2 research outputs found
Exact results for the reactivity of a single-file system
We derive analytical expressions for the reactivity of a Single-File System
with fast diffusion and adsorption and desorption at one end. If the conversion
reaction is fast, then the reactivity depends only very weakly on the system
size, and the conversion is about 100%. If the reaction is slow, then the
reactivity becomes proportional to the system size, the loading, and the
reaction rate constant. If the system size increases the reactivity goes to the
geometric mean of the reaction rate constant and the rate of adsorption and
desorption. For large systems the number of nonconverted particles decreases
exponentially with distance from the adsorption/desorption end.Comment: 4 pages, 2 figure