46 research outputs found
Securing multi-tenancy systems through multi DB instances and multiple databases on different physical servers
Use of the same application by multiple users through internet as a service is supported by cloud computing system. Both the user and attacker stay in the same machine as both of them are users of the same application creating an in-secure environment. Service must ensure secrecy both at the application and data layer level. Data isolation and Application isolation are two basic aspects that must be ensured to cater for security as desired by the clients that accesses the service. In this paper a more secured mechanism has been presented that help ensuring data isolation and security when Multi-tenancy of the users to the same service has been implemented
Ferroelectric Properties and Transmission Response ofPZN-PT Single Crystals for Underwater Communication
Single crystal of Pb[(Zn1/3Nb2/3)0.91Ti0.09]O3 (PZN-PT) at the composition of morphotropicphase boundary (MPB) shows a very high electromechanical coupling coefficient, piezoelectriccoefficient, and dielectric constant compared to conventional PZT ceramics. These exceptionalproperties of these single crystals find enormous applications in medical ultrasound imaging andunderwater communication (Sonar). The growth of PZN-PT single crystals has been carried outby bottom-supported flux Bridgman method. There are many growth issues to be addressedduring the process of growth. The grown crystals are oriented and cut along <001> directionwith the crystal dimension of 8 x 6 x 1.5 mm3 for further analysis. The oriented crystals were poledat a rate of 1 kV/mm. The poled crystals have been characterised for dielectric, strain andpiezoelectric values. Further, the poled specimen were tested for transmitting response at variousfrequencies in acoustic test facility and the difficulties in their growth
Development of eAgromet Prototype to Improve the Performance of Integrated Agromet Advisory Service
In several countries, the systems for forecasting weather are being operated to deal with weather and its related factors affecting agricultural production. India meteorological department (IMD) is providing several types of weather forecasts. One of the forecast service is medium range forecast (MRF). As a part of MRF, the expected values of rain fall, temperature, cloud cover, humidity, wind speed and wind direction for next five days are forecasted twice a week by considering district as a unit. Agriculture is markedly affected by weather condition during crop season. IMD in collaboration with Indian Council of Agriculture Research (ICAR) and State Agriculture Universities (SAUs) has set-up about 130 Agro-meteorological Field Units (AMFUs) and each AMFU covers about five districts. Based on MRF, IMD is rendering Integrated Agromet Advisory Service to the farming community of the country in the form of agromet advisory bulletin. The agromet advisory bulletins contain possible risk mitigation measures for the major crops and livestock. Based on the weather forecast, a group of interdisciplinary scientists and agromet scientists at AMFU prepare district-level agromet advisory bulletins. These bulletins are sent to the farmers and other stakeholders of the corresponding district. To ease the process of preparing agromet bulletins, an effort has started to build IT-based agrometeorological advisory system called, eAgromet. In this paper, we explain the concepts of eAgromet and its operation
Clinical Use and Therapeutic Potential of IVIG/SCIG, Plasma-Derived IgA or IgM, and Other Alternative Immunoglobulin Preparations
Intravenous and subcutaneous immunoglobulin preparations, consisting of IgG class antibodies, are increasingly used to treat a broad range of pathological conditions, including humoral immune deficiencies, as well as acute and chronic inflammatory or autoimmune disorders. A plethora of Fab- or Fc-mediated immune regulatory mechanisms has been described that might act separately or in concert, depending on pathogenesis or stage of clinical condition. Attempts have been undertaken to improve the efficacy of polyclonal IgG preparations, including the identification of relevant subfractions, mild chemical modification of molecules, or modification of carbohydrate side chains. Furthermore, plasma-derived IgA or IgM preparations may exhibit characteristics that might be exploited therapeutically. The need for improved treatment strategies without increase in plasma demand is a goal and might be achieved by more optimal use of plasma-derived proteins, including the IgA and the IgM fractions. This article provides an overview on the current knowledge and future strategies to improve the efficacy of regular IgG preparations and discusses the potential of human plasma-derived IgA, IgM, and preparations composed of mixtures of IgG, IgA, and IgM
Synthesis of PAN nanoparticles via nonconventional microemulsion technique using Co(II)/EDTA in situ complex
119-125Synthesis of polyacrylonitrile nanoparticles was carried out under the catalytic effect of in situ developed Co(II)/EDTA complex with ammonium persulphate as initiator, in the absence of added emulsifier. The microemulsion polymerization was studied at varying concentrations of initiator, monomer, complex and solvent over a temperature range of 30-70ºC. The overall activation energy (Ea, 49.79 kJ/mol), energy of dissociation of initiator (Ed, 82.68 kJ/mol), number of micelles
(0.163 x 1018) and the viscosity average molecular weight of the polymer were computed. The distribution of particle sizes was determined by transmission electron microscopy (TEM). It was found that the oil-in-water polymerization was stabilized by the presence of the CoCl₂/EDTA in situ complex reducing the particle size into nano order. The average diameters of PAN nano particles, obtained by TEM, were in the range of 50-150 nm at maximum conversion. The experimental particle size was mainly dependent on the concentration of complex and temperature
Microwave-Assisted Preparation of Biodegradable Water Absorbent Polyacrylonitrile/Montmorillonite Clay Nanocomposite
Polyacrylonitrile (PAN)/Montmorillonite (MMT) clay nanocomposite was prepared in a microwave oven using a transition metal Co(III) complex taking ammonium persulfate (APS) as initiator with a motive of converting hydrophobic PAN into hydrophilic nanocomposite material via nanotechnology by the inclusion of MMT to the virgin polymer. UV-visible spectral analysis revealed various interactions between the developed complex with other reaction components. The formation of the PAN/MMT nanocomposites was characterized by FTIR. Furthermore, as evidenced by X-ray diffraction (XRD), transmission electron microscopy (TEM), the composite so obtained was found to have nano-order. XRD and TEM were suggesting that montmorillonite layers were exfoliated during the polymerization process. An increasing in the thermal stability for the developed nanocomposite was recorded by thermogravimetric analysis (TGA). The water absorption and biodegradation properties were carried out for its ecofriendly nature and better commercialization
Complex-mediated microwave-assisted synthesis of polyacrylonitrile nanoparticles
Trinath Biswal, Ramakanta Samal, Prafulla K SahooDepartment of Chemistry, Utkal University, Vani Vihar, Bhubaneswar 751004, IndiaAbstract: The polymerization of acrylonitrile (AN) is efficiently, easily, and quickly achieved in the presence of trans-[Co(III)en2Cl2]Cl complex in a domestic microwave (MW) oven. MW irradiation notably promoted the polymerization reaction; this phenomenon is ascribed to the acceleration of the initiator, ammonium persulfate (APS), decomposition by microwave irradiation in the presence of [Co(III)en2Cl2]Cl. The conversion of monomer to the polymer was mostly excellent in gram scale. Irradiation at low power and time produced more homogeneous polymers with high molecular weight and low polydispersity when compared with the polymer formed by a conventional heating method. The interaction of reacting components was monitored by UV-visible spectrometer. The average molecular weight was derived by gel permeation chromatography (GPC), viscosity methods, and sound velocity by ultrasonic interferometer. The uniform and reduced molecular size was characterized by transmission electron microscopy, the diameter of polyacrylonitrile nanoparticles (PAN) being in the range 50&ndash;115 nm and 40&ndash;230 nm in microwave and conventional heating methods respectively. The surface morphology of PAN prepared by MW irradiation was characterized by scanning electron microscope (SEM). From the kinetic results, the rate of polymerization (Rp) was expressed as Rp = [AN]0.63 [APS]0.57 [complex (I)].0.88Keywords: microwave, complex catalyst, nanoparticle, kinetic
Spectrophotometric determination of meloxicam by sodium nitroprusside and 1,10-phenanthroline reagents in bulk and its pharmaceutical formulation
111-115Two simple and selective spectrophotometric
methods have been developed for the quantitative determination of meloxicam in
pure form and in pharmaceutical formulations. The first method is based on the
electron transfer reaction of drug with sodium nitroprusside in presence of hydroxyl
amine HCl and the absorption maxima is recorded at 363 nm (Method A). Second
method is based on the formation of a complex of drug with ferric chloride and
followed by coupling with 1,10-phenanthroline, and the absorption maximum is
recorded at 343 nm (Method B). Both the methods follow Beer’s range in the
concentration range 4-20 μg mL-1 and 10-50 μg mL-1 for
Methods A and B respectively. Good correlation coefficients (0.9955-0.9973) are
observed between absorbance and corresponding concentrations of the drug. The
calculated apparent molar absorptivity values are found to be 0.6079 × 10-4 and 0.4849 × 10-4
mol-1cm-1 for the Methods A and B
respectively. The limits of detection and quantification are also reported for
both spectrophotometric methods. Intra-day & inter-day precisions and the
accuracy of the methods have also been evaluated. No interference is observed
from common pharmaceutical adjutants. The reliability of the methods is further
ascertained by performing recovery tests by standard addition method.
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