2-Isopropoxyphenyl N-methyl­carbamate

In the title compound, C11H15NO3, the mean planes of the carboxamide and isopropyl groups are inclined at 109.9 (1) and 128.7 (2)°, respectively, to the mean plane of the phen­oxy group. In the crystal structure, mol­ecules are stacked along the b axis, without any π–π inter­actions. The stacked columns are linked together by inter­molecular N—H⋯O hydrogen bonds, with an N⋯O distance of 2.842 (2) Å

Photo-production of lowest Σ1/2−∗\Sigma^*_{1/2^-} state within the Regge-effective Lagrangian approach

Since the lowest $\Sigma^{*}$ state, with quantum numbers spin-parity $J^{P} =1/2^{-}$, is far from established experimentally and theoretically, we have performed a theoretical study on the $\Sigma^*_{1/2^-}$ photo-production within the Regge-effective Lagrangian approach. Taking into account that the $\Sigma^*_{1/2^-}$ couples to the $\bar{K}N$ channel, we have considered the contributions from the $t$-channel $K$ exchange diagram. Moreover, these contributions from $t$-channel $K^*$ exchange, $s$-channel nucleon pole, $u$-channel $\Sigma$ exchange, and the contact term, are considered. The differential and total cross sections of the process $\gamma n \to K^{+}\Sigma^{*-}_{1/2^-}$ are predicted with our model parameters. The results should be helpful to search for the $\Sigma^*_{1/2^-}$ state experimentally in future.Comment: 7 pages, 4 figure

4-(4-Ethoxy­benz­yl)-1,3-oxazolidin-2-one

In the title compound, C12H15NO3, the ethoxy­benzyl ring plane forms a dihedral angle of 60.3 (4)° with the mean plane of the oxazolidine ring. The mol­ecules are linked through N—H⋯O hydrogen bonds into a chain running in the b direction

Dimethyl 2-nitro­terephthalate

In the mol­ecule of the title compound, C10H9NO6, the two ester groups and the nitro group are inclined at 9.2 (2), 123.3 (6) and 135.2 (5)°, respectively to the mean plane of the benzene ring. In the crystal structure, mol­ecules are stacked along the a axis, without any π–π inter­actions. The stacked columns are linked together by non-classical intermolecular interactions of the type C—H⋯O

Ethyl 3-carb­oxy-5-nitro­benzoate

In the title compound, C10H9NO6, the carb­oxy, ethoxy­carbonyl and nitro groups form dihedral angles of 3.8 (1), 4.5 (1) and 164.8 (1)°, respectively, with the mean plane of the benzene ring. In the crystal structure, mol­ecules lying about inversion centers are linked through O—H⋯O hydrogen bonds. C—H⋯O inter­actions are also present

Isobutyl 3,5-dinitro­benzoate

In the structure of the title compound, C11H12N2O6, the mol­ecules are stacked along the b axis without any π–π inter­actions. The stacked columns are linked together by non-classical inter­molecular C—H⋯O inter­actions,. In the molecule, the nitro groups make dihedral angles of 9.4 (5) and 10.3 (5)° with the benzene ring

Comparative analysis of SOFC-MGT top-level and new bottom-level system performance

In order to make the SOFC-MGT system more widely used, the mathematical simulation models of the SOFC-MGT top-level circulatory system and the new bottom circulatory system were first established, and then the performance of the two systems was analyzed and compared using Matlab/Simulink simulation software. The research results show that the output performance of the SOFC-MGT top-level circulation system is due to the new bottom-level circulation system, and the stack output performance of the two systems is not much different

Genetic Analysis of Floral Symmetry Transition in African Violet Suggests the Involvement of Trans-acting Factor for CYCLOIDEA Expression Shifts

With the growing demand for its ornamental uses, the African violet (Saintpaulia ionantha) has been popular owing to its variations in color, shape and its rapid responses to artificial selection. Wild type African violet (WT) is characterized by flowers with bilateral symmetry yet reversals showing radially symmetrical flowers such as dorsalized actinomorphic (DA) and ventralized actinomorphic (VA) peloria are common. Genetic crosses among WT, DA, and VA revealed that these floral symmetry transitions are likely to be controlled by three alleles at a single locus in which the levels of dominance are in a hierarchical fashion. To investigate whether the floral symmetry gene was responsible for these reversals, orthologs of CYCLOIDEA (CYC) were isolated and their expressions correlated to floral symmetry transitions. Quantitative RT-PCR and in situ results indicated that dorsal-specific SiCYC1s expression in WT S. ionantha (SCYC1A and SiCYC1B) shifted in DA with a heterotopically extended expression to all petals, but in VA, SiCYC1s' dorsally specific expressions were greatly reduced. Selection signature analysis revealed that the major high-expressed copy of SCYC1A had been constrained under purifying selection, whereas the low-expressed helper SiCYC1B appeared to be relaxed under purifying selection after the duplication into SCYC1A and SiCYC1B. Heterologous expression of SCYC1A in Arabdiopsis showed petal growth retardation which was attributed to limited cell proliferation. While expression shifts of SCYC1A and SiCYC1B correlate perfectly to the resulting symmetry phenotype transitions in F1s of WT and DA, there is no certain allelic combination of inherited SiCYC1s associated with specific symmetry phenotypes. This floral transition indicates that although the expression shifts of SCYC1A/1B are responsible for the two contrasting actinomorphic reversals in African violet, they are likely to be controlled by upstream trans-acting factors or epigenetic regulations

Identifying the pollution characteristics of atmospheric polycyclic aromatic hydrocarbons associated with functional districts in Ningbo, China

Duplicate polyurethane foam based passive air samplers (PUF-PAS) were deployed at seven sites in Ningbo from November 1, 2014 to October 31, 2015 and were used to analyze 15 priority polycyclic aromatic hydrocarbons (PAHs). Higher benzo[a]pyrene toxic equivalent concentrations were observed in the industrial areas during wintertime. Correspondence analysis (CA) was used to characterize the PAH congener profiles associated with each functional district and their temporal variations. It showed that different PAH composition profiles and seasonal variations were observed in mountain, rural area and residential areas; and different industrial layouts also led to different properties of PAH congener emissions. Higher levels of PAHs were observed around oil refinery in summer and at mountainous areas in winter, which might be attributed to the evaporation of petroleum and the impact of local biomass burning. This study also demonstrated that the factors influencing the representativeness of a site could be more clearly understood using PUF-PAS and CA analysis. © 2019, Springer Science+Business Media, LLC, part of Springer Nature

Caspase polymorphisms and prognosis of hepatocellular carcinoma

The aim of our study was to determine the impact of genetic polymorphisms in the caspase (CASP) genes on prognosis of hepatocellular carcinoma (HCC). We genotyped 7 potentially functional polymorphisms in CASP3, CASP7, CASP8, CASP9, CASP10 genes in 362 HCC patients of receiving surgical resection of HCC tumor. The associations of genotype and haplotype with overall survival (OS) and disease free survival (DFS) were analyzed by using the Cox proportional hazards model. We found that the CASP9 rs4645981 C allele was significantly associated with positive effect on DFS (P = 0.011 and 0.016 for CT+CC vs. TT in univariate and multivariate analysis, respectively), CT genotype was associated with a better OS of HCC than the TT genotype both in univariate and multivariate analysis (P = 0.048 and 0.041, respectively). Moreover, the CASP3 rs2705897 GT genotype showed marginally significant association with decreased OS and DFS, compared with the GG genotype. One haplotype TT/TG in CASP3 (constructed by rs12108497 T>C and rs2705897 T>G) was significantly associated with decreased OS and DFS, compared to the common haplotype TT/TT both in univariate analysis (P = 0.021 and 0.026, respectively) and multivariate analysis (P = 0.025 and 0.030, respectively). The haplotype GT/GT in CASP9 (constructed by rs4645978 A>G and rs4645981 C>T) was significantly associated with decreased DFS both in univariate and multivariate analysis (P = 0.012 and 0.010, respectively). In conclusion, the CASP9 rs4645981 polymorphism, CASP3 and CASP9 haplotypes may be useful prognosis markers for HCC patients with surgical resection of tumor