4,444 research outputs found
1-(2-Hydroxybenzoyl)thiosemicarbazide hemihydrate
The asymmetric unit of the title compound, C8H9N3O2S·0.5H2O, contains two thiosemicarbazide molecules with the short distance of 3.521 (3) Å between the centroids of the benzene rings, and one water molecule. In the two independent molecules, the benzene rings and the thiosemicarbazone fragments are twisted at 9.2 (3) and 18.5 (3)°. An extensive three-dimensional hydrogen-bonding network, formed by intermolecular N—H⋯O, N—H⋯S and O—H⋯O hydrogen bonds, consolidates the crystal packing
Recovery of the orbital parameters and pulse evolution of V0332+53 during a huge outburst
The high mass X-ray binary (HMXB) V0332+53 became active at the end of 2004
and the outburst was observed at hard X-rays by RXTE and INTEGRAL. Based on
these hard X-ray observations, the orbital parameters are measured through
fitting the Doppler-shifted spin periods. The derived orbital period and
eccentricity are consistent with those of Stella et al. (1985) obtained from
EXOSAT observations, whereas the projected semimajor axis and the periastron
longitude are found to have changed from 484 to 86 lt-s and
from 31310 to 28314, respectively. This would
indicate an angular speed of 1.50.8 yr for
rotation of the orbit over the past 21 years. The periastron passage time of
MJD 533671 is just around the time when the intensity reached maximum and
an orbital period earlier is the time when the outburst started. This
correlation resembles the behavior of a Type I outburst. During outburst the
source spun up with a rate of 8.01 s
day. The evolution of pulse profile is highly intensity dependent. The
separation of double pulses remained almost constant ( 0.47) when the
source was bright, and dropped to 0.37 within 3 days as the source
became weaker. The pulse evolution of V0332+53 may correlate to the change in
dominance of the emission between fan-beam and pencil-beam mechanisms.Comment: 13 pages, 3 figures, accepted for publication in ApJ
Communication-Efficient Topologies for Decentralized Learning with Consensus Rate
Decentralized optimization is an emerging paradigm in distributed learning in
which agents achieve network-wide solutions by peer-to-peer communication
without the central server. Since communication tends to be slower than
computation, when each agent communicates with only a few neighboring agents
per iteration, they can complete iterations faster than with more agents or a
central server. However, the total number of iterations to reach a network-wide
solution is affected by the speed at which the agents' information is ``mixed''
by communication. We found that popular communication topologies either have
large maximum degrees (such as stars and complete graphs) or are ineffective at
mixing information (such as rings and grids). To address this problem, we
propose a new family of topologies, EquiTopo, which has an (almost) constant
degree and a network-size-independent consensus rate that is used to measure
the mixing efficiency.
In the proposed family, EquiStatic has a degree of , where
is the network size, and a series of time-dependent one-peer topologies,
EquiDyn, has a constant degree of 1. We generate EquiDyn through a certain
random sampling procedure. Both of them achieve an -independent consensus
rate. We apply them to decentralized SGD and decentralized gradient tracking
and obtain faster communication and better convergence, theoretically and
empirically. Our code is implemented through BlueFog and available at
\url{https://github.com/kexinjinnn/EquiTopo}Comment: NeurIPS 202
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