Effect of conducting additives on the properties of composite cathodes for lithium-ion batteries

In an attempt to achieve lithium-ion batteries with high rate capability, the effect of conducting additives with various shapes and contents on the physical and electrochemical performances was evaluated. Although the density of the cathode decreased upon the addition of the additives, the electrical conductivity and electrochemical performance were greatly improved. The composite cathodes with well-dispersed multi-walled carbon nanotubes (MWCNTs) exhibited excellent high rate capabilities and cyclabilities. In the case of cathode with 8 wt.% of MWCNTs (low density-LD), the highest discharge capacity of 136 mAh/g was obtained at 5 C-rate and capacity retention of 97% for 50 cycles was observed at 1 C-rate of discharge. The cathode with a mixture of 2 wt.% of Super P and 4 wt.% of MWCNTs (LD) also exhibits improved cycle performances. The volume changes in the charge and discharge processes were successfully controlled by the bundles distributed between the host particles.close8

Effect of MWCNT on the performances of the rounded shape natural graphite as anode material for lithium-ion batteries

Multi-walled carbon nanotube (MWCNT) with bundle-type morphology was introduced as a new functional additive working as a particle connector or an expansion absorber in the anodes of lithium-ion batteries. By controlling the dispersion process, the MWCNT bundles were successfully divided and dispersed between the host particles. The composite anode consisting of rounded shape natural graphite and 2 wt.% of MWCNT exhibited the capacity of 300 mAh g -1 at 3 C rate and excellent cyclability. The well-dispersed MWCNT bundles made it possible to relieve the large strains developed at high discharge C rates and to keep the electrical contact between the host particles during repeated intercalation/deintercalation. This study has also emphasized that when high C-rate applications of lithium-ion batteries are targeted, it is important to get optimum content of MWCNT as well as uniform dispersion of their bundles in the composite anodes.close3

Design Progress for the National Ignition Facility Laser Alignment and Beam Diagnostics

Earlier papers have described approaches to NIF alignment and laser diagnostics tasks. 1,2,3 Now, detailed design of alignment and diagnostic systems for the National Ignition Facility (NIF) laser is in its last year. Specifications are more detailed, additional analyses have been completed, Pro-E models have been developed, and prototypes of specific items have been built. In this paper we update top level concepts, illustrate specific areas of progress, and show design implementations as represented by prototype hardware. The alignment light source network has been fully defined. It utilizes an optimized number of lasers combined with fiber optic distribution to provide the chain alignment beams, system centering references, final spatial filter pinhole references, target alignment beams, and wavefront reference beams. The input and output sensors are being prototyped. They are located respectively in the front end just before beam injection into the full aperture chain and at the transport spatial filter, where the full energy infrared beam leaves the laser. The modularity of the input sensor is improved, and each output sensor mechanical package now incorporates instrumentation for four beams. Additional prototype hardware has been tested for function, and lifetime tests are underway. We report some initial results