Superspreading and Drying of Trisiloxane-Laden Quantum Dot Nanofluids on Hydrophobic Surfaces

Nanofluids hold promise for a wide range of areas of industry. However, understanding the wetting behavior and deposition formation in the course of drying and spreading of nanofluids, particularly containing surfactants, is still poor. In this paper, the evaporation dynamics of quantum dot-based nanofluids and evaporation-driven self-assembly in nanocolloidal suspensions on hexamethyldisilazane-, polystyrene-, and polypropylene-coated hydrophobic surfaces have been studied experimentally. Moreover, for the very first time, we make a step toward understanding the wetting dynamics of superspreader surfactant-laden nanofluids. It was revealed that drying of surfactant-free quantum dot nanofluids in contrast to pure liquids undergoes not three but four evaporation modes including last additional pinning mode when the contact angle decreases while the triple contact line is pinned by the nanocrystals. In contrast to previous studies, it was found out that addition of nanoparticles to aqueous surfactant solutions leads to deterioration of the spreading rate and to formation of a double coffee ring. For all surfaces examined, superspreading in the presence and absence of quantum dot nanoparticles takes place. Despite the formation of coffee rings on all substrates, they have different morphologies. In particular, the knot-like structures are incorporated into the ring on hexamethyldisilazane- and polystyrene-coated surfaces

Microrheology to Understand the Viscosity Behavior of a Sophorolipid Biosurfactant

The microstructure of the aqueous solutions of purified acidic Sophorolipid (SL) has previously been studied using highly sophisticated methods such as SANS and Cryo-TEM. We were interested in whether (a) the main findings also apply to commercially available SL (which is a mixture of acidic and lactonic SL) and (b) more readily available methods such as DLS can be used to gain insight into the molecular aggregation of SL. Our work was motivated by the increasing interest in biosurfactants for applications in personal and household care. Moreover, the origin behind the more or less lack of rheological response to changes in pH is of practical relevance, as it is somewhat unusual for a carboxylate-group containing surfactant. By using DLS microrheology, we could elucidate the aggregation structure and dynamics of the surfactant on a microscopic scale. Surprisingly, the different degrees of protonation only impacted the microscopic properties such as exchange kinetics and the plateau values of the storage moduli

Microrheology to Understand the Viscosity Behavior of a Sophorolipid Biosurfactant

The microstructure of the aqueous solutions of purified acidic Sophorolipid (SL) has previously been studied using highly sophisticated methods such as SANS and Cryo-TEM. We were interested in whether (a) the main findings also apply to commercially available SL (which is a mixture of acidic and lactonic SL) and (b) more readily available methods such as DLS can be used to gain insight into the molecular aggregation of SL. Our work was motivated by the increasing interest in biosurfactants for applications in personal and household care. Moreover, the origin behind the more or less lack of rheological response to changes in pH is of practical relevance, as it is somewhat unusual for a carboxylate-group containing surfactant. By using DLS microrheology, we could elucidate the aggregation structure and dynamics of the surfactant on a microscopic scale. Surprisingly, the different degrees of protonation only impacted the microscopic properties such as exchange kinetics and the plateau values of the storage moduli

Surface tension behavior of superspreading and non-superspreading trisiloxane surfactants

One parameter frequently considered to be relevant for superspreading of trisiloxane surfactants is surface tension kinetics. In the scientific literature, some experimental results reported for trisiloxane surfactants are in contradiction with fundamental concepts of surfactant monomer diffusion. Therefore, maximum bubble pressure tensiometry has been used to determine dynamic surface tension (DST) of two types of trisiloxane surfactants: superspreader and non-superspreader. Results show that both surfactants behave similarly at concentrations below critical micelle concentration (CMC), as expected. The CMC curves, as determined by drop shape analysis, confirmed that the more hydrophilic non-superspreader has a higher CMC as compared to the more hydrophobic superspreader. Accordingly, the lower surfactant monomer concentration of the superspreader results in a higher DST than the non-superspreader at the same surface age. So, in contrary to claims in the literature, there is nothing mysterious or unexpected concerning the surface tension behavior of trisiloxane surfactants

Effect of Geometry on Electrokinetic Characterization of Solid Surfaces

An analytical approach is presented to describe pressure-driven streaming current (<i>I</i>_str) and streaming potential (<i>U</i>_str) generation in geometrically complex samples, for which the classical Helmholtz–Smoluchowski (H–S) equation is known to be inaccurate. The new approach is valid under the same prerequisite conditions that are used for the development of the H–S equation, that is, the electrical double layers (EDLs) are sufficiently thin and surface conductivity and electroviscous effects are negligible. The analytical methodology is developed using linear velocity profiles to describe liquid flow inside of EDLs and using simplifying approximations to describe macroscopic flow. At first, a general expression is obtained to describe the <i>I</i>_str generated in different cross sections of an arbitrarily shaped sample. Thereafter, assuming that the generated <i>U</i>_str varies only along the pressure-gradient direction, an expression describing the variation of generated <i>U</i>_str along the sample length is obtained. These expressions describing <i>I</i>_str and <i>U</i>_str generation constitute the theoretical foundation of this work, which is first applied to a set of three nonuniform cross-sectional capillaries and thereafter to a square array of cylindrical fibers (model porous media) for both parallel and transverse fiber orientation cases. Although analytical solutions cannot be obtained for real porous substrates because of their random structure, the new theory provides useful insights into the effect of important factors such as fiber orientation, sample porosity, and sample dimensions. The solutions obtained for the model porous media are used to device strategies for more accurate zeta potential determination of porous fiber plugs. The new approach could be thus useful in resolving the long-standing problem of sample geometry dependence of zeta potential measurements

Spreading and Imbibition of Vesicle Dispersion Droplets on Porous Substrates

Vesicles have recently found widespread use in applications such as conditioning of textiles, paper and hair, as well as transdermal drug delivery. The mode of treatment in several such cases involves the application of droplets of aqueous dispersions of vesicles onto dry porous substrates like paper and textiles. One of the factors which affects the performance of such treatments is the rate at which the droplets spread and imbibe on the porous substrate. Depending upon the specific purpose of the treatment either a fast or slow droplet spreading kinetics could be desired. Therefore, it is important to have a good understanding of the droplet spreading process and the factors which influence it. In this work, an experimental investigation of the simultaneous spreading and imbibition of vesicle dispersion droplets on cellulose filter papers is carried out. Two different types of vesicles which are composed of similar lipid molecules but exhibit contrasting lipid bilayer phase behavior are used. Two different grades of filter papers with comparable porosities but different thicknesses are used as porous substrate. It is found that the droplet spreading behavior is of the “complete wetting” type on the thicker porous substrate, whereas it is of the “partial wetting” type on the thinner substrate. Furthermore, it is observed that the spreading of droplets containing vesicles with liquid-crystalline phase bilayers occurs faster than that of vesicles with solid-gel phase bilayers. The secondary radial penetration which commences after the initial droplet spreading is complete is also investigated and discussed

Dynamic Wetting of Hydrophobic Polymers by Aqueous Surfactant and Superspreader Solutions

In this paper, we comparatively investigated the wetting performance of aqueous surfactant solutions in a wide range of concentrations, including conventional ionic surfactants (CTAB, SDS) and two nonionic polyether-modified trisiloxane surfactants (TSS6/3, TSS10/2), over hydrophobic polypropylene substrates. In all cases, scaling analysis of the experimental data of spreading drops showed that the early spreading stage was dominated by inertia and that the duration of this stage was not influenced by the addition of surfactant. For conventional surfactant solutions, we only observed the inertia-dominated spreading stage before the drops stopped wetting with a finite stable contact angle. For both trisiloxane surfactants, after the inertial stage we observed a second viscosity-dominated spreading stage. In this stage, TSS10/2 showed an enhanced wetting capability independent of its concentration, while TSS6/3 started to show a concentration-dependent spreading behavior that was fully developed in a third superspreading stage. Our findings suggest that the superspreading property of TSS6/3 began to take effect after a characteristic time, before which the superspreading TSS6/3 and the nonsuperspreading TSS10/2 behaved similarly. Power law fits to the superspreading regime are in agreement with an interpretation of Marangoni flows resulting from surface tension gradients