Latitudinal differences in the amplitude of the OAE-2 carbon isotopic excursion: pCO2 and paleoproductivity [Discussion paper]

A complete, well-preserved record of the Cenomanian/Turonian (C/T) Oceanic Anoxic Event 2 (OAE-2) was recovered from Demerara Rise in the southern North Atlantic Ocean (ODP site 1260). Across this interval, we determined changes in the stable carbon isotopic composition of sulfur-bound phytane (δ13Cphytane, a biomarker for photosynthetic algae. The δ13Cphytane record shows a positive excursion at the onset of the OAE-2 interval, with an unusually large amplitude (~7 ‰) compared to existing C/T proto-North Atlantic δ13Cphytane records (3–6 ‰). Overall, the amplitude of the excursion of δ13Cphytane decreases with latitude. Using reconstructed sea surface temperature (SST) gradients for the proto-North Atlantic, we investigated environmental factors influencing the latitudinal δ13Cphytane gradient. The observed gradient is best explained by high productivity at DSDP Site 367 and Tarfaya basin before OAE-2, which changed in overall high productivity throughout the proto-North Atlantic during OAE-2. During OAE-2, productivity at site 1260 and 603B was thus more comparable to the mid-latitude sites. Using these constraints as well as the SST and δ13Cphytane-records from Site 1260, we subsequently reconstructed pCO2 levels across the OAE-2 interval. Accordingly, pCO2 decreased from ca. 1750 to 900 ppm during OAE-2, consistent with enhanced organic matter burial resulting in lowering pCO2. Whereas the onset of OAE-2 coincided with increased pCO2, in line with a volcanic trigger for this event, the observed cooling within OAE-2 probably resulted from CO2 sequestration in black shales outcompeting CO2 input into the atmosphere. Together these results show that the ice-free Cretaceous world was sensitive to changes in pCO2 related to perturbations of the global carbon cycle

Latitudinal differences in the amplitude of the OAE-2 carbon isotopic excursion : pCO2 and paleo productivity

A complete, well-preserved record of the Cenomanian/Turonian (C/T) Oceanic Anoxic Event 2 (OAE-2) was recovered from Demerara Rise in the southern North Atlantic Ocean (ODP site 1260). Across this interval, we determined changes in the stable carbon isotopic composition of sulfur-bound phytane (δ13Cphytane), a biomarker for photosynthetic algae. The δ13Cphytane record shows a positive excursion at the onset of the OAE-2 interval, with an unusually large amplitude (~7‰) compared to existing C/T proto-North Atlantic δ13Cphytane records (3–6‰). Overall, the amplitude of the excursion of δ13Cphytane decreases with latitude. Using reconstructed sea surface temperature (SST) gradients for the proto-North Atlantic, we investigated environmental factors influencing the latitudinal δ13Cphytane gradient. The observed gradient is best explained by high productivity at DSDP Site 367 and Tarfaya basin before OAE-2, which changed in overall high productivity throughout the proto-North Atlantic during OAE-2. During OAE-2, productivity at site 1260 and 603B was thus more comparable to the mid-latitude sites. Using these constraints as well as the SST and δ13Cphytane-records from Site 1260, we subsequently reconstructed pCO2 levels across the OAE-2 interval. Accordingly, pCO2 decreased from ca. 1750 to 900 ppm during OAE-2, consistent with enhanced organic matter burial resulting in lowering pCO2. Whereas the onset of OAE-2 coincided with increased pCO2, in line with a volcanic trigger for this event, the observed cooling within OAE-2 probably resulted from CO2 sequestration in black shales outcompeting CO2 input into the atmosphere. Together these results show that the ice-free Cretaceous world was sensitive to changes in pCO2 related to perturbations of the global carbon cycle

Fast Deterministic Fully Dynamic Distance Approximation

In this paper, we develop deterministic fully dynamic algorithms for computing approximate distances in a graph with worst-case update time guarantees. In particular, we obtain improved dynamic algorithms that, given an unweighted and undirected graph $G=(V,E)$ undergoing edge insertions and deletions, and a parameter $0 < \epsilon \leq 1$, maintain $(1+\epsilon)$-approximations of the $st$-distance between a given pair of nodes $s$ and $t$, the distances from a single source to all nodes ("SSSP"), the distances from multiple sources to all nodes ("MSSP"), or the distances between all nodes ("APSP"). Our main result is a deterministic algorithm for maintaining $(1+\epsilon)$-approximate $st$-distance with worst-case update time $O(n^{1.407})$ (for the current best known bound on the matrix multiplication exponent $\omega$). This even improves upon the fastest known randomized algorithm for this problem. Similar to several other well-studied dynamic problems whose state-of-the-art worst-case update time is $O(n^{1.407})$, this matches a conditional lower bound [BNS, FOCS 2019]. We further give a deterministic algorithm for maintaining $(1+\epsilon)$-approximate single-source distances with worst-case update time $O(n^{1.529})$, which also matches a conditional lower bound. At the core, our approach is to combine algebraic distance maintenance data structures with near-additive emulator constructions. This also leads to novel dynamic algorithms for maintaining $(1+\epsilon, \beta)$-emulators that improve upon the state of the art, which might be of independent interest. Our techniques also lead to improved randomized algorithms for several problems such as exact $st$-distances and diameter approximation.Comment: Changes to the previous version: improved bounds for approximate st distances using new algebraic data structure

Proportionality in Approval-Based Participatory Budgeting

The ability to measure the satisfaction of (groups of) voters is a crucial prerequisite for formulating proportionality axioms in approval-based participatory budgeting elections. Two common - but very different - ways to measure the satisfaction of a voter consider (i) the number of approved projects and (ii) the total cost of approved projects, respectively. In general, it is difficult to decide which measure of satisfaction best reflects the voters' true utilities. In this paper, we study proportionality axioms with respect to large classes of approval-based satisfaction functions. We establish logical implications among our axioms and related notions from the literature, and we ask whether outcomes can be achieved that are proportional with respect to more than one satisfaction function. We show that this is impossible for the two commonly used satisfaction functions when considering proportionality notions based on extended justified representation, but achievable for a notion based on proportional justified representation. For the latter result, we introduce a strengthening of priceability and show that it is satisfied by several polynomial-time computable rules, including the Method of Equal Shares and Phragm\`en's sequential rule

Cost-Effectiveness of Pharmacotherapy to Reduce Obesity

Aims: Obesity causes a high disease burden in Australia and across the world. We aimed to analyse the cost-effectiveness of weight reduction with pharmacotherapy in Australia, and to assess its potential to reduce the disease burden due to excess body weight

Investigation of the Processability of Polyether Block Amide in High Speed Sintering

The High Speed Sintering (HSS) process ranks among the processes of Powder Bed Fusion of polymers (PBF-P) of Additive Manufacturing (AM). Its scalability, constant layer time and high quality of complex parts compared to other AM processes are some of the characteristics of the HSS showing its potential for series production for small to medium series. Most of the investigations for the PBF-P processes were conducted using commercially available materials like Polyamide 12 (PA12), Polyamide 6 (PA6), Thermoplastic polyurethane (TPU), Polypropylene (PP) and Polybutylene terephthalate (PBT). This work reports from the processing of Polyether block amide (PEBA) in HSS. As a block-copolymer on amide basis, PEBA shows higher performance compared to other block-copolymers like TPU: The high elastic properties, low density and high service temperature make PEBA an ideal material for the use in the athletic footwear and outdoor industry. Until now, no research was conducted on processing PEBA powder in HSS. This work focusses on the material analysis of PEBA powder and manufacturing of specimens of varying sets of process parameters using methods of Design of Experiments (DoE) and IFINAM TPA powder from Evonik. Based on a predictive model, parameter sets for optimum mechanical properties, dimensional accuracy and overall part properties of HSS PEBA parts were optimised within the framework of this work.Mechanical Engineerin

The rise of policy coherence for development: a multi-causal approach

In recent years policy coherence for development (PCD) has become a key principle in international development debates, and it is likely to become even more relevant in the discussions on the post-2015 sustainable development goals. This article addresses the rise of PCD on the Western donors’ aid agenda. While the concept already appeared in the work of Organisation for Economic Co-operation and Development (OECD) in the early 1990s, it took until 2007 before PCD became one of the Organisation’s key priorities. We adopt a complexity-sensitive perspective, involving a process-tracing analysis and a multi-causal explanatory framework. We argue that the rise of PCD is not as contingent as it looks. While actors such as the EU, the DAC and OECD Secretariat were the ‘active causes’ of the rise of PCD, it is equally important to look at the underlying ‘constitutive causes’ which enabled policy coherence to thrive well

An organic borate salt with superior p‐doping capability for organic semiconductors

Molecular doping allows enhancement and precise control of electrical properties of organic semiconductors, and is thus of central technological relevance for organic (opto‐) electronics. Beyond single‐component molecular electron acceptors and donors, organic salts have recently emerged as a promising class of dopants. However, the pertinent fundamental understanding of doping mechanisms and doping capabilities is limited. Here, the unique capabilities of the salt consisting of a borinium cation (Mes2B+; Mes: mesitylene) and the tetrakis(penta‐fluorophenyl)borate anion [B(C6F5)4]− is demonstrated as p‐type dopant for polymer semiconductors. With a range of experimental methods, the doping mechanism is identified to comprise electron transfer from the polymer to Mes2B+, and the positive charge on the polymer is stabilized by [B(C6F5)4]−. Notably, the former salt cation leaves during processing and is not present in films. The anion [B(C6F5)4]− even enables the stabilization of polarons and bipolarons in poly(3‐hexylthiophene), not yet achieved with other molecular dopants. From doping studies with high ionization energy polymer semiconductors, the effective electron affinity of Mes2B+[B(C6F5)4]− is estimated to be an impressive 5.9 eV. This significantly extends the parameter space for doping of polymer semiconductors