11,098 research outputs found
On Morals, Markets, and Climate Change: Exploring Pope Francis’ Challenge
The relation between Culture and Business has caught researchers’ attention long ago; itis not hard to find studies relating to these topics. According to Hofstede et al. (2010, p.18), Hampden-Turner and Trompenaars (2012, p. 8), and Erez and Gati (2004, p. 5),culture can be defined in many levels, for example, organizational culture, and national culture. The field of Business also contains several disciplines, for example, International Business Management, Project Management, and Project Governance. However, not somany studies can be found studying the relation between National Culture and Project Governance; therefore, this study is focused on this relation.This study is designed following a qualitative approach in order to clarify the relation between National Culture and Project Governance Principles. Case studies are used targeting the IT industry of three countries, Spain, Sweden, and Taiwan. These cases also contain the classical theory of cultural dimensions from Hofstede. Hofstede’s dimensionsare Power Distance (PDI), Individualism vs. Collectivism (IDV), Uncertainty Avoidance(UAI), Masculinity vs. Femininity (MAS), Long-term Orientation (LTO), and Indulgencevs. Restraint (IDU). They are applied in this study for distinguishing the differences between countries. This study is also based on the definition of Project GovernancePrinciples from Garland (2009), Klakegg (2008), and Müller et al. (2013). ProjectGovernance Principles are split into two categories as well, hard/ structural principles andsoft/ behaviour principles.In order to clarify the link between National Culture and Project Governance Principles,this thesis’ authors interviewed 19 people, including 10 project managers and 9 experts.All of them have a long experience dealing with Project Management in the three selected countries. Their answers are based on the knowledge and experience of Project Management and Project Governance, as well as their opinions about their own national culture. After analysing the interviews, the authors consider that differences between these three countries in Project Governance and Project Governance Principles do exist. On the other hand, there are also some similar parts, for example, the influence ofcustomers’ orientation and preference. Moreover, respondents, Project Managers and Experts, all mentioned it is also necessary to be aware of the globalized environment, inother words, there is no influence of a single national culture in one country anymore.However, they all admit the importance of their own national culture as well. All these findings from this study encourage further and deeper study in the future
Issues Relevant to C-H Activation at Platinum(II): Comparative Studies between Cationic, Zwitterionic, and Neutral Platinum(II) Compounds in Benzene Solution
Cationic late metal systems are being highly scrutinized due to
their propensity to mediate so-called electrophilic C-H
activation reactions. This contribution compares the reactivity
of highly reactive cationic platinum(II) systems with
structurally related but neutral species. Our experimental
design exploits isostructural neutral and cationic complexes
supported by bis(phosphine) ligands amenable to mechanistic
examination in benzene solution. The data presented herein
collectively suggests that neutral platinum complexes can be
equally if not more reactive towards benzene than their
cationic counter-parts. Moreover, a number of unexpected
mechanistic distinctions between the two systems arise that
help to explain their respective reactivity
Using baseline-dependent window functions for data compression and field-of-interest shaping in radio interferometry
In radio interferometry, observed visibilities are intrinsically sampled at
some interval in time and frequency. Modern interferometers are capable of
producing data at very high time and frequency resolution; practical limits on
storage and computation costs require that some form of data compression be
imposed. The traditional form of compression is a simple averaging of the
visibilities over coarser time and frequency bins. This has an undesired side
effect: the resulting averaged visibilities "decorrelate", and do so
differently depending on the baseline length and averaging interval. This
translates into a non-trivial signature in the image domain known as
"smearing", which manifests itself as an attenuation in amplitude towards
off-centre sources. With the increasing fields of view and/or longer baselines
employed in modern and future instruments, the trade-off between data rate and
smearing becomes increasingly unfavourable. In this work we investigate
alternative approaches to low-loss data compression. We show that averaging of
the visibility data can be treated as a form of convolution by a boxcar-like
window function, and that by employing alternative baseline-dependent window
functions a more optimal interferometer smearing response may be induced. In
particular, we show improved amplitude response over a chosen field of
interest, and better attenuation of sources outside the field of interest. The
main cost of this technique is a reduction in nominal sensitivity; we
investigate the smearing vs. sensitivity trade-off, and show that in certain
regimes a favourable compromise can be achieved. We show the application of
this technique to simulated data from the Karl G. Jansky Very Large Array (VLA)
and the European Very-long-baseline interferometry Network (EVN)
Cosmological consequences of a principle of finite amplitudes
Over 30 years ago, Barrow & Tipler proposed the principle according to which the action integrated over the entire 4-manifold describing the universe should be finite. Here we explore the cosmological consequences of a related criterion, namely that semi-classical transition amplitudes from the early universe up to current field values should be well defined. On a classical level, our criterion is weaker than the Barrow-Tipler principle, but it has the advantage of being sensitive to quantum effects. We find significant consequences for early universe models, in particular: eternal inflation and strictly cyclic universes are ruled out. Within general relativity, the first phase of evolution cannot be inflationary, and it can be ekpyrotic only if the scalar field potential is trustworthy over an infinite field range. Quadratic gravity eliminates all non-accelerating backgrounds near a putative big bang (thus imposing favourable initial conditions for inflation), while the expected infinite series of higher-curvature quantum corrections eliminates Lorentzian big bang spacetimes altogether. The scenarios that work best with the principle of finite amplitudes are the no-boundary proposal, which gives finite amplitudes in all dynamical theories that we have studied, and string-inspired loitering phases. We also comment on the relationship of our proposal to the swampland conjectures
Dynamical quantum phase transition of a two-component Bose-Einstein condensate in an optical lattice
We study dynamics of a two-component Bose-Einstein condensate where the two
components are coupled via an optical lattice. In particular, we focus on the
dynamics as one drives the system through a critical point of a first order
phase transition characterized by a jump in the internal populations. Solving
the time-dependent Gross-Pitaevskii equation, we analyze; breakdown of
adiabaticity, impact of non-linear atom-atom scattering, and the role of a
harmonic trapping potential. Our findings demonstrate that the phase transition
is resilient to both contact interaction between atoms and external trapping
confinement.Comment: 8 pages, 8 figure
Bis(phosphino)borates:  A New Family of Monoanionic Chelating Phosphine Ligands
The reaction of dimethyldiaryltin reagents Me_(2)SnR_(2) (R ) Ph (1), p-MePh (2), m,m-Me_(2)Ph (3), p-tBuPh (4), p-MeOPh
(5), p-CF_(3)Ph (6)) with BCl_(3) provided a high-yielding, simple preparative route to the corresponding diarylchloroboranes R_(2)BCl (R ) Ph (10), p-MePh (11), m,m-Me2Ph (12), p-tBuPh (13), p-MeOPh (14), p-CF_(3)Ph (15)). In some cases, the desired diarylchloroborane was not formed from an appropriate tin reagent Me_(2)SnR_(2) (R ) o-MeOPh (7), o,o-(MeO)_(2)Ph (8), o-CF_(3)Ph (9)). The reaction of lithiated methyldiaryl- or methyldialkylphosphines with diarylchloroboranes or dialkylchloroboranes is discussed. Specifically, several new monoanionic bis(phosphino)borates
are detailed: [Ph_(2)B(CH_(2)PPh_(2))_(2)] (25); [(p-MePh)_(2)B(CH_(2)PPh_(2))_(2)] (26); [(p-^(t)BuPh)_(2)B(CH_(2)PPh_(2))_(2)] (27); [(p-MeOPh)_(2)B-
(CH_(2)PPh_(2))_(2)] (28); [(p-CF_(3)Ph)_(2)B(CH_(2)PPh_(2))_(2)] (29); [Cy_(2)B(CH_(2)PPh_(2))_(2)] (30); [Ph_(2)B(CH_(2)P{p-^(t)BuPh}_(2))_(2)] (31); [(p-MeOPh)_(2)B- (CH_(2)P{p-^(t)BuPh}_(2))_(2)] (32); [Ph_(2)B(CH_(2)P{p-CF_(3)Ph}_(2))_(2)] (33); [Ph_(2)B(CH_(2)P(BH_(3))(Me)_(2))_(2)] (34); [Ph_(2)B(CH_(2)P(S)(Me)_(2))_(2)] (35); [Ph_(2)B(CH_(2)PiPr_(2))_(2)] (36); [Ph_(2)B(CH_(2)P^(t)Bu_(2))_(2)] (37); [(m,m-Me_(2)Ph)_(2)B(CH_(2)P^(t)Bu_(2))_(2)] (38). The chelation of diarylphosphine derivatives 25-33 and 36 to platinum was examined by generation of a series of platinum dimethyl complexes. The electronic effects of substituted bis(phosphino)borates on the carbonyl stretching frequency of neutral platinum alkyl carbonyl complexes were studied by infrared spectroscopy. Substituents remote from the metal center (i.e. on boron) have minimal effect on the electronic nature of the metal center, whereas substitution close to the metal center (on phosphorus) has a greater effect on the electronic nature of the metal center
A homoleptic phosphine adduct of Tl(I)
A homoleptic phosphine adduct of thallium(I) supported by a tris(phosphino)borate ligand has been isolated and structurally characterized
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