by X-ray diffractiopn and scanning electron microscopy, respectively; nad showed that the surface roughness for the Al2O3-BST films increased with the Al2O3 content. Apart from that, the broadening in the intensity peak in XRD result indicating the grain size of the Al2O3-BST films reduced with the increasing of Al2O3 dopant. We measured the dielctric properties of Al2O3-BST films with a home-made non-destructive dual resonator method at frequency ~ 7.7 GHZ. The effect of doped Al2O3 into BST thin films significantly reduced the dielectric constant, dielectric loss and tunability compare to pure BST thin film. Our result shows the figure of merit (K), used to compare the films with varied dielectric properties, increased with the Al2O3 content. Therefore Al2O3-BST films show the potential to be exploited in tunable microwave devices.Comment: 8 pages, 4 figures, 1 table. Accepted & tentatively for Feb 15 2004 issue, Journal of Applied Physic

Characterizing anomalies in distributed strain measurements of cast-in-situ bored piles

This paper describes the method of identifying typical defects of bored cast-in-situ piles when instrumenting using Distributed Optical Fiber Strain Sensing (DOFSS). The DOFSS technology is based on Brillouin Optical Time Domain Analyses (BOTDA), which has the advantage of recording continuous strain profile as opposed to the conventional discrete based sensors such as Vibrating Wire strain gauges. In pile instrumentation particularly, obtaining distributed strain profile is important when analysing the load-transfer and shaft friction of a pile, as well as detecting any anomalies in the strain regime. Features such as defective pile shaft necking, discontinuity of concrete, intrusion of foreign matter and improper toe formation due to contamination of concrete at base with soil particles, among others, may cause the pile to fail. In this study, a new technique of detecting such defects is proposed using DOFSS technology which can potentially supplement the existing non-destructive test (NDT) methods. Discussion on the performance of instrumented piles by means of maintained load test are also presented

Mode-coupling theory for structural and conformational dynamics of polymer melts

A mode-coupling theory for dense polymeric systems is developed which unifyingly incorporates the segmental cage effect relevant for structural slowing down and polymer chain conformational degrees of freedom. An ideal glass transition of polymer melts is predicted which becomes molecular-weight independent for large molecules. The theory provides a microscopic justification for the use of the Rouse theory in polymer melts, and the results for Rouse-mode correlators and mean-squared displacements are in good agreement with computer simulation results.Comment: 4 pages, 3 figures, Phys. Rev. Lett. in pres