610 research outputs found
N′-Diphenylmethylene-2-hydroxybenzohydrazide
The title compound, C20H16N2O2, was synthesized by the reaction of 2-hydroxybenzohydrazide with diphenylmethanone. The dihedral angle between the phenyl rings is 76.28 (11)°. The amino H atom is involved in an intramolecular N—H⋯O hydrogen bond. In the crystal structure, the hydroxy groups and carbonyl O atoms form intermolecular O—H⋯O hydrogen bonds, which link the molecules into chains running along the b axis
1-(2-Chlorobenzylidene)-2-(2,4-dinitrophenyl)hydrazine
In the title compound, C13H9ClN4O4, there are two crystallographically independent molecules in the asymmetric unit, which have very similar conformations. The C=N—N angles in each independent molecule are 115.0 (2) and 116.6 (2)°, which are significantly smaller than the ideal value of 120° expected for sp
2-hybridized N atoms. This is probably a consequence of repulsion between the nitrogen lone pairs and the adjacent N—N bonds. Two bifurcated intramolecular N—H⋯O hydrogen bonds help to establish the molecular conformation and consolidate the crystal packing
2-(1H-1,2,3-Benzotriazol-1-yl)-N′-(2-chlorobenzylidene)acetohydrazide
In the title compound, C15H12ClN5O, the mean planes of the benzotriazole and chlorophenyl fragments form a dihedral angle of 70.8 (1)°. In the crystal, molecules are linked into infinite chains along the a axis by N—H⋯O hydrogen bonds. Weak intermolecular C—H⋯N hydrogen bonds further link these chains into layers parallel to the ab plane. The crystal studied was a racemic twin
The synergistic inhibitory effect of somatostatin-doxorubicin co-treatment on gallbladder carcinoma
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