112 research outputs found
MnSi nanoparticles embedded in Si: Superparamagnetism with a collective behavior
The doping of Mn in Si is attracting research attentions due to the
possibility to fabricate Si-based diluted magnetic semiconductors. However, the
low solubility of Mn in Si favors the precipitation of Mn ions even at
non-equilibrium growth conditions. MnSi nanoparticles are the common
precipitates, which show exotic magnetic properties in comparison with the
MnSi bulk phase. In this paper we present the static and dynamic
magnetic properties of MnSi nanoparticles. Using the Preisach model, we
derive the magnetic parameters, such as the magnetization of individual
particles, the distribution of coercive fields and the inter-particle
interaction field. Time-dependent magnetization measurements reveal a
spin-glass behavior of the system.Comment: 11 pages, 6 figures, submitted to PR
Absence of ferromagnetism in V-implanted ZnO single crystals
The structural and magnetic properties of V doped ZnO are presented. V ions
were introduced into hydrothermal ZnO single crystals by ion implantation with
fluences of 1.2*10^16 to 6*10^16 cm^-2. Post-implantation annealing was
performed in high vacuum from 823 K to 1023 K. The ZnO host material still
partly remains in a crystalline state after irradiation, and is partly
recovered by annealing. The V ions show a thermal mobility as revealed by depth
profile Auger electron spectroscopy. Synchrotron radiation x-ray diffraction
revealed no secondary phase formation which indicates the substitution of V
onto Zn site. However in all samples no pronounced ferromagnetism was observed
down to 5 K by a superconducting quantum interference device magnetometer.Comment: 13 pages, 4 figs, MMM conference 2007, accepted by J. Appl. Phy
Origin of magnetic moments in defective TiO2 single crystals
In this paper we show that ferromagnetism can be induced in pure TiO2 single
crystals by oxygen ion irradiation. By combining x-ray diffraction,
Raman-scattering, and electron spin resonance spectroscopy, a defect complex,
\emph{i.e.} Ti ions on the substitutional sites accompanied by oxygen
vacancies, has been identified in irradiated TiO2. This kind of defect complex
results in a local (TiO) stretching Raman mode. We elucidate that
Ti ions with one unpaired 3d electron provide the local magnetic
moments.Comment: 4 pages, 4 figures, to be published at Phys. Rev.
Spinel ferrite nanocrystals embedded inside ZnO: magnetic, electronic and magneto-transport properties
In this paper we show that spinel ferrite nanocrystals (NiFe2O4, and CoFe2O4)
can be texturally embedded inside a ZnO matrix by ion implantation and
post-annealing. The two kinds of ferrites show different magnetic properties,
e.g. coercivity and magnetization. Anomalous Hall effect and positive
magnetoresistance have been observed. Our study suggests a
ferrimagnet/semiconductor hybrid system for potential applications in
magneto-electronics. This hybrid system can be tuned by selecting different
transition metal ions (from Mn to Zn) to obtain various magnetic and electronic
properties.Comment: 12 pages, 14 figs. accepted for publication at PR
Crystallographically oriented Co and Ni nanocrystals inside ZnO formed by ion implantation and postannealing
In the last decade, transition-metal-doped ZnO has been intensively
investigated as a route to room-temperature diluted magnetic semiconductors
(DMSs). However, the origin for the reported ferromagnetism in ZnO-based DMS
remains questionable. Possible options are diluted magnetic semiconductors,
spinodal decomposition, or secondary phases. In order to clarify this question,
we have performed a thorough characterization of the structural and magnetic
properties of Co- and Ni-implanted ZnO single crystals. Our measurements reveal
that Co or Ni nanocrystals (NCs) are the major contribution of the measured
ferromagnetism. Already in the as-implanted samples, Co or Ni NCs have formed
and they exhibit superparamagnetic properties. The Co or Ni NCs are
crystallographically oriented with respect to the ZnO matrix. Their magnetic
properties, e.g., the anisotropy and the superparamagnetic blocking
temperature, can be tuned by annealing. We discuss the magnetic anisotropy of
Ni NCs embedded in ZnO concerning the strain anisotropy.Comment: 13 pages, 14 figure
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