The importance of along-margin terrane transport in northern Gondwana: insights from detrital zircon parentage in Neoproterozoic rocks from Iberia and Brittany

Detrital zircons from late Neoproterozoic rocks of the peri-Gondwanan Cadomian belt of SW Iberia and north Armorican Domain of Brittany record Neoproterozoic (ca. 860-550 Ma), Palaeoproterozoic (ca. 2300-1800) and Archaean (ca 3300-2600 Ma) U-Pb ages. The absence of Mesoproterozoic zircons suggests that these terranes evolved in a peri-W African realm. This is in contrast to other western European terranes that preserve Mesoproterozoic zircons and are likely to have evolved in a peri-Amazonian realm. Such a contrast in detrital zircon populations, coupled with the presence of Mesoproterozoic zircons in the Ordovician Armorican quartzite, deposited in a peri-African platform, is interpreted to record along-margin terrane transport. The change in provenance suggests that subduction was replaced by transform faults that juxtaposed Amazonia-derived terranes against W Africa-derived terranes to form the Avalonia and Armorica microcontinents. Subsequent extension along the margin resulted in the birth of the Rheic Ocean and the outboard drift of Avalonia

Lithogeochemical and Sm-Nd and U-Pb isotope data from the Silurian– Lower Devonian Arisaig Group clastic rocks, Avalon terrane, Nova Scotia: A record of terrane accretion in the Appalachian-Caledonide orogen

The Silurian–Lower Devonian Arisaig Group, in the Avalon terrane of Nova Scotia, consists of a thick (~1900 m) sequence of unmetamorphosed fossiliferous siliciclastic strata deposited during terrane accretionary events in the Appalachian-Caledonide orogen. Geochemistry and Sm-Nd and U-Pb (detrital zircon) isotope data of Arisaig Group rocks contrast with the underlying Avalonian rocks, indicating that they were not derived from Avalonian basement. All sedimentary rocks are characterized by strongly negative εNd(t) values (from –4.8 to –9.3, t = 430 Ma) and TDM ages older than 1.5 Ga; the overall trend from the base to the top of the group is toward increasingly negative εNd values. The fact that some Silurian sedimentary rocks contain detrital zircons of similar age suggests that basin formation was broadly coeval with active volcanism in the orogen. These samples also contain abundant Neoproterozoic–Early Cambrian zircons (ca. 620–520 Ma) and lesser abundances at ca. 1200–900 and 2200–1500 Ma. Archean zircons are very minor. The sample of Lower Devonian strata contains Late Silurian and Early Ordovician zircons and, in comparison to the Silurian samples, less abundant Cambrian (ca. 520–510 Ma) and Neoproterozoic (610–550 Ma; 834 Ma) zircons and subordinate Mesoproterozoic (1000–1200 Ma), Meso proterozoic (1400–1600 Ma), and Paleo proterozoic (2000–2100 Ma) zircons. There are no Archean zircons. A comparison between the U-Pb detrital-zircon data and the age of tectonothermal events in potential source areas, together with regional geologic data, suggests that Silurian strata of the Arisaig Group were primarily derived from Baltica, but that there was increasing input from Laurentia by the time of deposition of the Lower Devonian strata of the group. The Arisaig Group is interpreted to have been deposited adjacent to the trailing edge of Avalonia during Appalachian accretionary events, and the geochemical and isotopic characteristics of its strata clearly record the signatures of these regional tectonic events

Diachronous post‐orogenic magmatism within a developing orocline in Iberia, European Variscides

U‐Pb (zircon) crystallization ages of 52 late‐Variscan granitoid intrusions from NW Iberia (19 from new data, 33 from previous studies) constrain the lithospheric evolution of this realm of the Variscan belt of Western Europe and allow assessment of the relationship between oroclinal development and magmatism in late‐Carboniferous‐early Permian times. The U‐Pb ages, in conjunction with a range of geological observations, are consistent with the following sequence of events: (i) oroclinal bending starts at 310–305 Ma producing lithospheric thinning and asthenospheric upwelling in the outer arc of the orocline accompanied by production of mantle and lower crustal melts; (ii) between 305 and 300 Ma, melting continues under the outer arc of the orocline (Central Iberian Zone of the Iberian Variscan belt) and mid‐crustal melting is initiated. Coevally, the lithospheric root beneath the inner arc of the orocline thickened due to progressive arc closure; (iii) between 300 and 292 Ma, foundering of the lithospheric root followed by melting in the lithospheric mantle and the lower crust beneath the inner arc due to upwelling of asthenospheric mantle; (iv) cooling of the lithosphere between 292 and 286 Ma resulting in a drastic attenuation of lower crustal high‐temperature melting. By 285 Ma, the thermal engine generated by orocline‐driven lithospheric thinning/delamination had cooled down beyond its capability to produce significant amounts of mantle or crustal melts. The model proposed explains the genesis of voluminous amounts of granitoid magmas in post‐orogenic conditions and suggests that oroclines and similar post‐orogenic granitoids, common constituents of numerous orogenic belts, may be similarly related elsewhere

Heterogeneity in lunar anorthosite meteorites: Implications for the lunar magma ocean model

The lunar magma ocean model is a well-established theory of the early evolution of the Moon. By this model, the Moon was initially largely molten and the anorthositic crust that now covers much of the lunar surface directly crystallized from this enormous magma source. We are undertaking a study of the geochemical characteristics of anorthosites from lunar meteorites to test this model. Rare earth and other element abundances have been measured in situ in relict anorthosite clasts from two feldspathic lunar meteorites: Dhofar 908 and Dhofar 081. The rare earth elements were present in abundances of approximately 0.1 to approximately 10× chondritic (CI) abundance. Every plagioclase exhibited a positive Eu-anomaly, with Eu abundances of up to approximately 20×CI. Calculations of the melt in equilibrium with anorthite show that it apparently crystallized from a magma that was unfractionated with respect to rare earth elements and ranged in abundance from 8 to 80×CI. Comparisons of our data with other lunar meteorites and Apollo samples suggest that there is notable heterogeneity in the trace element abundances of lunar anorthosites, suggesting these samples did not all crystallize from a common magma source. Compositional and isotopic data from other authors also suggest that lunar anorthosites are chemically heterogeneous and have a wide range of ages. These observations may support other models of crust formation on the Moon or suggest that there are complexities in the lunar magma ocean scenario to allow for multiple generations of anorthosite formation

A pre-Rodinian ophiolite involved in the Variscan suture of Galicia (Cabo Ortegal Complex, NW Spain)

U–Pb dating of zircons from a metagabbro of the Purrido amphibolitic unit (Cabo Ortegal Complex, NW Iberian Massif) yielded an age of 1159 ± 39 Ma, interpreted to approximate the crystallization age of the gabbroic protolith. Considering the arc affinity of the metagabbroic rocks, the unit is interpreted as a pre-Rodinian ophiolite developed in a back-arc setting. It is suggested that the ophiolite was obducted over the West African terranes during the assembly of Rodinia. There, this terrane remained tectonically stable and facing an ocean for a long time, and eventually became part of the Gondwanan margin. The ophiolite was finally involved in the Variscan suture of Galicia where it is sandwiched between Palaeozoic rocks. The Purrido unit is so far the only example of a Mesoproterozoic ophiolite in the European Variscan belt, where pre-Neoproterozoic rocks are very scarce and restricted to small exposures

A U-Pb Study of Zircons from a Lower Crustal Granulite Xenolith of the Spanish Central System: A Record of Iberian Lithospheric Evolution from the Neoproterozoic to the Triassic

A U-Pb laser ablation inductively coupled plasma mass spectrometry and secondary ion mass spectrometry geochronological study has been performed on zircons from a felsic granulite xenolith from the lower crust under the Variscan belt of Iberia. The ages obtained reveal zircon-forming events that span from the late Neoproterozoic (Cadomian-Avalonian orogeny) to the early stages of the opening of the Atlantic Ocean in the Mesozoic, through Cambro-Ordovician rifting, Devono-Carboniferous Variscan-Alleghenian collision, and Permian-Triassic extension and uplift. The U-Pb age groups found in zircons from this single lower crustal xenolith (ca. 220, 250, 280–310, 460–490, 525, and 550–490 Ma) record at least one complete cycle of closing and opening of oceanic basins and collision of continental masses. Zircons from the felsic granulite xenolith contain a synthesis of the geochronological information found on the surface geology and record most but not all major lithospheric events in the region in a ca. 400-m.yr. period

New data (U–Pb, K–Ar) on the geochronology of the alkaline-carbonatitic association of Fuerteventura, Canary Islands, Spain

Zircons from a nepheline-syenite of the Fuerteventura Basal Complex were dated by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS). The age obtained from a total of 21 U–Th–Pb analyses is 25.4F0.3 Ma (2r) indicating a late Oligocene–early Miocene crystallization. This age is consistent with new K–Ar ages on nepheline-syenites and pyroxenites, and contradicts previously published 39Ar–40Ar (feldspar) ages that were interpreted to represent a late Cretaceous–early Paleocene, pyroxenitic–syenitic magmatic episode. These new geochronological data are consistent with both field observations and most of the previously published ages on alkaline silicate rocks and associated carbonatites of Fuerteventura. Therefore, they strongly support the existence of a single, late Oligocene–early Miocene event of alkaline–carbonatitic magmatism in the Basal Complex of Fuerteventura, taking place at approximately 25 Ma and comprising: alkaline-pyroxenites, melteigites-ijolites, nepheline-syenites and carbonatites, as well as their volcanic equivalents and associated dykes. These new data provide an estimate for the length of time that it took the island to grow, thus eliminating one of the major problems in explaining its development by a hot-spot model

Terrane accretion and dispersal in the northern Gondwana margin. An Early Paleozoic analogue of a long-lived active margin

If reconstruction of major events in ancient orogenic belts is achieved in sufficient detail, the tectonic evolution of these belts can offer valuable information to widen our perspective of processes currently at work in modern orogens. Here, we illustrate this possibility taking the western European Cadomian–Avalonian belt as an example. This research is based mainly on the study and interpretation of U–Pb ages of more than 300 detrital zircons from Neoproterozoic and Early Paleozoic sedimentary rocks from Iberia and Brittany. Analyses have been performed using the laser ablation–ICP–MS technique. The U–Pb data record contrasting detrital zircon age spectra for various terranes of western Europe. The differences provide information on the processes involved in the genesis of the western European Precambrian terranes along the northern margin of Neoproterozoic Gondwana during arc construction and subduction, and their dispersal and re-amalgamation along the margin to form the Avalonia and Armorica microcontinents. The U–Pb ages reported here also support the alleged change from subduction to transform activity that led to the final break-up of the margin, the birth of the Rheic Ocean and the drift of Avalonia. We contend that the active northern margin of Gondwana evolved through several stages that match the different types of active margins recognised in modern settings

Iberian late-Variscan granitoids: Some considerations on crustal sources and the significance of “mantle extraction ages

A suite of post-tectonic granitoids (mostly peraluminous, broadly I-type granodiorites and monzogranites) and mafic rocks from NWIberia with crystallization ages between ca. 309 and 290 Ma has been investigated for Sm–Nd isotopes and inherited zircon content in order to constrain the nature of their source rocks. εNd values (at 300 Ma) vary from −0.2 to −5.9 and TDM values range from 1.01 to 1.58 Ga. Inherited (xenocrystic) zircons yielded ages ranging from 458 to 676 Ma, with 90% of data between 490 and 646 Ma, corresponding to Neoproterozoic(mostly Ediacaran), Cambrian andOrdovician ages. Only three highlydiscordant analyses yielded ages older than 650 Ma. Based on the data reported herein and relevant data fromthe literaturewe contend that post-tectonic granitoids of the Iberian Variscan Belt (with exception of the scarce anatectic S-type granitoids) were derived mostly from metaigneous lower crustal sources which in turn were ultimately derived from a subcontinental lithospheric mantle enriched between ca. 0.9 and 1.1 Ga. I-type granitoids and mantle-derived mafic rocks both underwent varying degrees of contamination by ametasedimentary lower crust depleted in pre-650 Ma zircon (through previousmelting episodes) with a time-integrated Sm–Nd evolution different to that of the metaigneous lower crust. Participation of this metasedimentary crust in the genesis of these granitoids may account for Nd isotopic variability and Nd model ages well in excess of 1.2 Ga

U–Pb (LA–ICP-MS) dating of detrital zircons from Cambrian clastic rocks in Avalonia: erosion of a Neoproterozoic arc along the northern Gondwanan margin

Most Neoproterozoic and Early Palaeozoic tectonic syntheses place Avalonia and related peri-Gondwanan terranes facing an open ocean along the northern margin of Gondwana, thereby providing important constraints for palaeocontinental reconstructions during that time interval. However, the precise location of Avalonia along the margin and its position relative to other peri-Gondwanan terranes is controversial. We present laser ablation–inductively coupled plasma mass spectrometry U–Pb data for detrital zircons from Cambrian clastic rocks in two localities in Avalonia: the Antigonish Highlands of Nova Scotia (62 analyses) and the British Midlands (55 analyses). The data from both samples are very similar, and taken together indicate an overwhelming dominance of Neoproterozoic (c. 580–680 Ma) or Early Cambrian source rocks with minor older Neoproterozoic clusters at c. 710 Ma or of Mesoproterozoic age, three Palaeoproterozoic zircons and one Archaean zircon. The zircons can all be derived from local Avalonian sources. The Neoproterozoic zircons are attributed to erosion of the underlying Avalonian arc. Mesoproterozoic and Palaeoproterozoic zircons of similar ages are also found in Avalonian Neoproterozoic clastic rocks and their presence in the Cambrian clastic rocks could represent recycling of Neoproterozoic strata and do not necessarily imply the presence of Mesoproterozoic or Palaeoproterozoic basement rocks within their respective drainage basins. Comparison with the data from the Neoproterozoic arc-related clastic sequences suggests significant differences between their respective drainage systems. Whereas the Neoproterozoic data require extensive drainage systems, the Cambrian data can be attributed to localized drainage systems. The change in drainage patterns could reflect rifting and isolation of Avalonia from Amazonia between c. 585 and 540 Ma. Alternatively, it might reflect the creation of topographical barriers along the northern Gondwanan margin, in a manner analogous to the Cenozoic rise of the Andes or the creation of the Basin-and-Range topography in the Western USA