Study of the Electromagnetic Properties of Nano (MxZn1−x)Fe2O4 (M=Cu, Ni) as a Function of the Sintering Temperature

In this study, the chemical co-precipitation method was used to prepare a nanoscale ferrite powder with Cu-Zn and Ni-Zn compositions. Ferrite, in different Cu-Zn stoichiometric ratios, showed optimal composition of saturated magnetization for Cu0.7Zn0.3Fe2O4; under an air environment and calcined at 900 °C, the saturated magnetization was 60.19 M(emu/g). The average particle diameter was 10 nm for the non-calcined sample, while when the sintering temperature was 900 °C, the particle diameter was about 150 nm. In addition, in different Ni-Zn stoichiometric ratios, the optimal composition of the saturated magnetization was Ni0.5Zn0.5Fe2O4; under an air environment and calcination at 900 °C, the saturated magnetization was 91.40 M(emu/g). The average particle diameter for the non-calcined sample was about 10 nm, but when the sintering temperature was 1200 °C, the particle diameter was 201.06 nm. The prepared ferrite nano-powder was characterized by scanning electron microscopy(SEM), X-ray diffraction(XRD), and vibrating sample magnetometer(VSM) to reveal its microscopic structure and related electromagnetic properties. Ferrite powders of either Cu-Zn or Ni-Zn composition can be used as catalysts for chemical reactions or iron core materials