Maxwell demons in phase space

Although there is not a complete "proof" of the second law of thermo- dynamics based on microscopic dynamics, two properties of Hamiltonian systems have been used to prove the impossibility of work extraction from a single thermal reservoir: Liouville's theorem and the adiabatic invariance of the volume enclosed by an energy shell. In this paper we analyze these two properties in the Szilard engine and other systems related with the Maxwell demon. In particular, we recall that the enclosed volume is no longer an adiabatic invariant in non ergodic systems and explore the consequences of this on the second law.Comment: 14 pages, to appear in EPJS

Thermodynamic Reversibility in Feedback Processes

The sum of the average work dissipated plus the information gained during a thermodynamic process with discrete feedback must exceed zero. We demonstrate that the minimum value of zero is attained only by feedback-reversible processes that are indistinguishable from their time-reversal, thereby extending the notion of thermodynamic reversibility to feedback processes. In addition, we prove that in every realization of a feedback-reversible process the sum of the work dissipated and change in uncertainty is zero.Comment: 6 pages, 4, figures, accepted in EPL, expanded discussion of thermodynamic reversibilit

Nonequilibrium potential and fluctuation theorems for quantum maps

We derive a general fluctuation theorem for quantum maps. The theorem applies to a broad class of quantum dynamics, such as unitary evolution, decoherence, thermalization, and other types of evolution for quantum open systems. The theorem reproduces well-known fluctuation theorems in a single and simplified framework and extends the Hatano-Sasa theorem to quantum nonequilibrium processes. Moreover, it helps to elucidate the physical nature of the environment inducing a given dynamics in an open quantum system.Comment: 10 page

Quantum fluctuation theorems for arbitrary environments: adiabatic and non-adiabatic entropy production

We analyze the production of entropy along non-equilibrium processes in quantum systems coupled to generic environments. First, we show that the entropy production due to final measurements and the loss of correlations obeys a fluctuation theorem in detailed and integral forms. Second, we discuss the decomposition of the entropy production into two positive contributions, adiabatic and non-adiabatic, based on the existence of invariant states of the local dynamics. Fluctuation theorems for both contributions hold only for evolutions verifying a specific condition of quantum origin. We illustrate our results with three relevant examples of quantum thermodynamic processes far from equilibrium.Comment: 20 pages + 6 of appendices; 7 figures; v2: New example added (example A) and some minor corrections; accepted in Phys. Rev.

Autonomous thermal machine for amplification and control of energetic coherence

We present a model for an autonomous quantum thermal machine comprised of two qubits capable of manipulating and even amplifying the local coherence in a non-degenerate external system. The machine uses only thermal resources, namely, contact with two heat baths at different temperatures, and the external system has a non-zero initial amount of coherence. The method we propose allows for an interconversion between energy, both work and heat, and coherence in an autonomous configuration working in out-of-equilibrium conditions. This model raises interesting questions about the role of fundamental limitations on transformations involving coherence and opens up new possibilities in the manipulation of coherence by autonomous thermal machines.Comment: v1: 5 + 3 pages, 2 figures. v2: Restructured version with several new results and a new appendix, 11 + 14 pages, 4 + 3 figures. v3: Improved and corrected version with new discussions, 8 + 8 pages, 4 + 3 figure