The Majorana spin in magnetic atomic chain systems

In this paper, we establish that Majorana zero modes emerging from a topological band structure of a chain of magnetic atoms embedded in a superconductor can be distinguished from trivial localized zero energy states that may accidentally form in this system using spin resolved measurements. To demonstrate this key Majorana diagnostics, we study the spin composition of magnetic impurity induced in-gap Shiba states in a superconductor using a quantum impurity model (at the mean-field level). By examining the spin and spectral densities in the context of the Bogoliubov-de Gennes (BdG) particle-hole symmetry, we derive a sum rule that relates the spin densities of localized Shiba states with those in the normal state without superconductivity. Extending our investigations to ferromagnetic chain of magnetic impurities, we identify key features of the spin properties of the extended Shiba state bands, as well as those associated with a localized Majorana end mode when the effect of spin-orbit interaction is included. We then formulate a phenomenological theory for the measurement of the local spin densities with spin-polarized scanning tunneling microscopy (STM) techniques. By combining the calculated spin densities and the measurement theory, we show that spin-polarized STM measurements can reveal a sharp contrast in spin polarization between an accidentally-zero-energy trivial Shiba state and a Majorana zero mode in a topological superconducting phase in atomic chains. We further confirm our results with numerical simulations that address generic parameter settings.Comment: 22 pages, 12 figures (references updated

Cd3As2 is Centrosymmetric

This is a revised version of a manuscript that was originally posted here in February of 2014. It has been accepted at the journal Inorganic Chemistry after reviews that included those of two crystallographers who made sure all the t's were crossed and the i's were dotted. The old work (from 1968) that said that Cd3As2 was noncentrosymmetric was mistaken, with the authors of that study making a type of error that in the 1980s became infamous in crystallography. As a result of the increased scrutiny of the issue of centrosymmetricity of the 1980's, there are now much better analysis tools to resolve the issue fully, and its important to understand that not just our crystals are centrosymmetric, even the old guy's crystals were centrosymmetric (and by implication everyone's are). There is no shame in having made that error back in the day and those authors would not find the current centrosymmetric result controversial; their paper is excellent in all other aspects. This manuscript describes how the structure is determined, explains the structure schematically, calculates the electronic structure based on the correct centrosymmetric crystal structure, and gives the structural details that should be used for future analysis and modeling.Comment: Accepted by ACS Inorganic Chemistr

Observation of a Majorana zero mode in a topologically protected edge channel

Superconducting proximity pairing in helical edge modes, such as those of topological insulators (TI), is predicted to provide a unique platform for realizing Majorana zero modes (MZMs). We use scanning tunneling microscopy measurements to probe the influence of proximity induced superconductivity and magnetism on the helical hinge states of Bi(111) films, grown on a superconducting Nb substrate and decorated with magnetic Fe clusters. Consistent with model calculations, our measurements reveal the emergence of a localized MZM at the interface between the superconducting helical edge channel and the Fe clusters with strong magnetization component along the edge. Our experiments also resolve the MZM spin signature that distinguishes it from trivial in-gap states that may accidently occur at zero energy in a superconductor

Observation of Majorana Fermions in Ferromagnetic Atomic Chains on a Superconductor

Majorana fermions are predicted to localize at the edge of a topological superconductor, a state of matter that can form when a ferromagnetic system is placed in proximity to a conventional superconductor with strong spin-orbit interaction. With the goal of realizing a one-dimensional topological superconductor, we have fabricated ferromagnetic iron (Fe) atomic chains on the surface of superconducting lead (Pb). Using high-resolution spectroscopic imaging techniques, we show that the onset of superconductivity, which gaps the electronic density of states in the bulk of the Fe chains, is accompanied by the appearance of zero energy end states. This spatially resolved signature provides strong evidence, corroborated by other observations, for the formation of a topological phase and edge-bound Majorana fermions in our atomic chains.Comment: 18 pages, 5 figures, and supplementary information. appears in Science (2014

Theoretical and Experimental Studies of the Dechlorination Mechanism of Carbon Tetrachloride on a Vivianite Ferrous Phosphate Surface

Chlorinated organics are the principal and most frequently found contaminants in soil and groundwater, generating significant environmental problems. Over the past several decades, Fe-containing minerals naturally occurring in aquatic and terrestrial environments have been used as natural electron donors, which can effectively dechlorinate a variety of chlorinated organics. However, a full understanding of the reaction mechanism of the dechlorination pathway cannot be obtained by experimental investigations alone, due to the immeasurability of chemical species formed over a short reaction time. In this report, we describe experiments and density functional theory (DFT) calculations carried out to investigate the complex reduction pathway of carbon tetrachloride (CT) on a vivianite (Fe^(II)_3(PO_4)_2·8H_2O) surface. Our results indicate that chloroform (HCCl_3) and formate are the primary transformation products. The experimental results reveal that the reduction kinetics of CCl_4 can be dramatically accelerated as the pH is increased from 3 to 11. On the basis of the DFT calculations, we found that HCCl_3 can be formed by ^•CCl_3 and :CCl_3^(–*) on a deprotonated vivianite surface (an adsorbate on vivianite is denoted using an asterisk). In addition, :CCl_3^(–*) can be nonreductively dechlorinated to form :CCl_2^* followed by sequential nucleophilic attack by OH^(–*), resulting in the formation of :CCl(OH)^* and :C(OH)_2^*, which are responsible for production of CO and formate, respectively. The results obtained from this study can facilitate the modeling of systems of other halogenated species and minerals, which will provide fundamental insight into their corresponding reaction mechanisms

Properties of Central Caustics in Planetary Microlensing

To maximize the number of planet detections, current microlensing follow-up observations are focusing on high-magnification events which have a higher chance of being perturbed by central caustics. In this paper, we investigate the properties of central caustics and the perturbations induced by them. We derive analytic expressions of the location, size, and shape of the central caustic as a function of the star-planet separation, $s$, and the planet/star mass ratio, $q$, under the planetary perturbative approximation and compare the results with those based on numerical computations. While it has been known that the size of the planetary caustic is \propto \sqrt{q}, we find from this work that the dependence of the size of the central caustic on $q$ is linear, i.e., \propto q, implying that the central caustic shrinks much more rapidly with the decrease of $q$ compared to the planetary caustic. The central-caustic size depends also on the star-planet separation. If the size of the caustic is defined as the separation between the two cusps on the star-planet axis (horizontal width), we find that the dependence of the central-caustic size on the separation is \propto (s+1/s). While the size of the central caustic depends both on $s$ and q, its shape defined as the vertical/horizontal width ratio, R_c, is solely dependent on the planetary separation and we derive an analytic relation between R_c and s. Due to the smaller size of the central caustic combined with much more rapid decrease of its size with the decrease of q, the effect of finite source size on the perturbation induced by the central caustic is much more severe than the effect on the perturbation induced by the planetary caustic. Abridged.Comment: 5 pages, 4 figures, ApJ accepte

Imaging electronic states on topological semimetals using scanning tunneling microscopy

Following the intense studies on topological insulators, significant efforts have recently been devoted to the search for gapless topological systems. These materials not only broaden the topological classification of matter but also provide a condensed matter realization of various relativistic particles and phenomena previously discussed mainly in high energy physics. Weyl semimetals host massless, chiral, low-energy excitations in the bulk electronic band structure, whereas a symmetry protected pair of Weyl fermions gives rise to massless Dirac fermions. We employed scanning tunneling microscopy/spectroscopy to explore the behavior of electronic states both on the surface and in the bulk of topological semimetal phases. By mapping the quasiparticle interference and emerging Landau levels at high magnetic field in Dirac semimetals Cd$_3$As$_2$ and Na$_3$Bi, we observed extended Dirac-like bulk electronic bands. Quasiparticle interference imaged on Weyl semimetal TaAs demonstrated the predicted momentum dependent delocalization of Fermi arc surface states in the vicinity of the surface-projected Weyl nodes