Intermolecular C-H...N and C-H...O interactions in (2S,4S,5R)-(-)-3,4-dimethyl-5-phenyl-2-(1,3-thiazol-2-yl)-1,3-oxazolidine

The title compound, C₁₄H₁₆N₂OS, prepared from (1R,2S)-(-)-ephedrine, contains the oxazolidine ring in an envelope conformation, with the nitrogen atom 0.623 (2) Å from the plane of the other four oxazolidine ring atoms. Intermolecular C--H...N and C--H...O interactions generate a two-dimensional hydrogen-bonded network, with shortest C...N and C...O distances of 3.403 (3) and 3.463 (2) Å, respectively

Intermolecular N-H...O and C-H...O interactions form a two-dimensional network in (2S,4S,5R)-(-)-3,4-dimethyl-5-phenyl-2-(pyrrol-2-yl)-1,3-oxazolidine

The title compound, C₁₅H₁₈N₂0, prepared from (1R,2S)- (-)-ephedrine, crystallizes in space group P1 with two molecules in the asymmetric unit. The oxazolidine rings of the two molecules adopt an envelope conformation, with the N atom 0.609 (6) and 0.623 (6)Å from the plane of the other four oxazolidine ring atoms. Intermolecular Npyrrole--H...O and Cphenyl--H...O interactions generate a two-dimensional hydrogen-bonded network with N...O and C...O distances of 3.004 (4) and 3.051 (4)Å, respectively, and 3.599 (5) and 3.632 (5)Å, respectively, for the two independent hydrogen-bonding systems

On One-Loop Gap Equations for the Magnetic Mass in d=3 Gauge Theory

Recently several workers have attempted determinations of the so-called magnetic mass of d=3 non-Abelian gauge theories through a one-loop gap equation, using a free massive propagator as input. Self-consistency is attained only on-shell, because the usual Feynman-graph construction is gauge-dependent off-shell. We examine two previous studies of the pinch technique proper self-energy, which is gauge-invariant at all momenta, using a free propagator as input, and show that it leads to inconsistent and unphysical result. In one case the residue of the pole has the wrong sign (necessarily implying the presence of a tachyonic pole); in the second case the residue is positive, but two orders of magnitude larger than the input residue, which shows that the residue is on the verge of becoming ghostlike. This happens because of the infrared instability of d=3 gauge theory. A possible alternative one-loop determination via the effective action also fails. The lesson is that gap equations must be considered at least at two-loop level.Comment: 21 pages, LaTex, 2 .eps figure

Nexus solitons in the center vortex picture of QCD

It is very plausible that confinement in QCD comes from linking of Wilson loops to finite-thickness vortices with magnetic fluxes corresponding to the center of the gauge group. The vortices are solitons of a gauge-invariant QCD action representing the generation of gluon mass. There are a number of other solitonic states of this action. We discuss here what we call nexus solitons, in which for gauge group SU(N), up to N vortices meet a a center, or nexus, provided that the total flux of the vortices adds to zero (mod N). There are fundamentally two kinds of nexuses: Quasi-Abelian, which can be described as composites of Abelian imbedded monopoles, whose Dirac strings are cancelled by the flux condition; and fully non-Abelian, resembling a deformed sphaleron. Analytic solutions are available for the quasi-Abelian case, and we discuss variational estimates of the action of the fully non-Abelian nexus solitons in SU(2). The non-Abelian nexuses carry Chern-Simons number (or topological charge in four dimensions). Their presence does not change the fundamentals of confinement in the center-vortex picture, but they may lead to a modified picture of the QCD vacuum.Comment: LateX, 24 pages, 2 .eps figure

Center vortices and confinement vs. screening

We study adjoint and fundamental Wilson loops in the center-vortex picture of confinement, for gauge group SU(N) with general N. There are N-1 distinct vortices, whose properties, including collective coordinates and actions, we study. In d=2 we construct a center-vortex model by hand so that it has a smooth large-N limit of fundamental-representation Wilson loops and find, as expected, confinement. Extending an earlier work by the author, we construct the adjoint Wilson-loop potential in this d=2 model for all N, as an expansion in powers of $\rho/M^2$, where $\rho$ is the vortex density per unit area and M is the vortex inverse size, and find, as expected, screening. The leading term of the adjoint potential shows a roughly linear regime followed by string breaking when the potential energy is about 2M. This leading potential is a universal (N-independent at fixed fundamental string tension $K_F$) of the form $(K_F/M)U(MR)$, where R is the spacelike dimension of a rectangular Wilson loop. The linear-regime slope is not necessarily related to $K_F$ by Casimir scaling. We show that in d=2 the dilute vortex model is essentially equivalent to true d=2 QCD, but that this is not so for adjoint representations; arguments to the contrary are based on illegal cumulant expansions which fail to represent the necessary periodicity of the Wilson loop in the vortex flux. Most of our arguments are expected to hold in d=3,4 also.Comment: 29 pages, LaTex, 1 figure. Minor changes; references added; discussion of factorization sharpened. Major conclusions unchange

Speculations on Primordial Magnetic Helicity

We speculate that above or just below the electroweak phase transition magnetic fields are generated which have a net helicity (otherwise said, a Chern-Simons term) of order of magnitude $N_B + N_L$, where $N_{B,L}$ is the baryon or lepton number today. (To be more precise requires much more knowledge of B,L-generating mechanisms than we currently have.) Electromagnetic helicity generation is associated (indirectly) with the generation of electroweak Chern-Simons number through B+L anomalies. This helicity, which in the early universe is some 30 orders of magnitude greater than what would be expected from fluctuations alone in the absence of B+L violation, should be reasonably well-conserved through the evolution of the universe to around the times of matter dominance and decoupling, because the early universe is an excellent conductor. Possible consequences include early structure formation; macroscopic manifestations of CP violation in the cosmic magnetic field (measurable at least in principle, if not in practice); and an inverse-cascade dynamo mechanism in which magnetic fields and helicity are unstable to transfer to larger and larger spatial scales. We give a quasi-linear treatment of the general-relativistic MHD inverse cascade instability, finding substantial growth for helicity of the assumed magnitude out to scales $\sim l_M\epsilon^{-1}$, where $\epsilon$ is roughly the B+L to photon ratio and $l_M$ is the magnetic correlation length. We also elaborate further on an earlier proposal of the author for generation of magnetic fields above the EW phase transition.Comment: Latex, 23 page

On The Phase Transition in D=3 Yang-Mills Chern-Simons Gauge Theory

$SU(N)$ Yang-Mills theory in three dimensions, with a Chern-Simons term of level $k$ (an integer) added, has two dimensionful coupling constants, $g^2 k$ and $g^2 N$; its possible phases depend on the size of $k$ relative to $N$. For $k \gg N$, this theory approaches topological Chern-Simons theory with no Yang-Mills term, and expectation values of multiple Wilson loops yield Jones polynomials, as Witten has shown; it can be treated semiclassically. For $k=0$, the theory is badly infrared singular in perturbation theory, a non-perturbative mass and subsequent quantum solitons are generated, and Wilson loops show an area law. We argue that there is a phase transition between these two behaviors at a critical value of $k$, called $k_c$, with $k_c/N \approx 2 \pm .7$. Three lines of evidence are given: First, a gauge-invariant one-loop calculation shows that the perturbative theory has tachyonic problems if $k \leq 29N/12$.The theory becomes sensible only if there is an additional dynamic source of gauge-boson mass, just as in the $k=0$ case. Second, we study in a rough approximation the free energy and show that for $k \leq k_c$ there is a non-trivial vacuum condensate driven by soliton entropy and driving a gauge-boson dynamical mass $M$, while both the condensate and $M$ vanish for $k \geq k_c$. Third, we study possible quantum solitons stemming from an effective action having both a Chern-Simons mass $m$ and a (gauge-invariant) dynamical mass $M$. We show that if M \gsim 0.5 m, there are finite-action quantum sphalerons, while none survive in the classical limit $M=0$, as shown earlier by D'Hoker and Vinet. There are also quantum topological vortices smoothly vanishing as $M \rightarrow 0$.Comment: 36 pages, latex, two .eps and three .ps figures in a gzipped uuencoded fil