Probing crustal and mantle lithosphere origin through Ordovician volcanic rocks along the Iberian passive margin of Gondwana

Northwestern Iberia preserves one of the most complete Paleozoic sequences that document the origin and development of a passive margin along the southern (Gondwanan) flank of the Rheic Ocean. In addition to a well preserved sedimentary record, there is widespread Ordovician volcanic activity that can be used to probe the nature of the lower crust and mantle lithosphere that sourced the volcanic rocks during the Rheic ocean opening. The Ordovician rift-related volcanic sequences provide first-order constraints on the early evolution of the Rheic Ocean. In addition to published and new lithogeochemical data, we provide Sm/Nd isotopic data which together constrain the mantle or crustal source and allow an assessment on the role of the basement in Rheic Ocean magmatism. The data imply that the mafic rocks are derived from a variety of sources, including juvenile mantle that was contaminated by subduction coeval with Early Ordovician magmatism, suggesting the importance of arc activity in northwest Iberia during the opening of the Rheic Ocean. Other basalts were derived from a subcontinental lithospheric mantle that was enriched at about 1.0 Ga. Basalts derived from a mantle enriched at ca. 1.0 Ga occur along other parts of the Gondwanan margin (Avalonia, Oaxaquia) and so the Iberian basalts may be a local representation of a regionally significant enriched mantle. The Sm–Nd isotopic characteristics permit a genetic connection between this mantle source and the basement rocks recently identified in northwest Iberia. Felsic magmas are predominantly intracrustal magmas derived from melting a Mesoproterozoic crust, lending support to other lines of data that the Gondwanan margin of northwest Iberia was predominantly underlain by a South American (Rio Negro) source

40Ar/39Ar phlogopite geochronology of lamprophyre dykes in Cornwall, UK: new age constraints on Early Permian post-collisional magmatism in the Rhenohercynian Zone, SW England

Journal of the Geological Society (2015), http://jgs.lyellcollection.org/content/early/2015/06/03/jgs2014-151. Copyright © Geological Society of London 2015The spatial and temporal association of post-collisional granites and lamprophyre dykes is a common but enigmatic relationship in many orogenic belts, including the Variscan orogenic belt of SW England. The geology of SW England has long been interpreted to reflect orogenic processes associated with the closure of the Rheic Ocean and the formation of Pangaea. The SW England peninsula is composed largely of Early Devonian to Carboniferous volcano-sedimentary successions deposited in synrift and subsequent syncollisional basins that underwent deformation and low-grade regional metamorphism during the Variscan orogeny. Voluminous Early Permian granitic magmatism (Cornubian Batholith) is considered to be broadly coeval with the emplacement of lamprophyric dykes and lamprophyric and basaltic lava flows, largely on the basis of geochronological data from lamprophyric lavas in Devon. Although published geochronological data for Cornish lamprophyre dykes are consistent with this interpretation, these data are limited largely to imprecise K–Ar whole-rock and biotite analyses, hindering the understanding of the processes responsible for their genesis and their relationship to granitic magmatism and regional Variscan tectonics. 40Ar/39Ar geochronological data for four previously undated lamprophyre dykes from Cornwall, combined with published data, suggest that lamprophyre magmatism occurred between c. 293.6 and c. 285.4 Ma, supporting previous inferences that their emplacement was coeval with the Cornubian Batholith. These data provide insights into (1) the relative timing between the lamprophyres and basalts, the Cornubian batholith and post-collisional magmatism elsewhere in the European Variscides, and (2) the post-collisional processes responsible for the generation and emplacement of lamprophyres, basalts and granitoids.NSERC (Canada) Discovery grant

Does the Meguma Terrane Extend into SW England?

The peri-Gondwanan Meguma terrane of southern Nova Scotia, Canada, is the only major lithotectonic element of the northern Appalachian orogen that has no clear correlatives elsewhere in the Appalachians and lacks firm linkages to the Caledonide and Variscan orogens of western and southern Europe. This characteristic is in contrast with its immediate peri-Gondwanan neighbor, Avalonia, which has features in common with portions of Carolinia in the southern Appalachians and has been traced from the Rhenohercynian Zone of southern Britain eastward around the Bohemian Massif to the Carpathians and western Pontides. At issue is the tendency in Europe to assign all peri-Gondwanan terranes lying outboard of the Rheic suture to Avalonia, characterized by relatively juvenile basement and detrital zircon ages that include Mesoproterozoic populations, and those inboard of the suture to Cadomia, characterized by a more evolved basement and detrital zircon ages that match Paleoproterozoic and older sources in the West African craton.    Although the unexposed basements of Avalonia and Meguma are thought to be isotopically very similar, the Meguma sedimentary cover contains scarce Mesoproterozoic zircon and is dominated instead by Neoproterozoic and Paleoproterozoic populations like those of Cadomia. Hence, felsic magma produced by crustal melting in the Meguma terrane (e.g. the ca. 370 Ma South Mountain Batholith) is isotopically more juvenile (eNd = –5 to –1, TDM = 1.3 Ga) than the rocks it intruded (eNd= –12 to –7, TDM = 1.7 Ga). By contrast, felsic magma produced by crustal melting in Avalonia (eNd = –1 to +6, TDM = 0.7–1.2 Ga) is isotopically similar to its host rocks (eNd = –3 to +4, TDM = 0.9–1.4).    The isotopic relationship shown by the Meguma terrane has also been recognized in the South Portuguese Zone of southern Spain, which is traditionally assigned to Avalonia. However, the Sierra Norte Batholith of the South Portuguese Zone (ca. 330 Ma; eNd = +1 to –3, TDM = 0.9–1.2 Ga) is on average more juvenile than the Late Devonian host rocks (eNd = –5 to –11) it intruded, suggesting instead an extension of the Meguma terrane into Europe. Available data for the Cornubian Batholith of SW England (ca. 275–295 Ma; eNd = –4 to –7, TDM = 1.3–1.8 Ga) and the Devonian–Carboniferous metasedimentary rocks it intruded (eNd = –8 to –11) suggests this may also be true of that part of the southern Britain (Rhenohercynian Zone) with which the South Portuguese Zone is traditionally correlated.SOMMAIRELe terrane péri-gondwanien de Meguma en Nouvelle-Écosse au Canada, est le seul grand élément lithotectonique de l’orogène des Appalaches du Nord qui n’ait pas de correspondant avéré ailleurs dans les Appalaches et qui ne montre aucun lien sûr avec les orogènes calédonienne et varisque de l’ouest et du sud de l’Europe.  Cette situation contraste avec celle de son voisin péri-gondwanien immédiat, l’Avalonie, qui partage certaines caractéristiques avec des portions de Carolinia des Appalaches du sud et qui a été suivi à partir de la zone rhénohercynienne dans le sud de la Grande-Bretagne vers l’est autour du massif bohémien jusqu’aux Carpates et l’ouest de la chaîne pontique.  Ce qui est en question ici c’est la tendance en Europe à assigner l’Avalonie à tous les terranes péri-gondwaniens situés à l’extérieur de la suture rhéïque lesquels sont caractérisés par un socle relativement juvénile et des âges de zircons détritiques qui comportent des populations mésoprotérozoïques, et ceux situés à l’intérieur de la suture à Cadomia, lesquels sont caractérisés par un socle plus évolué et des âges de zircons détritiques qui correspondent à des sources du craton ouest africain paléoprotérozoïques et plus anciennes.     Bien que l’on estime que les socles non-exposés des terranes d’Avalonie et de Meguma soient très similaires isotopiquement, le couvert sédimentaire de Meguma ne renferme que de rares zircons mésoprotérozoïques, et ce sont plutôt les populations de zircons néoprotérozoïques et paléoprotérozoïques qui dominent, comme c’est le cas pour Cadomia.  Il en ressort que le magma felsique produit par la fusion de croûte dans le terrane de Meguma (par ex. le batholite de South Mountain de 370 Ma env.) est isotopiquement plus jeune (eNd = –5 à –1, TDM = 1.3 Ga) que les roches qu’il recoupe (eNd= –12 à –7, TDM = 1.7 Ga).  Par opposition, le magma felsique produit par la fusion de la croûte dans le terrane d’Avalonie (eNd = –1 à +6, TDM = 0.7–1.2 Ga) est isotopiquement similaire aux roches de son encaissant (eNd = –3 à +4, TDM = 0.9–1.4).     Le profil isotopique du terrane de Meguma, traditionnellement assignée à l’Avalonie,  a aussi été détecté dans la Zone sud-portugaise du sud de l’Espagne.  Cependant, le batholite de Sierra Norte de la Zone sud-portugaise (ca. 330 Ma; eNd = +1 à –3, TDM = 0.9–1.2 Ga) est en moyenne plus jeune que l’encaissant du Dévonien moyen (eNd = –5 à –11) qu’il recoupe, ce qui permet de penser à une extension du terrane de Meguma en Europe.  Les données disponibles du batholite de Cornubian dans le S-O de l’Angleterre (ca. 275–295 Ma; eNd = –4 à –7, TDM = 1.3–1.8 Ga) et des roches métasédimentaires dévono-carbonifères qu’il recoupe (eNd = –8 to –11) permet de penser qu’il pourrait en être de même de cette portion du sud de la Grande-Bretagne (Zone rhénohercynienne) avec laquelle la Zone sud-portugaise est traditionnellement corrélée

SARS Coronavirus-2 microneutralisation and commercial serological assays correlated closely for some but not all enzyme immunoassays

Serological testing for SARS-CoV-2-specific antibodies provides important research and diagnostic information relating to COVID-19 prevalence, incidence and host immune response. A greater understanding of the relationship between functionally neutralising antibodies detected using microneutralisation assays and binding antibodies detected using scalable enzyme immunoassays (EIA) is needed in order to address protective immunity post-infection or vaccination, and assess EIA suitability as a surrogate test for screening of convalescent plasma donors. We assessed whether neutralising antibody titres correlated with signal cut-off ratios in five commercially available EIAs, and one in-house assay based on expressed spike protein targets. Sera from recovered patients or convalescent plasma donors who reported laboratory-confirmed SARS-CoV-2 infection (n = 200), and negative control sera collected prior to the COVID-19 pandemic (n = 100), were assessed in parallel. Performance was assessed by calculating EIA sensitivity and specificity with reference to microneutralisation. Neutralising antibodies were detected in 166 (83%) samples. Compared with this, the most sensitive EIAs were the Cobas Elecsys Anti-SARS-CoV-2 (98%) and Vitros Immunodiagnostic Anti-SARS-CoV-2 (100%), which detect total antibody targeting the N and S1 antigens, respectively. The assay with the best quantitative relationship with microneutralisation was the Euroimmun IgG. These results suggest the marker used (total Ab vs. IgG vs. IgA) and the target antigen are important determinants of assay performance. The strong correlation between microneutralisation and some commercially available assays demonstrates their potential for clinical and research use in assessing protection following infection or vaccination, and use as a surrogate test to assess donor suitability for convalescent plasma donation

Viewing scenes of the history of chemistry through the opera glass

Artistic creation has always reflected the spirit of the moment and opera has not been an exception. There are several examples of operas which appeared at key moments of the development of science, portraying them. Additionally there are also operas that emerged after scientific events or the lifetime of the scientists they were inspired on. In what concerns chemistry, the first category could be exemplified by the apothecary operas (already discussed by the author in a previous paper of this journal) while the others could be illustrated by recent operas such as Dr. Atomic or Madame Curie. Continuing our endeavor of establishing relations between opera and chemistry, and considering that history of science plays an important role in the process of teaching and learning sciences, some milestones of the history of chemistry are here revisited through the opera glass. The operas analyzed have been grouped in the following categories: Operas of Fire and Metallurgy, Operas of the Philosophers of Antiquity, Operas of Alchemy, Operas of the Age of Enlightenment, Operas of the Revolutions and Operas of Entropy.Thanks are due to the Foundation for Science and Technology (FCT–Portugal) and FEDER (European Fund for Regional Development)-COMPETE/QREN/EU for financial support through the research unity PEst-C/QUI/UI686/2013.

Detrital zircon geochronology from the Nueva Segovia Schist, Nicaragua: evidence for the tectonic evolution of the Chortís Block?

SF2: U–PB data table

Probing the composition of unexposed basement, South Portuguese Zone, southern Iberia: implications for the connections between the Appalachian and Variscan orogens

Geochemistry and Sm–Nd and U–Pb (magmatic zircon) isotope data from a postcollisional batholith that crosscuts the allochthonous South Portuguese Zone (SPZ) of southern Iberia suggest that the basement is compositionally more juvenile than the exposed upper crust. The SPZ is an allochthonous terrane of the late Paleozoic Variscan orogen. The oldest exposed units in the SPZ are Late Devonian continental clastics, and as a result, the origins of the SPZ are unknown. Multifaceted inherited zircon cores from a granitoid batholith (Sierra Norte Batholith, SNB) reveal Neoproterozoic (ca. 561–647 Ma) and Mesoproterozoic ages (ca. 1075 – ca. 1116 Ma). Granitoid samples are characterized by εNd values ranging from +1.4 to –9.6 and model ages ca. 0.76–1.8 Ga. Conversely, the exposed Late Devonian clastics of the SPZ are characterized by more negative εNd values (–7.5 to –10.4). Taken together, U–Pb and Sm–Nd data indicate the lower crust that melted to yield the SNB was (i) Neoproterozoic (ca. 560–650 Ma) to Mesoproterozoic (ca. 1.0–1.2 Ga) in age, (ii) was not compositionally similar to the overlying Devono-Carboniferous continental detritus but was instead more juvenile, with model ages between ca. 0.9–1.2 Ga. This unusual relationship is similar to the relationship between the relatively juvenile basement and ancient upper crust documented in the exposed portion of the Meguma terrane in the northern Appalachians, which paleogeographic reconstructions show was immediately outboard of southern Iberia in the Late Devonian.Department of Earth Sciences, Saint Francis Xavier University, CanadáInstituto Geológico y Minero de España, EspañaDepartment of Earth and Ocean Sciences, The University of British Columbia, Canad

Tectonic escape of a crustal fragment during the closure of the Rheic Ocean: U–Pb detrital zircon data from the Late Palaeozoic Pulo do Lobo and South Portuguese zones, southern Iberia

<p>The Pulo do Lobo Zone, which crops out immediately north of the allochthonous South Portuguese Zone in southern Iberia, is classically interpreted as a polydeformed accretionary complex developed along the southern margin of the Gondwanan parautochthon (Ossa–Morena Zone), during the late Palaeozoic closure of the Rheic Ocean. This closure was a major event during the amalgamation of Pangaea. U–Pb laser ablation inductively coupled mass spectrometry dating of detrital zircons from late Palaeozoic Devono-Carboniferous clastic units in the South Portuguese Zone and Pulo do Lobo Zone yield contrasting age populations and attest to the exotic nature of both zones. Detrital zircons from the South Portuguese Zone display populations typical of detritus derived from either Gondwana (Ossa–Morena Zone), or peri-Gondwanan terranes. In contrast, rocks from the Pulo do Lobo Zone contain populations consistent with derivation from Baltica, Laurentia or recycled early Silurian deposits along the Laurentian margin. An example of one such deposit is the Southern Uplands terrane of the British Caledonides. Taken together, these data can be reconciled by a model involving tectonic transport of a crustal fragment that was laterally equivalent to the Southern Uplands terrane between the allochthonous South Portuguese Zone and Gondwana as a result of an early Devonian collision between an Iberian indenter with Laurussia. </p

Tectonic escape of a crustal fragment during the closure of the Rheic Ocean: U–Pb detrital zircon data from the Late Palaeozoic Pulo do Lobo and South Portuguese zones, southern Iberia

<p>The Pulo do Lobo Zone, which crops out immediately north of the allochthonous South Portuguese Zone in southern Iberia, is classically interpreted as a polydeformed accretionary complex developed along the southern margin of the Gondwanan parautochthon (Ossa–Morena Zone), during the late Palaeozoic closure of the Rheic Ocean. This closure was a major event during the amalgamation of Pangaea. U–Pb laser ablation inductively coupled mass spectrometry dating of detrital zircons from late Palaeozoic Devono-Carboniferous clastic units in the South Portuguese Zone and Pulo do Lobo Zone yield contrasting age populations and attest to the exotic nature of both zones. Detrital zircons from the South Portuguese Zone display populations typical of detritus derived from either Gondwana (Ossa–Morena Zone), or peri-Gondwanan terranes. In contrast, rocks from the Pulo do Lobo Zone contain populations consistent with derivation from Baltica, Laurentia or recycled early Silurian deposits along the Laurentian margin. An example of one such deposit is the Southern Uplands terrane of the British Caledonides. Taken together, these data can be reconciled by a model involving tectonic transport of a crustal fragment that was laterally equivalent to the Southern Uplands terrane between the allochthonous South Portuguese Zone and Gondwana as a result of an early Devonian collision between an Iberian indenter with Laurussia. </p

Depositional environment and provenance of Early Carboniferous clastic sedimentary rocks at McIsaacs Point, Nova Scotia: Implications for syntectonic basin development during the formation of Pangaea

U–Pb dat