Some Insights into Analytical Bias Involved in the Application of Grab Sampling for Volatile Organic Compounds: A Case Study against Used Tedlar Bags

In this study, we have examined the patterns of VOCs released from used Tedlar bags that were once used for the collection under strong source activities. In this way, we attempted to account for the possible bias associated with the repetitive use of Tedlar bags. To this end, we selected the bags that were never heated. All of these target bags were used in ambient temperature (typically at or below 30°C). These bags were also dealt carefully to avoid any mechanical abrasion. This study will provide the essential information regarding the interaction between VOCs and Tedlar bag materials as a potential source of bias in bag sampling approaches

Emission Rates of Volatile Organic Compounds Released from Newly Produced Household Furniture Products Using a Large-Scale Chamber Testing Method

The emission rates of volatile organic compounds (VOCs) were measured to investigate the emission characteristics of five types of common furniture products using a 5 m3 size chamber at 25°C and 50% humidity. The results indicated that toluene and α-pinene are the most dominant components. The emission rates of individual components decreased constantly through time, approaching the equilibrium emission level. The relative ordering of their emission rates, if assessed in terms of total VOC (TVOC), can be arranged as follows: dining table > sofa > desk chair > bedside table > cabinet. If the emission rates of VOCs are examined between different chemical groups, they can also be arranged in the following order: aromatic (AR) > terpenes (TER) > carbonyl (CBN) > others > paraffin (PR) > olefin (HOL) > halogenated paraffin (HPR). In addition, if emission strengths are compared between coated and uncoated furniture, there is no significant difference in terms of emission magnitude. Our results indicate that the emission characteristics of VOC are greatly distinguished between different furniture products in terms of relative dominance between different chemicals

Ambient particulate matter (PM10) concentrations in major urban areas of Korea during 1996–2010

AbstractIn this study, ambient particulate matter pollution was investigated using monthly PM10 concentration data collected from seven major cities in Korea from 1996 to 2010. The highest mean value for the whole study period is seen from the capital city, Seoul (63.2±17.9μg m–3), while the lowest is from Ulsan (46.7±14.8μg m–3). The concentrations of PM10 in all cities exhibited seasonal variations with the peak values occurring consistently in spring (March or April). The PM10 data in each city consistently exhibited strong correlations (p<0.01) with gaseous pollutants (SO2, NO2, and CO), except for O3 (p>0.05). The analysis of long term trends of PM10 levels indicates a weak but consistent decline in concentrations in most cities with the relative average annual reductions of between 0.4 and 2.8% y–1

Development and Verification of a Risk Index for Evaluating the Chemical Accident Risk of Korean Chemical Enterprises

The scale of the damage due to chemical accidents in Korea is significant, and appropriate preparation and response are required. Currently, Korean enterprises are managed on the basis of the presence of certain substances. However, chemicals other than these also cause chemical accidents. It is necessary to develop a relative ranking risk index that can be calculated through use of the chemical enterprise information on chemical enterprises that is available. The Korean chemical accident risk index (KCARI), which consists of the flammability, reactivity, explosiveness, corrosiveness, toxicity, and inventory sub-indices, was developed and verified by determining the for difference in KCARI was performed by accident, and accident severity category, calculating the correlation between the KCARI values, the factors, and some sub-indices, determining how an increase in the KCARI would impact how the incident rate changed as KCARI increased and how well the KCARI can predict the chemical accident risk of chemical handling enterprises, and confirming the consistency of the proposed index and the current system. These results indicated that the frequency and severity of chemical accidents, and the presence of accidental substances, showed significant differences in the KCARI values. However, there were limitations in the ability of the fitted model to precisely predict the accident. Thus, this model can be used as a tool for the early screening and management of enterprises with a high risk of chemical accident

Occupational exposure to VOCs and carbonyl compounds in beauty salons and health risks associated with it in South Korea

Long-term exposure to volatile organic compounds (VOCs) and carbonyl compounds in beauty products may adversely impact the health of beauty salon technicians. Previous studies have focused on assessing indoor air concentrations of chemicals, such as benzene and toluene, and not on personal exposure concentrations. This study measured the indoor and personal exposure concentrations of VOCs and carbonyl compounds in fifty-three beauty salons in Korea. Non-carcinogenic and carcinogenic risks and sensitivity were analyzed using the Monte Carlo simulation technique. The indoor and personal exposure concentrations of acetone were 82.24 µg/m3 and 104.97 µg/m3, respectively, the highest among all measured chemicals. Beauty salon technicians who experienced adverse health effects had significantly higher concentrations of acetone, benzaldehyde, and toluene than those who did not experience adverse health effects (p-value < 0.05). The average hazard quotients of formaldehyde and acetaldehyde were higher than the acceptable risk level (1), and the average cancer risks of formaldehyde exceeded the acceptable risk level (10−6). Wearing personal protective equipment was the most efficient risk reduction strategy for reducing the non-cancer risks of acetaldehyde and formaldehyde and the carcinogenic risks of formaldehyde. The results of this study can be used as a basis for reducing exposure to VOCs and carbonyl compounds among salon technicians

Cyclodextrin-metal–organic framework (CD-MOF): From synthesis to applications

Porous coordination compounds, commonly known as metal–organic frameworks (MOFs), exhibit many unique characteristics (e.g., high surface area, high porosity, and tunability). The corresponding naturally occurring counterparts, CD-MOFs have opened a new avenue of research in light of its non-toxic, edible, and renewable nature. These characteristics have led to their applications into numerous directions including drug delivery, CO2 capture, separation/purification, adsorption, sensors, food packaging, electrical conductors, memristors, photocatalysis, and polymerization. In this review, we provide a brief discussion about the available technologies for the synthesis of CD-MOFs and their applications in many prospective areas

Sensitivity Analysis of Weather Variables on Offsite Consequence Analysis Tools in South Korea and the United States

We studied sensitive weather variables for consequence analysis, in the case of chemical leaks on the user side of offsite consequence analysis (OCA) tools. We used OCA tools Korea Offsite Risk Assessment (KORA) and Areal Location of Hazardous Atmospheres (ALOHA) in South Korea and the United States, respectively. The chemicals used for this analysis were 28% ammonia (NH3), 35% hydrogen chloride (HCl), 50% hydrofluoric acid (HF), and 69% nitric acid (HNO3). The accident scenarios were based on leakage accidents in storage tanks. The weather variables were air temperature, wind speed, humidity, and atmospheric stability. Sensitivity analysis was performed using the Statistical Package for the Social Sciences (SPSS) program for dummy regression analysis. Sensitivity analysis showed that impact distance was not sensitive to humidity. Impact distance was most sensitive to atmospheric stability, and was also more sensitive to air temperature than wind speed, according to both the KORA and ALOHA tools. Moreover, the weather variables were more sensitive in rural conditions than in urban conditions, with the ALOHA tool being more influenced by weather variables than the KORA tool. Therefore, if using the ALOHA tool instead of the KORA tool in rural conditions, users should be careful not to cause any differences in impact distance due to input errors of weather variables, with the most sensitive one being atmospheric stability