Entropy driven key-lock assembly

The effective interaction between a sphere with an open cavity (lock) and a spherical macroparticle (key), both immersed in a hard sphere fluid, is studied by means of Monte Carlo simulations. As a result, a 2d map of the key-lock effective interaction potential is constructed, which leads to the proposal of a self-assembling mechanism: there exists trajectories through which the key-lock pair could assemble avoiding trespassing potential barriers. Hence, solely the entropic contribution can induce their self-assembling even in the absence of attractive forces. This study points out the solvent contribution within the underlying mechanisms of substrate-protein assembly/disassembly processes, which are important steps of the enzyme catalysis and protein mediated transport

Cosmology with moving dark energy and the CMB quadrupole

We study the consequences of a homogeneous dark energy fluid having a non-vanishing velocity with respect to the matter and radiation large-scale rest frames. We consider homogeneous anisotropic cosmological models with four fluids (baryons, radiation, dark matter and dark energy) whose velocities can differ from each other. Performing a perturbative calculation up to second order in the velocities, we obtain the contribution of the anisotropies generated by the fluids motion to the CMB quadrupole and compare with observations. We also consider the exact problem for arbitrary velocities and solve the corresponding equations numerically for different dark energy models. We find that models whose equation of state is initially stiffer than radiation, as for instance some tracking models, are unstable against velocity perturbations, thus spoiling the late-time predictions for the energy densities. In the case of scaling models, the contributions to the quadrupole can be non-negligible for a wide range of initial conditions. We also consider fluids moving at the speed of light (null fluids) with positive energy and show that, without assuming any particular equation of state, they generically act as a cosmological constant at late times. We find the parameter region for which the models considered could be compatible with the measured (low) quadrupole.Comment: 23 pages, 6 figures. Confidence intervals calculated from WMAP data, new references and comments included. Final version to appear in PR

An infrared study of galactic OH/IR stars. I. An optical/near-IR atlas of the Arecibo sample

In this paper we present optical and near-infrared finding charts, accurate astrometry (~1") and single-epoch near-infrared photometry for 371 IRAS sources, 96% of those included in the so-called Arecibo sample of OH/IR stars (Eder et al. 1988; Lewis et al. 1990a; Chengalur et al. 1993). The main photometric properties of the stars in the sample are presented and discussed as well as the problems found during the process of identification of the optical/near-infrared counterparts. In addition, we also identify suitable reference stars in each field to be used for differential photometry purposes in the future. We find that 39% of the sources (144 in number) have no optical counterpart, 8 of them being invisible even at near infrared wavelengths. The relative distribution of sources with and without optical counterpart in the IRAS two-colour diagram and their characteristic near infrared colours are interpreted as the consequence of the increasing thickness of their circumstellar shells. Among the objects not detected at near infrared wavelengths four non-variable sources are proposed to be heavily obscured post-AGB stars which have just very recently left the AGB. Eight additional objects with unusually bright and/or blue near-infrared colours are identified as candidate post-AGB stars and/or proto-planetary nebulae.Comment: 28 pages, 9 figures, for associated finding charts see: http://www.edpsciences.org/articles/aa/full/2005/08/aa1709/FINDING_CHARTS/are cibo_index.htm

Contour dynamics model for electric discharges

A contour dynamics model for electrical discharges is obtained and analyzed. The model is deduced as the asymptotic limit of the minimal streamer model for the propagation of electric discharges, in the limit of small electron diffusion. The dispersion relation for a non planar 2-D discharge is calculated. The development and propagation of finger-like patterns are studied and their main features quantified.Comment: 4 pages, 2 fi