Analyses of celestial pole offsets with VLBI, LLR, and optical observations

This work aims to explore the possibilities of determining the long-period part of the precession-nutation of the Earth with techniques other than very long baseline interferometry (VLBI). Lunar laser ranging (LLR) is chosen for its relatively high accuracy and long period. Results of previous studies could be updated using the latest data with generally higher quality, which would also add ten years to the total time span. Historical optical data are also analyzed for their rather long time-coverage to determine whether it is possible to improve the current Earth precession-nutation model

Rare case of magnetic Ag3+^{3+} ion: double perovskite Cs2_{2}KAgF6_{6}

Normally $4d$ or $5d$ transition metals are in a low-spin state. Here using first-principles calculations, we report on a rare case of a high-spin $S$=1 magnetic state for the Ag$^{3+}$ ion in the double perovskite Cs$_{2}$KAgF$_{6}$. We also explored a possibility of a conventional low-spin $S$=0 ground state and find an associated tetragonal distortion to be 0.29 {\AA}. However, the lattice elastic energy cost and the Hund exchange loss exceed the e$_{g}$ crystal-field energy gain, thus making the low-spin tetragonal structure less favorable than the high-spin cubic structure. We conclude that the compact perovskite structure of Cs$_{2}$KAgF$_{6}$ is an important factor in stabilizing the unusual high-spin ground state of Ag$^{3+}$.Comment: 6 pages, 6 figures, accepted for publication in PR