3,774 research outputs found

    Ethyl 4-hy­droxy-6-(4-hy­droxy­phen­yl)-4-trifluoro­methyl-2-sulfanyl­idene-1,3-diazinane-5-carboxyl­ate ethanol monosolvate

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    The title compound, C14H15F3N2O4S·C2H5OH, was prepared by reaction of 4-hy­droxy­benzaldehyde, ethyl 4,4,4-trifluoro-3-oxobutano­ate and thio­urea. The hexa­hydro­pyrimidine ring adopts a half-chair conformation, the mean plane formed by the ring atoms excluding the C atom bonded to the eth­oxy­carbonyl group has an r.m.s. deviation of 0.0333 Å, and the dihedral angle between this plane and the benzene ring is 56.76 (5)°. The mol­ecular conformation is stabilized by an intra­molecular O—H⋯O hydrogen bond, generating an S(6) ring. The crystal structure is stabilized by inter­molecular O—H⋯O, O—H⋯S, N—H⋯O and N—H⋯S hydrogen bonds. The ethyl group of the ester unit is disordered over two positions, with an occupancy ratio of 0.757 (10):0.243 (10)

    Get Tired of Socializing as Social Animal? An Empirical Explanation on Discontinuous Usage Behavior in Social Network Services

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    This research aims to explain users’ discontinuous usage behavior in social network context. With system features increasing, information flooding and personal network expanding of SNSs, users begin to emerge social network fatigue, and ultimately induce discontinuous usage intention. To explain this phenomenon, we develop a research model based on a cognition-affection-conation framework. This study examines the role of perceived overload (in terms of system feature overload, information overload and social overload) in influencing users’ negative affections of SNSs including social network fatigue and dissatisfaction, and the effects of such emotions on users’ discontinuous intention, which are validated through an empirical survey. The findings of this study contribute to a better understanding of the relationship among perceived overload, social network fatigue and users’ discontinuous usage behavior, and give some implications to SNSs providers to improve this situation

    Quantum logical gates with four-level SQUIDs coupled to a superconducting resonator

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    We propose a way for realizing a two-qubit controlled phase gate with superconducting quantum interference devices (SQUIDs) coupled to a superconducting resonator. In this proposal, the two lowest levels of each SQUID serve as the logical states and two intermediate levels of each SQUID are used for the gate realization. We show that neither adjustment of SQUID level spacings during the gate operation nor uniformity in SQUID parameters is required by this proposal. In addition, this proposal does not require the adiabatic passage or a second-order detuning and thus the gate is much faster.Comment: 6 pages, 3 figure
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