Flow conveying and diagnosis with carbon nanotube arrays

Dense arrays of aligned carbon nanotubes are designed into strips, nanowicks, as a miniature wicking element for liquid delivery and potential microfluidic chemical analysis devices. Liquid wicks away along the nanowicks spontaneously. This delivery function of nanowicks enables novel fluid transport devices to run without any power input, moving parts or external pump. Flow around the opaque nanotubes can be detected either directly or indirectly. Direct signals of the flow come out of dyed liquid or from the liquid–air interface; indirect signals are detected through observing surface-tension-induced deformation and dislocation of the nanotubes. Here we show that flow progression around and inside nanowicks is sensitive to liquid properties. Different flow progression leaves different traces of liquid. These traces not only allow liquid diagnosis any time after sampling, but also enable analysis of flow at a nanoscale resolution with scanning electron microscopy

Inherent-opening-controlled pattern formation in carbon nanotube arrays

We have introduced inherent openings into densely packed carbon nanotube arrays to study self-organized pattern formation when the arrays undergo a wetting–dewetting treatment from nanotube tips. These inherent openings, made of circular or elongated hollows in nanotube mats, serve as dewetting centres, from where liquid recedes from. As the dewetting centres initiate dry zones and the dry zones expand, surrounding nanotubes are pulled away from the dewetting centres by liquid surface tension. Among short nanotubes, the self-organized patterns are consistent with the shape of the inherent openings, i.e. slender openings lead to elongated trench-like structures, and circular holes result in relatively round nest-like arrangements. Nanotubes in a relatively high mat are more connected, like in an elastic body, than those in a short mat. Small cracks often initialize themselves in a relatively high mat, along two or more adjacent round openings; each of the cracks evolves into a trench as liquid dries up. Self-organized pattern control with inherent openings needs to initiate the dewetting process above the nanotube tips. If there is no liquid on top, inherent openings barely enlarge themselves after the wetting–dewetting treatment