Steam gasification of sewage sludge for synthesis processes

The paper presents measurement results of a gasification test run. Municipal sewage sludge from a digestion tower is gasified in an advanced dual fluidized bed reactor system. Steam is used as gasification agent and an olivine-limestone mixture as bed material. The fuel analysis shows a very high ash content and a low heating value of the dried sewage sludge. In addition, a significant amount of nitrogen in the fuel is present, leading to a high ammonia content in the product gas.Sintering effects caused by the high ash content do not occur. Thus, a gasification process without limitation is achieved. The fuel input is located in the lower gasification reactor operating as bubbling fluidized bed, whereas the upper gasification reactor is designed as a column of turbulent fluidized zones for tar cracking. The results show an efficient in-situ tar reduction. With a look on the product gas composition a comparatively high carbon dioxide and a low carbon monoxide content is surprising. It is obvious that an iron oxide reduction of the initial fuel ash occur in the gasification reactor. In addition, it is assumed that the significant iron content in the fuel ash also leads to a transport of oxygen from the combustion reactor to the gasification reactor. Thus, carbon monoxide and hydrogen are oxidized in the gasification reactor by the circulating iron-rich ash particles (chemical looping effect).FFG - Österr. Forschungsförderungs- gesellschaft mbH4351

Combined cyclic deformation and artificial ageing of an Al-Mg-Si alloy

Room-temperature cyclic deformation of age-hardenable alloys can produce similar strength as artificial ageing in much shorter time, but industrial applicability is limited due to the high number of required cycles. As an alternative, fewer cyclic deformation steps can be combined with traditional artificial ageing: Introducing a small plastic deformation step every ten minutes during artificial ageing of AA6060 at 160 °C reduces ageing time up to a factor of nine, resulting in comparable yield strength yet slightly reduced ultimate tensile strength

Measurement of coherent surface acoustic wave attenuation in polycrystalline aluminum

Attenuation of Rayleigh-type surface acoustic waves induced by grain-boundary scattering is studied experimentally and theoretically by an effective medium approach. A frequency domain opto-acoustic laboratory setup, capable of measuring a coherent Rayleigh wave response by emulating an ensemble average via spatial averaging, is presented. Measurements are conducted on polycrystalline aluminum at ultrasonic frequencies from 10 MHz to 130 MHz. A constant effective phase velocity of 2893 m s−1 is found below 80 MHz. The effective attenuation coefficient varies in the whole frequency range by nearly two orders of magnitude, and shows classical scattering behavior, comprising stochastic and geometric scattering regimes. A semi-analytical attenuation model is presented, valid below the geometric limit. The model incorporates the material’s spatial two-point correlation function obtained from metallurgical micrographs. Comparisons to experimentally obtained attenuation coefficients show good quantitative agreement, with differences in the frequency power-law dependence. This study attempts to elucidate microstructure induced surface acoustic wave attenuation experimentally by means of a statistical approach. The proposed method and the obtained findings contribute to the understanding of wave propagation in heterogeneous media, and promote the use of surface acoustic waves in non-destructive microstructure characterization

Characterisation and Comparison of Process Chains for Producing Automotive Structural Parts from 7xxx Aluminium Sheets

Due to their high specific strength, EN AW-7xxx aluminium alloys are promising materials for reducing the weight of automotive structural parts. However, their formability at room temperature is poor due to pronounced natural ageing. Therefore, we investigated hot stamping and W-temper forming for EN AW-7075 and a modified variant of EN AW-7021. For hot stamping of the modified EN AW-7021, a low-temperature stabilisation heat treatment (pre-aging at 80 °C for 1 h) was incorporated into the process chain design to inhibit natural ageing after forming. The process chains were compared with respect to dimensional accuracy, mechanical properties, microstructure, precipitation status (assessed by differential scanning calorimetry) and crashworthiness. It was found that hot stamping is suitable to form failure-free parts with good dimensional accuracy for both alloys while W-temper forming suffers from springback. Within a time-span of 21 days after forming, hardness values of hot stamped and stabilised parts did not increase significantly. Compared to non-stabilised parts, stabilised parts also showed significantly improved folding behaviour in quasi-static compression testing and absorbed approximately 15% more energy

Characterization of Zr-Containing Dispersoids in Al–Zn–Mg–Cu Alloys by Small-Angle Scattering

The characterization of Zr-containing dispersoids in aluminum alloys is challenging due to their broad size distribution, low volume fraction, and heterogeneous distribution within the grains. In this work, small-angle X-ray scattering (SAXS) and small-angle neutron scattering (SANS) were compared to scanning electron microscopy (SEM) and transmission electron microscopy (TEM) regarding their capability to characterize Zr-containing dispersoids in aluminum alloys. It was demonstrated that both scattering techniques are suitable tools to characterize dispersoids in a multi-phase industrial 7xxx series aluminum alloy. While SAXS is more sensitive than SANS due to the high electron density of Zr-containing dispersoids, SANS has the advantage of being able to probe a much larger sample volume. The combination of both scattering techniques allows for the verification that the contribution from dispersoids can be separated from that of other precipitate phases such as the S-phase or GP-zones. The size distributions obtained from SAXS, SANS and TEM showed good agreement. The SEM-derived size distributions were, however, found to significantly deviate from those of the other techniques, which can be explained by considering the resolution-limited restrictions of the different techniques