The Quark/Antiquark Asymmetry of the Nucleon Sea

Although the distributions of sea quarks and antiquarks generated by leading-twist QCD evolution through gluon splitting $g \rightarrow \bar q q$ are necessarily CP symmetric, the distributions of nonvalence quarks and antiquarks which are intrinsic to the nucleon's bound state wavefunction need not be identical. In this paper we investigate the sea quark/antiquark asymmetries in the nucleon wavefunction which are generated by a light-cone model of energetically-favored meson-baryon fluctuations. The model predicts striking quark/antiquark asymmetries in the momentum and helicity distributions for the down and strange contributions to the proton structure function: the intrinsic $d$ and $s$ quarks in the proton sea are predicted to be negatively polarized, whereas the intrinsic $\bar d$ and $\bar s$ antiquarks give zero contributions to the proton spin. Such a picture is supported by experimental phenomena related to the proton spin problem and the violation of the Ellis-Jaffe sum rule. The light-cone meson-baryon fluctuation model also suggests a structured momentum distribution asymmetry for strange quarks and antiquarks which could be relevant to an outstanding conflict between two different determinations of the strange quark sea in the nucleon. The model predicts an excess of intrinsic $d \bar d$ pairs over $u \bar u$ pairs, as supported by the Gottfried sum rule violation. We also predict that the intrinsic charm and anticharm helicity and momentum distributions are not identical.Comment: LaTex 18 pages, 4 figures. To obtain a copy, send e-mail to [email protected]

Shear Modulus of a Carbonate Sand–Silt Mixture with THF Hydrate

The maximum shear modulus (Gmax) is an important factor determining soil deformation, and it is closely related to engineering safety and seafloor stability. In this study, a series of bender element tests was carried out to investigate the Gmax of a hydrate-bearing carbonate sand (CS)–silt mixture. The soil mixture adopted a CS:silt ratio of 1:4 by weight to mimic the fine-grained deposit of the South China Sea (SCS). Tetrahydrofuran (THF) was used to form the hydrate. Special specimen preparation procedures were adopted to form THF hydrate inside the intraparticle voids of the CS. The test results indicate that hydrate contributed to a significant part of the skeletal stiffness of the hydrate-bearing CS–silt mixture, and its Gmax at 5% hydrate saturation (Sh) was 4–6 times that of the host soil mixture. Such stiffness enhancement at a low Sh may be related to the cementation hydrate morphology. However, the Gmax of the hydrate-bearing CS–silt mixture was also sensitive to the effective stress for an Sh ranging between 5% and 31%, implying that the frame-supporting hydrate morphology also plays a key role in the skeletal stiffness of the soil mixture. Neither the existing cementation models nor the theoretical frame-supporting (i.e., Biot–Gassmann theory by Lee (BGTL)), could alone provide a satisfactory prediction of the test results. Thus, further theoretical study involving a combination of cementation and frame-supporting models is essential to understand the effects of complicated hydrate morphologies on the stiffness of soil with a substantial amount of intraparticle voids

Shear-induced phase transition of nanocrystalline hexagonal boron nitride to wurtzitic structure at room temperature and lower pressure

Disordered structures of boron nitride (BN), graphite, boron carbide (BC), and boron carbon nitride (BCN) systems are considered important precursor materials for synthesis of superhard phases in these systems. However, phase transformation of such materials can be achieved only at extreme pressure–temperature conditions, which is irrelevant to industrial applications. Here, the phase transition from disordered nanocrystalline hexagonal (h)BN to superhard wurtzitic (w)BN was found at room temperature under a pressure of 6.7 GPa after applying large plastic shear in a rotational diamond anvil cell (RDAC) monitored by in situ synchrotron X-ray diffraction (XRD) measurements. However, under hydrostatic compression to 52.8 GPa, the same hBN sample did not transform to wBN but probably underwent a reversible transformation to a high-pressure disordered phase with closed-packed buckled layers. The current phase-transition pressure is the lowest among all reported direct-phase transitions from hBN to wBN at room temperature. Usually, large plastic straining leads to disordering and amorphization; here, in contrast, highly disordered hBN transformed to crystalline wBN. The mechanisms of strain-induced phase transformation and the reasons for such a low transformation pressure are discussed. Our results demonstrate a potential of low pressure–room temperature synthesis of superhard materials under plastic shear from disordered or amorphous precursors. They also open a pathway of phase transformation of nanocrystalline materials and materials with disordered and amorphous structures under extensive shear

Poly[[(μ3-5,6-dicarboxy­bicyclo­[2.2.2]oct-7-ene-2,3-dicarboxyl­ato)(1,10-phenanthroline)copper(II)] monohydrate]

In the title compound, {[Cu(C12H10O8)(C12H8N2)]·H2O}n, the CuII ion is five-coordinated by two N atoms from one phenanthroline ligand and three O atoms from three different H2 L 2− anions (H4 L is bicyclo­[2.2.2]oct-7-ene-2,3,5,6-tetra­carboxylic acid) in a distorted square-pyramidal geometry. Each H2 L 2− ion bridges three CuII atoms to form a zigzag sheet parallel to the ab plane. The crystal structure is consolidated by O—H⋯O hydrogen bonds

Molecular Beam Epitaxy Growth of Superconducting LiFeAs Film on SrTiO3(001) Substrate

The stoichiometric "111" iron-based superconductor, LiFeAs, has attacted great research interest in recent years. For the first time, we have successfully grown LiFeAs thin film by molecular beam epitaxy (MBE) on SrTiO3(001) substrate, and studied the interfacial growth behavior by reflection high energy electron diffraction (RHEED) and low-temperature scanning tunneling microscope (LT-STM). The effects of substrate temperature and Li/Fe flux ratio were investigated. Uniform LiFeAs film as thin as 3 quintuple-layer (QL) is formed. Superconducting gap appears in LiFeAs films thicker than 4 QL at 4.7 K. When the film is thicker than 13 QL, the superconducting gap determined by the distance between coherence peaks is about 7 meV, close to the value of bulk material. The ex situ transport measurement of thick LiFeAs film shows a sharp superconducting transition around 16 K. The upper critical field, Hc2(0)=13.0 T, is estimated from the temperature dependent magnetoresistance. The precise thickness and quality control of LiFeAs film paves the road of growing similar ultrathin iron arsenide films.Comment: 7 pages, 6 figure