Interplay between Quantum Size Effect and Strain Effect on Growth of Nanoscale Metal Thin Film

We develop a theoretical framework to investigate the interplay between quantum size effect (QSE) and strain effect on the stability of metal nanofilms. The QSE and strain effect are shown to be coupled through the concept of "quantum electronic stress. First-principles calculations reveal large quantum oscillations in the surface stress of metal nanofilms as a function of film thickness. This adds extrinsically additional strain-coupled quantum oscillations to surface energy of strained metal nanofilms. Our theory enables a quantitative estimation of the amount of strain in experimental samples, and suggests strain be an important factor contributing to the discrepancies between the existing theories and experiments

Experimental and numerical studies on multi-spherical sliding friction isolation bearing

An innovative multi-spherical sliding friction isolation (MSFI) bearing has recently been developed. The novel isolator has efficient energy dissipation capacity and enough displacement capacity under strong earthquake excitations. The MSFI bearing is completely passive devices, yet shows smart stiffness and smart damping under external excitation. The principles of operation and force-displacement relationship of the novel isolator are presented in this paper. The sliding order of all sliding surfaces and force-displacement hysteretic relationship are verified through a displacement-control testing program, and numerical analysis of the MSFI bearing under low cyclic loading is carried out based on ABAQUS program. The results show the sliding order and force-displacement relationship of the MSFI bearing derived from theoretical analysis results and numerical simulation results are well agree with experimental data which the compression-shear testing of the MSFI bearing specimen with the identical curvature radii and friction coefficients. The adaptive behavior of MSFI bearing permits the isolation system to be separately optimized for multiple levels of seismic intensity and ground motions

catena-Poly[[(4-amino­benzoato)aqua­silver(I)]-μ-hexa­methyl­enetetramine]

In the title coordination polymer, [Ag(C7H6NO2)(C6H12N4)(H2O)]n, the AgI ion is five-coordinated by two carboxyl­ate O atoms from one 4-amino­benzoate anion (L), two N atoms from two different hexa­methyl­enetetramine (hmt) ligands, and one water O atom in a distorted square-pyramidal geometry. The metal atom lies on a mirror plane and the L anion, hmt ligand and water mol­ecule all lie across crystallographic mirror planes. Each hmt ligand bridges two neighboring AgI ions, resulting in the formation of a chain structure along the b axis. The chains are linked into a three-dimensional framework by N—H⋯O and O—H⋯O hydrogen bonds

4-Amino-3,5-dichloro­benzene­sulfonamide

In the title compound, C6H6Cl2N2O2S, the O atoms of the sulfonamide group lie on one side of the benzene ring and the amino group lies on the opposite side. An inter­molecular N—H⋯Cl inter­action occurs. In the crystal, adjacent mol­ecules are linked by N—H⋯O hydrogen bonds, forming a three-dimensional structure with supporting π–π stacking inter­actions [centroid–centroid distance = 3.7903 (12) Å]. A short Cl⋯Cl contact [3.3177 (10) Å] also occurs