Minimization of Handoff Failure Probability for Next-Generation Wireless Systems

During the past few years, advances in mobile communication theory have enabled the development and deployment of different wireless technologies, complementary to each other. Hence, their integration can realize a unified wireless system that has the best features of the individual networks. Next-Generation Wireless Systems (NGWS) integrate different wireless systems, each of which is optimized for some specific services and coverage area to provide ubiquitous communications to the mobile users. In this paper, we propose to enhance the handoff performance of mobile IP in wireless IP networks by reducing the false handoff probability in the NGWS handoff management protocol. Based on the information of false handoff probability, we analyze its effect on mobile speed and handoff signaling delay.Comment: 16 Page

Experimental assessment of arsenic toxicity in garole sheep in India

Arsenic, a dangerous bio-accumulative poison, is a grave threat affecting a large number of people as well as animals throughout the World, particularly in Bangladesh and West Bengal, India. It is also a matter of concern as continuously entering into food chain through biotic and abiotic products. The present study was conducted to evaluate the experimental effect of arsenic toxicosis on Garole sheep of West Bengal. One group was subjected to oral arsenic exposure @ 6.6 mg Kg−1 over 133 days when rests considered as negative control. Periodical arsenic estimation in wool, urine and feces along with hemato-biochemical alteration were checked thoroughly. It was evident from the study that long term arsenic exposure exerted a significant (p < 0.01) alteration compared to normal animal which were further supported by clinical abnormalities. Exposed animals showed histological changes throughout major internal organs like coagulative necrosis of liver, tubular nephritis of kidney and acanthosis of skin etc. The bio-accumulative and excretion pattern of arsenic inside body were also well understood by the arsenic estimation study of wool, urine and feces which may be helpful for discussion regarding arsenic entry into food chain via animals

Global, regional, and national burden of disorders affecting the nervous system, 1990–2021: a systematic analysis for the Global Burden of Disease Study 2021

BackgroundDisorders affecting the nervous system are diverse and include neurodevelopmental disorders, late-life neurodegeneration, and newly emergent conditions, such as cognitive impairment following COVID-19. Previous publications from the Global Burden of Disease, Injuries, and Risk Factor Study estimated the burden of 15 neurological conditions in 2015 and 2016, but these analyses did not include neurodevelopmental disorders, as defined by the International Classification of Diseases (ICD)-11, or a subset of cases of congenital, neonatal, and infectious conditions that cause neurological damage. Here, we estimate nervous system health loss caused by 37 unique conditions and their associated risk factors globally, regionally, and nationally from 1990 to 2021.MethodsWe estimated mortality, prevalence, years lived with disability (YLDs), years of life lost (YLLs), and disability-adjusted life-years (DALYs), with corresponding 95% uncertainty intervals (UIs), by age and sex in 204 countries and territories, from 1990 to 2021. We included morbidity and deaths due to neurological conditions, for which health loss is directly due to damage to the CNS or peripheral nervous system. We also isolated neurological health loss from conditions for which nervous system morbidity is a consequence, but not the primary feature, including a subset of congenital conditions (ie, chromosomal anomalies and congenital birth defects), neonatal conditions (ie, jaundice, preterm birth, and sepsis), infectious diseases (ie, COVID-19, cystic echinococcosis, malaria, syphilis, and Zika virus disease), and diabetic neuropathy. By conducting a sequela-level analysis of the health outcomes for these conditions, only cases where nervous system damage occurred were included, and YLDs were recalculated to isolate the non-fatal burden directly attributable to nervous system health loss. A comorbidity correction was used to calculate total prevalence of all conditions that affect the nervous system combined.FindingsGlobally, the 37 conditions affecting the nervous system were collectively ranked as the leading group cause of DALYs in 2021 (443 million, 95% UI 378–521), affecting 3·40 billion (3·20–3·62) individuals (43·1%, 40·5–45·9 of the global population); global DALY counts attributed to these conditions increased by 18·2% (8·7–26·7) between 1990 and 2021. Age-standardised rates of deaths per 100 000 people attributed to these conditions decreased from 1990 to 2021 by 33·6% (27·6–38·8), and age-standardised rates of DALYs attributed to these conditions decreased by 27·0% (21·5–32·4). Age-standardised prevalence was almost stable, with a change of 1·5% (0·7–2·4). The ten conditions with the highest age-standardised DALYs in 2021 were stroke, neonatal encephalopathy, migraine, Alzheimer's disease and other dementias, diabetic neuropathy, meningitis, epilepsy, neurological complications due to preterm birth, autism spectrum disorder, and nervous system cancer.InterpretationAs the leading cause of overall disease burden in the world, with increasing global DALY counts, effective prevention, treatment, and rehabilitation strategies for disorders affecting the nervous system are needed

Multi-attribute decision making method using advanced Pythagorean fuzzy weighted geometric operator and their applications for real estate company selection

In this paper, a novel multi-attribute decision-making method using Advanced Pythagorean fuzzy weighted geometric operator in a Pythagorean fuzzy environment is developed. Pythagorean fuzzy aggregation operators have drawbacks that they give indeterminate results in some special cases when membership value or non-membership value gets 0 value or 1 value and the weight vector is of type (1,0)T or (0,1)T. The Advanced Pythagorean fuzzy geometric operator, the proposed operator can overcome the drawbacks. In some situations, for example, where the sum of squares of membership degree and non-membership degree gets unit value of a Pythagorean fuzzy number, multi-attribute decision making (MADM) methods using some existing aggregation operators give unreasonable ranking orders (ROs) of alternatives or can't discriminate the ROs of alternatives. But the present MADM method can get over the drawbacks of the existing MADM methods. The present MADM method is devoted to eliminate the drawbacks of the existing MADM methods and to select the best real estate company for investment

Morphology controlled synthesis of MnCO3–RGO materials and their supercapacitor applications

MnCO3-reduced graphene oxide (MnCO3–RGO) was grown on nickel foam by a facile successive ionic layer adsorption and reaction (SILAR) method and used as a supercapacitor electrode. The morphology of the MnCO3 functionalities was tuned from lotus to flake to spherical shape using different chelating agents during synthesis. The length and width of the individual petals of the lotus structure MnCO3 were found to be ∼200–300 and 50–100 nm, respectively. The reduction of graphene oxide (GO) in MnCO3–RGO composites was confirmed by Raman spectroscopy and electrical conductivity data analysis. The lotus shaped MnCO3 grown on RGO sheets provided a high surface area and electrical conductivity as compared to the developed electrode materials. The cyclic voltammetry, galvanostatic charge–discharge (GCD) and electrochemical impedance spectroscopy analyses showed that the lotus shaped MnCO3 grown on RGO sheets provided higher current response, large specific capacitance (SC) and low solution, charge-transfer and Warburg resistance as compared to the flake and spherically shaped MnCO3 grown on RGO sheets. A fabricated asymmetric supercapacitor (ASC) device with MnCO3 (lotus) – RGO as the positive electrode and sonochemically reduced GO as the negative electrode – exhibited a working potential of ∼0–1.6 V, SC of ∼ 335 F g−1 at ∼2 A g−1 (∼468 mF cm−2 at ∼2.8 mA cm−2), an energy density of ∼120 W h kg−1 (∼0.16 mW h cm−2) and a power density of ∼16 kW kg−1 (∼22 mW cm−2) with a GCD stability of ∼73% after 10 000 cycles

Surface modification of reduced graphene oxide through successive ionic layer adsorption and reaction method for redox dominant supercapacitor electrodes

Non-covalent surface modification technique, where the pre-reduction of graphene oxide (GO) was carried out to recover the π-π conjugation, was performed through a successive ionic layer adsorption and reaction (SILAR) method for preparing redox dominant supercapacitor electrodes. The π-π conjugation of reduced graphene oxide (RGO) facilitated non-covalent interaction with sulfanilic acid azo-chromotrop (SA) to develop electrolyte accessible layer-by-layer (LL) assembly of RGO and SA (LSARGO). In comparison, RGO was modified with SA through continuous stirring of SA and GO, followed by the post reduction technique and designated as NSARGO. The LSARGO revealed higher surface area, electrical conductivity and electrochemical performances than the NSARGO. Sharp redox peaks with well cathodic peak current density vs. square root of the scan rate slope value indicated a redox dominant LSARGO electrode, which was further confirmed by the specific capacitance (SC) values, calculated from the cyclic voltammetry and galvanostatic charge–discharge (GCD) curves in three electrode configuration. The electrochemical impedance spectroscopy study also revealed that the LSARGO provided more redox dominant supercapacitor characteristics as compared to NSARGO. The LSARGO exhibited a SC of ∼1023 F g−1 at scan rate of ∼10 m V s−1. The fabricated asymmetric supercapacitor device (ASC) showed an elevated energy and power density of ∼80 W h kg−1 and 17,500 W kg−1, respectively. The ASC experienced high GCD cyclic stability of ∼84% after 10,000 cycles

In situ preparation of a SAC-RGO@Ni electrode by electrochemical functionalization of reduced graphene oxide using sulfanilic acid azocromotrop and its application in asymmetric supercapacitors

In situ electro-deposition, reduction and functionalization of graphene oxide (GO) with sulfanilic acid azocromotrop (SAC) were carried out through a facile one-step electrochemical method. Nickel foam was used as the anode during the electro-deposition and the aqueous solution of SAC along with GO was used as the electrolyte. The SAC modified reduced GO (RGO) was deposited on the nickel foam (SAC-RGO@Ni) and was directly used as the electrode for capacitive property analysis. The reduction and functionalization of GO were examined by Fourier transform infrared (FT-IR), Raman and X-ray photoelectron spectroscopy (XPS) techniques. The SAC-RGO@Ni provides a very high specific capacitance of ∼1090 F g−1 due to the synergistic effect of double layer capacitance of RGO and the pseudocapacitance of –SO3H functionalities of SAC. An asymmetric supercapacitor (ASC) cell was designed with SAC-RGO@Ni and thermally reduced GO (TRGO) as positive and negative electrodes, respectively. The ASC device exhibits a high effective capacitance of ∼495 F g−1 at a current density of 10 A g−1 and ∼93% of its total discharging time lies in-between 1.5 and 0.75 V. The ASC cell remains stable up to 10[thin space (1/6-em)]000 charge–discharge cycles. Furthermore, the SAC-RGO@Ni-based ASC device can provide a very high energy density of ∼88.9 W h kg−1 and a large power density of 16[thin space (1/6-em)]500 W kg−1 ensuring its applicability in high power consumption devices

Efficient Access of Voltammetric Charge in Hybrid Supercapacitor Configured with Potassium Incorporated Nanographitic Structure Derived from Cotton (Gossypium arboreum) as Negative and Ni(OH)2/rGO Composite as Positive Electrode

Potassium (K) incorporated nanographitic structure has been derived from cotton (Gossypium arboreum) through KOH activation followed by postannealing treatment. The outer active sites increase as compared to the inner active sites in consequence to K incorporation. Diffusion time constant also decreases as surface area increases after K incorporation. Electrical conductivity of the nanographitic structure increases with K incorporation and showed a high specific capacitance (∼431 F g–1) as negative electrode material. An asymmetric supercapacitor (ASC) has been configured where α-Ni(OH)2/reduced graphene oxide composite was used as the positive electrode material. Appropriate incorporation of the positive and negative electrode materials in the ASC is supported by the efficient (74%) access of voltammetric charge available by the individual electrodes. Furthermore, low relaxation time constant (∼150 ms), high energy density (∼111 W h kg–1), and long life stability of the ASC ensure its potentiality in the energy storage applications

Formation of a supramolecular ladder using dinuclear dicyanamide bridged Cu(II) species: Synthesis, crystal structure and magnetic property

The reaction of Cu(ClO<SUB>4</SUB>)<SUB>2</SUB>·6H<SUB>2</SUB>O with bis(3-aminopropyl)methylamine and sodium dicyanamide in aqueous medium results in the formation of a dimeric dicyanamide complex of Cu(II), [Cu<SUB>2</SUB>(medpt)<SUB>2</SUB>(dca)<SUB>2</SUB>](ClO<SUB>4</SUB>)<SUB>2</SUB>. The single crystal X-ray structure reveals that the dinuclear entities are extended to form a supramolecular 1D ladder by H-bonding. Each dinuclear entity is joined to the adjacent unit via the perchlorate anion. Variable temperature magnetic study was performed and the best-fit parameters are J = −1.20 &#x000B1; 0.02 cm<SUP>-1</SUP>, g = 2.08 &#x000B1; 0.01 with R = 2 × 10<SUP>-5</SUP>. These clearly indicate the antiferromagnetic interaction between the Cu(II) center

Separation/purification of ethylene from an acetylene/ethylene mixture in a pillared-layer porous metal–organic framework

Here we report the synthesis, structure and porous properties of a 3D pillared-layer porous framework of Mn(II)–Mn(III), {[Mn3(bipy)3(H2O)4][Mn(CN)6]2·2(bipy)·4H2O}n (1). The guest-removed framework (1a) shows significant uptake of C2H2, whereas it excludes the other two C2 hydrocarbons (C2H4 and C2H6). Furthermore, excellent separation proficiency for C2H2 from a mixture of C2H2 and C2H4 (1 : 99, v/v) is realized in a breakthrough column experiment under ambient conditions