Experimental band structure of the nearly half-metallic CuCr2_2Se4_4: An optical and magneto-optical study

Diagonal and off-diagonal optical conductivity spectra have been determined form the measured reflectivity and magneto-optical Kerr effect (MOKE) over a broad range of photon energy in the itinerant ferromagnetic phase of CuCr$_2$Se$_4$ at various temperatures down to T=10 K. Besides the low-energy metallic contribution and the lower-lying charge transfer transition at $E$$\approx$2 eV, a sharp and distinct optical transition was observed in the mid-infrared region around $E$$=$0.5 eV with huge magneto-optical activity. This excitation is attributed to a parity allowed transition through the Se-Cr hybridization-induced gap in the majority spin channel. The large off-diagonal conductivity is explained by the high spin polarization in the vicinity of the Fermi level and the strong spin-orbit interaction for the related charge carriers. The results are discussed in connection with band structure calculations

Coexistence of localized and itinerant electrons in BaFe2X3 (X = S and Se) revealed by photoemission spectroscopy

We report a photoemission study at room temperature on BaFe2X3 (X = S and Se) and CsFe2Se3 in which two-leg ladders are formed by the Fe sites. The Fe 2p core-level peaks of BaFe2X3 are broad and exhibit two components, indicating that itinerant and localized Fe 3d sites coexist similar to KxFe2-ySe2. The Fe 2p core-level peak of CsFe2Se3 is rather sharp and is accompanied by a charge-transfer satellite. The insulating ground state of CsFe2Se3 can be viewed as a Fe2+ Mott insulator in spite of the formal valence of +2.5. The itinerant versus localized behaviors can be associated with the stability of chalcogen p holes in the two-leg ladder structure.Comment: 5 pages, 5 figures, Accepted in publication for Physical Review

Pressure-induced changes in the magnetic and valence state of EuFe2As2

We present the results of electrical resistivity, ac specific heat, magnetic susceptibility, X-ray absorption spectroscopy (XAS) and X-ray magnetic circular dichroism (XMCD) of the ternary iron arsenide EuFe2As2 single crystal under pressure. Applying pressure leads to a continuous suppression of the antiferromagnetism associated with Fe moments and the antiferromagnetic transition temperature becomes zero in the vicinity of a critical pressure Pc ~2.5-2.7 GPa. Pressure-induced re-entrant superconductivity, which is highly sensitive to the homogeneity of the pressure, only appears in the narrow pressure region in the vicinity of Pc due to the competition between superconductivity and the antiferromagnetic ordering of Eu2+ moments. The antiferromagnetic state of Eu2+ moments changes to the ferromagnetic state above 6 GPa. We also found that the ferromagnetic order is suppressed with further increasing pressure, which is connected with a valence change of Eu ions.Comment: 7 pages, 7 figures, accepted for publication in Phys. Rev.

Anomalous Hall effect as a probe of the chiral order in spin glasses

Anomalous Hall effect arising from the noncoplanar spin configuration (chirality) is discussed as a probe of the chiral order in spin glasses. It is shown that the Hall coefficient yields direct information about the linear and nonlinear chiral susceptibilities of the spin sector, which has been hard to obtain experimentally from the standard magnetic measurements. Based on the chirality scenario of spin-glass transition, predictions are given on the behavior of the Hall resistivity of canonical spin glasses.Comment: Order estimate of the effect given, one reference added. To appear in Phys. Rev. Letter

Spin Chirality Fluctuation and Anomalous Hall Effect in Itinerant Ferromagnets

The anomalous Hall effect due to the spin chirality order and fluctuation is studied theoretically in a Kondo lattice model without the relativistic spin-orbit interaction. Even without the correlations of the localized spins, $\sigma_{xy}$ can emerge depending on the lattice structure and the spin anisotropy. We reveal the condition for this chirality-fluctuation driven mechanism for $\sigma_{xy}$. Our semiquantitative estimates for a pyrochlore oxide Nd$_2$Mo$_2$O$_7$ give a finite \sigma_{xy} \sim 10 \Ohm^{-1} \cm^{-1} together with a high resistivity \rho_{xx} \sim 10^{-4}-10^{-3} \Ohm \cm, in agreement with experiments.Comment: 5 pages, including 4 figure

Parity-broken ground state for the spin-1 pyrochlore antiferromagnet

The ground-state properties of the spin-1 pyrochlore antiferromagnet are studied by applying the VBS-like tetrahedron-unit decomposition to the original spin system. The symmetrization required on every vertex is taken into account by introducing a ferromagnetic coupling. The pairwise effective Hamiltonian between the adjacent tetrahedrons is obtained by considering the next nearest neighbor and the third neighbor exchange interactions. We find that the transverse component of the spin chirality exhibits a long-range order, breaking the parity symmetry of the tetrahedral group, while the chirality itself is not broken.Comment: 4 pages, 3 figures, REVTeX(ver.3.1