Electrical activity of crystal defects in multicrystalline Si

Producción CientíficaUpgraded metallurgical-grade silicon solar cells with different ranges of efficiencies have been characterized by light-beam-induced current (LBIC) measurements. The interaction between grain boundaries and metallic impurities is studied for cells fabricated on wafers from different solidification heights of the ingot. A tight relation is observed between the electrical activity of the grain boundaries and the position of the wafer in the ingot, which is related to the impurity contamination. The presence of a large amount of metallic impurities enhances the electrical activity of the grain boundaries. The main features of the LBIC images are discussed in relation to the presence of metallic impurities.Junta de Castilla y León (project VA283P18)Ministerio de Economía, Industria y Competitividad (project ENE2017-89561-C4-3-R

Comportamiento mecánico de la aleación W+1%Y2O3 en función de la atmósfera y la temperatura

Mediante ensayos de flexión en tres puntos se compara y evalúa el comportamiento mecánico de la aleación W- 1wt%Y2O3 con el W puro fabricados ambos mediante HIP. Se ha obtenido la tenacidad de fractura, la resistencia a flexión y el límite elástico en atmósfera oxidante y de vacío en un intervalo de temperaturas comprendido entre -196 ºC, ensayos de inmersión en nitrógeno líquido, y 1200 ºC. Previamente, se ha medido la densidad, la dureza mediante ensayos Vickers y el módulo de elasticidad dinámico de los materiales. Además, la dureza y el módulo de elasticidad se han comparado con los obtenidos mediante ensayos instrumentados de nanoindentación. Finalmente se ha realizado un pequeño estudio de las superficies de fractura de las muestras ensayadas mediante microscopía electrónica de barrido para poder relacionar el modo de rotura de los materiales y las propiedades mecánicas macroscópicas con los micromecanismos de fallo involucrados en función de la temperatura

Mechanical characterisation of tungsten-1wt.% yttrium oxide as a function of temperature and atmosphere

This study evaluates the mechanical behaviour of an Y2O3-dispersed tungsten (W) alloy and compares it to a pure W reference material. Both materials were processed via mechanical alloying (MA) and subsequent hot isostatic pressing (HIP). We performed non-standard three-point bending (TPB) tests in both an oxidising atmosphere and vacuum across a temperature range from 77 K, obtained via immersion in liquid nitrogen, to 1473 K to determine the mechanical strength, yield strength and fracture toughness. This research aims to evaluate how the mechanical behaviour of the alloy is affected by oxides formed within the material at high temperatures, primarily from 873 K, when the materials undergo a massive thermal degradation. The results indicate that the alloy is brittle to a high temperature (1473 K) under both atmospheres and that the mechanical properties degrade significantly above 873 K. We also used Vickers microhardness tests and the dynamic modulus by impulse excitation technique (IET) to determine the elastic modulus at room temperature. Moreover, we performed nanoindentation tests to determine the effect of size on the hardness and elastic modulus; however, no significant differences were found. Additionally, we calculated the relative density of the samples to assess the porosity of the alloy. Finally, we analysed the microstructure and fracture surfaces of the tested materials via field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM). In this way, the relationship between the macroscopic mechanical properties and micromechanisms of failure could be determined based on the temperature and oxides forme

A P-Lingua based simulator for tissue P systems

AbstractInvestigations within the field of tissue-like P systems are being conducted, on one hand studying their computational efficiency, and on the other hand exploring the possibilities to use them as a computational modelling framework to biological phenomena.In both cases it is necessary to develop software that provides simulation tools (simulators) for the existing variety of tissue P systems. Such simulators allow us to carry on computations of solutions to computationally hard problems on certain (small) instances. Moreover, they also provide a way to verify tissue-like models for real biological processes, by means of experimental data.The paper presents an extension of P-Lingua (a specification language intended to become a standard for software devoted to P systems), in order to cover the class of tissue-like P systems, that were not considered in the previous release. This extension involves on one hand defining the syntax to be used, and on the other hand introducing a new built-in simulation algorithm that has been added to the core library of P-Lingua

Peninsular fibulae: elbow «sículas» or type «Monachil»? News and revision

Se estudia un amplio conjunto de fibulas de codo de las tradicionalmente denominadas «sículas», bajo nuestra nomenclatura de tipo «Monachil», que vienen a completar el panorama cada vez más conocido de este tipo de artilugios problemáticos y paradigmáticos del Bronce Final en la Península Ibérica. De nuevo, se profundiza en sus diferentes tipologías y cronologías, así como en su dispersión regional y posible autoctonía o aloctonía, con el fin de seguir incidiendo en la elaboración de un factible marco crono-cultural, en el que encuadrar mínimamente sus mal definidas formas y desarrollos. Con los datos actuales no es factible mantener un origen sículo para estas fíbulas en la Península Ibérica.We study a wide range of elbow fibulae, traditionally referred to as «sículas» in our Monachil nomenclature. This study will fulfill our knowledge of these problematic and paradigmatic devices in the Late Bronze in the Iberian Peninsula. The different typologies and chronologies are deeply analyzed, as well as their regional distribution, focusing on their native or foreign origin. Our aim is to build a chrono-cultural framework incorporating these fibulae. With the current information available, we cannot conclude that these Iberian fibulae have a Sicilian origin

Topological effects in ultrafast photoinduced processes between flurbiprofen and tryptophan in linked dyads and within human serum albumin

[EN] The interaction dynamics between flurbiprofen (FBP) and tryptophan (Trp) has been studied in covalently linked dyads and within human serum albumin (HSA) by means of fluorescence and ultrafast transient absorption spectroscopy. The dyads have proven to be excellent models to investigate photoinduced processes such as energy and/or electron transfer that may occur in proteins and other biological media. Since the relative spatial arrangement of the interacting units may affect the yield and kinetics of the photoinduced processes, two spacers consisting of amino and carboxylic groups separated by a cyclic or a long linear hydrocarbon chain (1 and 2, respectively) have been used to link the (S)- or (R)-FBP with the (S)-Trp moieties. The main feature observed in the dyads was a strong intramolecular quenching of the fluorescence, which was more important for the (S,S)- than for the (R,S)- diastereomer in dyads 1, whereas the reverse was true for dyads 2. This was consistent with the results obtained by simple molecular modelling (PM3). The observed stereodifferentiation in (S,S)-1 and (R,S)-1 arises from the deactivation of (1)Trp*, while in (S,S)-2 and (R,S)-2 it is associated with (FBP)-F-1*. The mechanistic nature of (FBP)-F-1* quenching is ascribed to energy transfer, while for (1)Trp* it is attributed to electron transfer and/or exciplex formation. These results are consistent with those obtained by ultrafast transient absorption spectroscopy, where (FBP)-F-1* was detected as a band with a maximum at ca. 425 nm and a shoulder at similar to 375 nm, whereas Trp did not give rise to any noticeable transient. Interestingly, similar photoprocesses were observed in the dyads and in the supramolecular FBP@HSA complexes. Overall, these results may aid to gain a deeper understanding of the photoinduced processes occurring in protein-bound drugs, which may shed light on the mechanistic pathways involved in photobiological damage.Grant PID2020-115010RB-I00 funded by MCIN/AEI/10.13039/501100011033 and grant from Conselleria d'Innovacio, Universitats, Ciencia i Societat Digital (CIAICO/2021/061) are gratefully acknowledged.Tamarit-Mayo, L.; García-Gabarda, L.; Jiménez, MC.; Miranda, MA.; Vayá Pérez, I. (2023). Topological effects in ultrafast photoinduced processes between flurbiprofen and tryptophan in linked dyads and within human serum albumin. Physical Chemistry Chemical Physics. 25(23):16148-16156. https://doi.org/10.1039/d3cp01082a1614816156252

Inoculation with rumen fluid in early life as a strategy to optimize the weaning process in intensive dairy goat systems

Ruminants are born with an undeveloped physical, metabolic, and microbial rumen. Rumen development is limited under artificial rearing systems when newborn animals are separated from the dam, fed on milk replacer, and weaned at an early age. This study aims to evaluate the effects of early-life inoculation of young ruminants with rumen fluid from adult animals. Eighty newborn goat kids were randomly allocated to 1 of 4 experimental treatments and inoculated daily from d 1 to wk 11 with autoclaved rumen fluid (AUT), fresh rumen fluid obtained from adult goats fed either a forage diet (RFF) or concentrate-rich diet (RFC), or absence of inoculation (CTL). Goat kids were artificially reared with ad libitum access to milk replacer, starter concentrate, and forage hay. Blood was sampled weekly and rumen microbial fermentation was monitored at 5 (preweaning), 7 (weaning), and 9 wk of age (postweaning). Results indicated that inoculation with fresh rumen fluid accelerated the rumen microbial and fermentative development before weaning. As a result, RFC and RFF animals had higher solid feed intake (+73%), rumen concentrations of ammonia-N (+26%), total volatile fatty acids (+46%), butyrate (+50%), and plasma β-hydroxybutyrate (+48%), and lower milk intake (−6%) than CTL and AUT animals at wk 5. Inoculation with fresh inoculum also promoted early rumen colonization by a complex and abundant protozoal community, whereas CTL animals remained protozoa free. Although all kids experienced moderate growth retardation during 1 wk after weaning, inoculation with fresh rumen fluid favored the weaning process, leading to 2.2 times higher weight gain than CTL and AUT animals during wk 8. Some of these advantages were retained during the postweaning period and RFF and RFC animals showed higher forage intake (up to +44%) than CTL and AUT animals with no detrimental effects on feed digestibility or stress levels. The superior microbial load of RFC compared with RFF inoculum tended to provide further improvements in terms of forage intake, plasma β-hydroxybutyrate, and rumen protozoa, whereas AUT inoculation provided minor (if any) advantages with respect to CTL animals. Although no differences were noted on animal growth, this study suggests that early life inoculation of goat kids with rumen microbiota can represent an effective strategy to accelerate the rumen development, facilitating a smooth transition from milk to solid feed and to the potential implementation of early weaning strategies.This study was funded by the Spanish government through the project AGL2017-86938-R and the Training Program for Academics grant, Madrid, Spain (FPU16/01981)

Relationship between foot eversion and thermographic foot skin temperature after running

[EN] The main instruments to assess foot eversion have some limitations (especially for field applications), and therefore it is necessary to explore new methods. The objective was to determine the relationship between foot eversion and skin temperature asymmetry of the foot sole (difference between medial and lateral side), using infrared thermography. Twenty-two runners performed a running test lasting 30 min. Skin temperature of the feet soles was measured by infrared thermography before and after running. Foot eversion during running was measured by kinematic analysis. Immediately after running, weak negative correlations were observed between thermal symmetry of the rearfoot and eversion at contact time, and between thermal symmetry of the entire plantar surface of the foot and maximum eversion during stance phase (r = −0.3 and p = 0.04 in both cases). Regarding temperature variations, weak correlations were also observed (r = 0.4 and p < 0.05). The weak correlations observed in this study suggest that skin temperature is not related to foot eversion. However, these results open interesting future lines of researchSIDirección General de Investigación Científica y 397 Técnica (DGICT) (DEP2013-48420-P); Ministerio de 398 Educación, Cultura y Deporte (MECD) (Doctoral 399 Fellowship (FPU))

Stratus 15 fifteenth setting of the Stratus Ocean Reference Station cruise on board RV Cabo de Hornos June 15 – 29, 2016 Valparaiso, Chile – Valparaiso, Chile

The Ocean Reference Station at 20°S, 85°W under the stratus clouds west of northern Chile is being maintained to provide ongoing climate-quality records of surface meteorology, air-sea fluxes of heat, freshwater, and momentum, and of upper ocean temperature, salinity, and velocity variability. The Stratus Ocean Reference Station (ORS Stratus) is supported by the National Oceanic and Atmospheric Administration’s (NOAA) Climate Observation Program. It is recovered and redeployed annually, with past cruises that have come between October and May. This cruise was conducted on the Chilean research vessel Cabo de Hornos. During the 2016 cruise on the Cabo de Hornos to the ORS Stratus site, the primary activities were the recovery of the previous (Stratus 14) WHOI surface mooring, deployment of the new Stratus 15 WHOI surface mooring, in-situ calibration of the buoy meteorological sensors by comparison with instrumentation installed on the ship, CTD casts near the moorings. Surface drifters and ARGO floats were also launched along the track.Funding was provided by the National Oceanic and Atmospheric Administration under Grant No. NA14OAR432015

A membrane parallel rapidly-exploring random tree algorithm for robotic motion planning

© 2020-IOS Press and the authors. All rights reserved. In recent years, incremental sampling-based motion planning algorithms have been widely used to solve robot motion planning problems in high-dimensional configuration spaces. In particular, the Rapidly-exploring Random Tree (RRT) algorithm and its asymptotically-optimal counterpart called RRT∗ are popular algorithms used in real-life applications due to its desirable properties. Such algorithms are inherently iterative, but certain modules such as the collision-checking procedure can be parallelized providing significant speedup with respect to sequential implementations. In this paper, the RRT and RRT∗ algorithms have been adapted to a bioinspired computational framework called Membrane Computing whose models of computation, a.k.a. P systems, run in a non-deterministic and massively parallel way. A large number of robotic applications are currently using a variant of P systems called Enzymatic Numerical P systems (ENPS) for reactive controlling, but there is a lack of solutions for motion planning in the framework. The novel models in this work have been designed using the ENPS framework. In order to test and validate the ENPS models for RRT and RRT*, we present two ad-hoc implementations able to emulate the computation of the models using OpenMP and CUDA. Finally, we show the speedup of our solutions with respect to sequential baseline implementations. The results show a speedup up to 6x using OpenMP with 8 cores against the sequential implementation and up to 24x using CUDA against the best multi-threading configuration