Mass transport and electrochemical properties of La2Mo2O9 as a fast ionic conductor

La2Mo2O9, as a new fast ionic conductor, has been investigated widely due to its high ionic conductivity which is comparable to those of the commercialized materials. However, little work has been reported on the oxygen transport and diffusion in this candidate electrolyte material. The main purpose of this project was to investigate oxide ion diffusion in La2Mo2O9 and also the factors which could affect oxygen transport properties. Oxygen isotope exchange followed by Secondary Ion Mass Spectrometry (SIMS) measurements were employed to obtain oxygen diffusion profiles. A correlation between oxygen ion transport and the electrochemical properties such as ionic conductivity was built upon the Nernst Einstein equation relating the diffusivity to electrical conductivity. In-situ neutron diffraction and AC impedance measurements were designed and conducted to investigate the correlation between crystal structure and oxygen transport in the bulk materials. Other techniques, such as synthesis, microstructure studies, and thermal analysis were also adopted to study the electrochemical properties of La2Mo2O9. The results of the study on the effects of microstructure on oxygen diffusion in La2Mo2O9 revealed that the grain boundary component played a significant role in electrochemical performance, although the grain size seemed to have little influence on oxygen transport. The oxygen isotope exchange in 18O2 was successfully carried out by introducing a silver coating on the sample surface, which solved the main difficulty in applying oxygen isotope exchange on pure ionic conductors. The ionic conductivity obtained from the diffusion coefficients was consistent with the result from AC impedance spectroscopy. The number of mobile oxygen ions was estimated to be 5 per unit cell. There was a difference of oxygen self diffusion coefficient when the isotope exchange was conducted in 18O2 and H2 18O. The activation energy of oxygen diffusion in humidified atmosphere was higher than that measured in dry atmosphere. It indicated that the humidified atmosphere had affected oxygen transport in the material. The studies on hydroxyl incorporation and transport explained the decreased oxygen diffusion coefficients in wet atmosphere and also suggested proton conductivity in La2Mo2O9, which leads to further investigation on applications of La2Mo2O9 as a proton conductor. In-situ neutron diffraction and AC impedance measurement revealed a close relationship between crystal structure and ionic conductivity. The successful application of this technique provides a new method to simultaneously investigate crystal structure and electrical properties in electro-ceramics in the future

BUDDHIST PHENOMENOLOGY AND THE PROBLEM OF ESSENCE

In this paper, I intend to make a case for Buddhist phenomenology. By Buddhist phenomenology, I mean a phenomenological interpretation of Yogācāra’s doctrine of consciousness. Yet, this interpretation will be vulnerable if I do not justify the way in which the anti-essentialistic Buddhist philosophy can countenance the Husserlian essence. I dub this problem of compatibility between Buddhist and phenomenology the ‘problem of essence’. Nevertheless, I argue that this problem will not jeopardize Buddhist phenomenology because: 1) Yogācārins, especially late Yogācārins represented by Xuanzang do not articulate emptiness as a negation but as an affirmation of the existent; 2) Husserl’s phenomenological essence is not a substance that Yogācārins reject but the ideal sense (Sinn) that Yogācārins also stress. After resolving the problem of essence, I formulate Buddhist phenomenology as follows: on the epistemological level, it describes intentional acts of consciousness; on the meta-epistemological level, it entails transcendental idealism

LAGC: Lazily Aggregated Gradient Coding for Straggler-Tolerant and Communication-Efficient Distributed Learning

Gradient-based distributed learning in Parameter Server (PS) computing architectures is subject to random delays due to straggling worker nodes, as well as to possible communication bottlenecks between PS and workers. Solutions have been recently proposed to separately address these impairments based on the ideas of gradient coding, worker grouping, and adaptive worker selection. This paper provides a unified analysis of these techniques in terms of wall-clock time, communication, and computation complexity measures. Furthermore, in order to combine the benefits of gradient coding and grouping in terms of robustness to stragglers with the communication and computation load gains of adaptive selection, novel strategies, named Lazily Aggregated Gradient Coding (LAGC) and Grouped-LAG (G-LAG), are introduced. Analysis and results show that G-LAG provides the best wall-clock time and communication performance, while maintaining a low computational cost, for two representative distributions of the computing times of the worker nodes.Comment: Submitte