Proton modified Pt zeolite fuel cell electrocatalysts

NaY Zeolite is selected as a suitable material to host 1.5 wt% Platinum (Pt) loading on zeolite using ion exchange method (a) Pt(NH3)4(NO3)2 without excess NH4NO3 nitrate and (b) Pt(NH3)4(NO3)2 with excess NH4NO3 nitrate. The structure/reactivity relationship of Pt nanoparticle has been experimentally studied via Nafion@ bound electrodes to investigate the interaction nature of Pt with zeolite and electron transfer using the extended X-ray adsorption fine structure (EXAFS) and Pt particle was predicted at 0.7 – 1.5 (nm). Pt oxides can be electrochemically reduced via a hydrogen ‘spillover’ phenomenon. A highly dispersed small Pt particle distribution can be achieved with excessive H+ ions on zeolite acidic sites

Density Functional Theory Studies of Magnetically Confined Fermi Gas

A theory is developed for magnetically confined Fermi gas at low temperature based on the density functional theory. The theory is illustrated by numerical calculation of density distributions of Fermi atoms $^{40}$K with parameters according to DeMarco and Jin's experiment[Science, 285(1999)1703]. Our results are in good agreement with the experiment. To check the theory, we also performed calculations using our theory at high temperature and compared very well to the result of classical limit.Comment: 6 page

Entanglement distribution over the subsystems and its invariance

We study the entanglement dynamics of two qubits, each of which is embedded into its local amplitude-damping reservoir, and the entanglement distribution among all the bipartite subsystems including qubit-qubit, qubit-reservoir, and reservoir-reservoir. It is found that the entanglement can be stably distributed among all components, which is much different to the result obtained under the Born-Markovian approximation by C. E. L\'{o}pez {\it et al.} [Phys. Rev. Lett. \textbf{101}, 080503 (2008)], and particularly it also satisfies an identity. Our unified treatment includes the previous results as special cases. The result may give help to understand the physical nature of entanglement under decoherence.Comment: 6 pages, 5 figure

Non-Markovian Relaxation of a Three-Level System: Quantum Trajectory Approach

The non-Markovian dynamics of a three-level quantum system coupled to a bosonic environment is a difficult problem due to the lack of an exact dynamic equation such as a master equation. We present for the first time an exact quantum trajectory approach to a dissipative three-level model. We have established a convolutionless stochastic Schr\"{o}dinger equation called time-local quantum state diffusion (QSD) equation without any approximations, in particular, without Markov approximation. Our exact time-local QSD equation opens a new avenue for exploring quantum dynamics for a higher dimensional quantum system coupled to a non-Markovian environment.Comment: 4 pages, 2 figure

Possible pairing symmetries in SrPtAs with a local lack of inversion center

We discuss possible pairing symmetries in the hexagonal pnictide superconductor SrPtAs. The local lack of inversion symmetry of the two distinct conducting layers in the unit cell results in a special spin-orbit coupling with a staggered structure. We classify the pairing symmetry by the global crystal point group D_3d, and suggest some candidates for the stable state using a tight-binding model with an in-plane, density-density type pairing interaction. We may have some unconventional states like s+f-wave and a mixture of chiral d-wave and chiral p-wave. The spin orbit coupling is larger than the interlayer hopping, and the mixing between spin-singlet and triplet states can be seen in spite of the fact that the system has a global inversion center.Comment: 5 pages, 3 figure