Axisymmetric buckling of a spherical shell embedded in an elastic medium under uniaxial stress at infinity

The problem of a thin spherical linearly-elastic shell, perfectly bonded to an infinite linearly-elastic medium is considered. A constant axisymmetric stress field is applied at infinity in the matrix, and the displacement and stress fields in the shell and matrix are evaluated by means of harmonic potential functions. In order to examine the stability of this solution, the buckling problem of a shell which experiences this deformation is considered. Using Koiter's nonlinear shallow shell theory, restricting buckling patterns to those which are axisymmetric, and using the Rayleigh–Ritz method by expanding the buckling patterns in an infinite series of Legendre functions, an eigenvalue problem for the coefficients in the infinite series is determined. This system is truncated and solved numerically in order to analyse the behaviour of the shell as it undergoes buckling, and to identify the critical buckling stress in two cases — namely where the shell is hollow and the stress at infinity is either uniaxial or radial

Influence of Functional Groups on Charge Transport in Molecular Junctions

Using density functional theory (DFT), we analyze the influence of five classes of functional groups, as exemplified by NO2, OCH3, CH3, CCl3, and I, on the transport properties of a 1,4-benzenedithiolate (BDT) and 1,4-benzenediamine (BDA) molecular junction with gold electrodes. Our analysis demonstrates how ideas from functional group chemistry may be used to engineer a molecule's transport properties, as was shown experimentally and using a semiempirical model for BDA [Nano Lett. 7, 502 (2007)]. In particular, we show that the qualitative change in conductance due to a given functional group can be predicted from its known electronic effect (whether it is pi/sigma donating/withdrawing). However, the influence of functional groups on a molecule's conductance is very weak, as was also found in the BDA experiments. The calculated DFT conductances for the BDA species are five times larger than the experimental values, but good agreement is obtained after correcting for self-interaction and image charge effects.Comment: 6 pages, 3 figures, J. Chem. Phys (in press

Algorithms for the workflow satisfiability problem engineered for counting constraints

The workflow satisfiability problem (WSP) asks whether there exists an assignment of authorized users to the steps in a workflow specification that satisfies the constraints in the specification. The problem is NP-hard in general, but several subclasses of the problem are known to be fixed-parameter tractable (FPT) when parameterized by the number of steps in the specification. In this paper, we consider the WSP with user-independent counting constraints, a large class of constraints for which the WSP is known to be FPT. We describe an efficient implementation of an FPT algorithm for solving this subclass of the WSP and an experimental evaluation of this algorithm. The algorithm iteratively generates all equivalence classes of possible partial solutions until, whenever possible, it finds a complete solution to the problem. We also provide a reduction from a WSP instance to a pseudo-Boolean SAT instance. We apply this reduction to the instances used in our experiments and solve the resulting PB SAT problems using SAT4J, a PB SAT solver. We compare the performance of our algorithm with that of SAT4J and discuss which of the two approaches would be more effective in practice

Coarsening of Two Dimensional Foam on a Dome

In this paper we report on bubble growth rates and on the statistics of bubble topology for the coarsening of a dry foam contained in the narrow gap between two hemispheres. By contrast with coarsening in flat space, where six-sided bubbles neither grow nor shrink, we observe that six sided bubbles grow with time at a rate that depends on their size. This result agrees with the modification to von Neumann's law predicted by J.E. Avron and D. Levine. For bubbles with a different number of sides, except possibly seven, there is too much noise in the growth rate data to demonstrate a difference with coarsening in flat space. In terms of the statistics of bubble topology, we find fewer 3, 4, and 5 sided bubbles, and more 6 and greater sided bubbles, in comparison with the stationary distribution for coarsening in flat space. We also find good general agreement with the Aboav-Weaire law for the average number of sides of the neighbors of an n-sided bubble

The (2√3×3)rect. phase of alkylthiolate self-assembled monolayers on Au(111): a symmetry-constrained structural solution

Low-energy electron-diffraction (LEED) patterns of the Au(111)(2√3×3)rect.-butylthiolate surface phase (a structure also seen in longer alkane chain thiolate self-assembled monolayers) show missing diffracted beams characteristic of glide symmetry, but do not show the larger set of missing beams found in surface x-ray diffraction (SXRD). The difference can be attributed to the greatly enhanced role of multiple scattering in LEED, but the combination of symmetry constraints placed on possible structural models by the observed SXRD and LEED beam extinctions greatly reduces the number of possible structural models. Only three such models are identified, one of which is clearly incompatible with other published experimental data. The relative merits of the remaining models, both involving Au adatom-thiolate moieties, are discussed in the light of the results of previous experimental studies

The Propagation and Survival of Interstellar Grains

In this paper we discuss the propagation of dust through the interstellar medium (ISM), and describe the destructive effects of stellar winds, jets, and supernova shock waves on interstellar dust. We review the probability that grains formed in stellar outflows or supernovae survive processing in and propagation through the ISM, and incorporate themselves relatively unprocessed into meteoritic bodies in the solar system. We show that very large (radii >= 5 micron) and very small grains (radii <= 100 Angstrom) with sizes similar to the pre-solar SiC and diamond grains extracted from meteorites, can survive the passage through 100\kms shock waves relatively unscathed. High velocity (>= 250 km/s) shocks destroy dust efficiently. However, a small (~10%) fraction of the stardust never encountered such fast shocks before incorporation into the solar system. All grains should therefore retain traces of their passage through interstellar shocks during their propagation through the ISM. The grain surfaces should show evidence of processing due to sputtering and pitting due to small grain cratering collisions on the micron-sized grains. This conclusion seems to be in conflict with the evidence from the large grains recovered from meteorites which seem to show little interstellar processing.Comment: 19 pages, 5 figures (.eps), LaTeX, to appear in "Astrophysical Implications of the Laboratory Study of Presolar Materials" AIP Conference Proceedings, 1997 T.J. Bernatowicz and E. Zinner (eds.

Experimental criteria for steering and the Einstein-Podolsky-Rosen paradox

We formally link the concept of steering (a concept created by Schrodinger but only recently formalised by Wiseman, Jones and Doherty [Phys. Rev. Lett. 98, 140402 (2007)] and the criteria for demonstrations of Einstein-Podolsky-Rosen (EPR) paradox introduced by Reid [Phys. Rev. A, 40, 913 (1989)]. We develop a general theory of experimental EPR-steering criteria, derive a number of criteria applicable to discrete as well as continuous-variables observables, and study their efficacy in detecting that form of nonlocality in some classes of quantum states. We show that previous versions of EPR-type criteria can be rederived within this formalism, thus unifying these efforts from a modern quantum-information perspective and clarifying their conceptual and formal origin. The theory follows in close analogy with criteria for other forms of quantum nonlocality (Bell-nonlocality, entanglement), and because it is a hybrid of those two, it may lead to insights into the relationship between the different forms of nonlocality and the criteria that are able to detect them.Comment: Changed title, updated references, minor corrections, added journal-ref and DO