8 research outputs found
Spin Susceptibility and Superexchange Interaction in the Antiferromagnet CuO
Evidence for the quasi one-dimensional (1D) antiferromagnetism of CuO is
presented in a framework of Heisenberg model. We have obtained an experimental
absolute value of the paramagnetic spin susceptibility of CuO by subtracting
the orbital susceptibility separately from the total susceptibility through the
Cu NMR shift measurement, and compared directly with the theoretical
predictions. The result is best described by a 1D antiferromagnetic
Heisenberg (AFH) model, supporting the speculation invoked by earlier authors.
We also present a semi-quantitative reason why CuO, seemingly of 3D structure,
is unexpectedly a quasi 1D antiferromagnet.Comment: 7 pages including 4 tables and 9 figure
Susceptibility and dilution effects of the kagome bi-layer geometrically frustrated network. A Ga-NMR study of SrCr_(9p)Ga_(12-9p)O_(19)
We present an extensive gallium NMR study of the geometrically frustrated
kagome bi-layer compound SrCr_(9p)Ga_(12-9p)O_(19) (Cr^3+, S=3/2) over a broad
Cr-concentration range (.72<p<.95). This allows us to probe locally the kagome
bi-layer susceptibility and separate the intrinsic properties due to the
geometric frustration from those related to the site dilution. Our major
findings are: 1) The intrinsic kagome bi-layer susceptibility exhibits a
maximum in temperature at 40-50 K and is robust to a dilution as high as ~20%.
The maximum reveals the development of short range antiferromagnetic
correlations; 2) At low-T, a highly dynamical state induces a strong wipe-out
of the NMR intensity, regardless of dilution; 3) The low-T upturn observed in
the macroscopic susceptibility is associated to paramagnetic defects which stem
from the dilution of the kagome bi-layer. The low-T analysis of the NMR
lineshape suggests that the defect can be associated with a staggered
spin-response to the vacancies on the kagome bi-layer. This, altogether with
the maximum in the kagome bi-layer susceptibility, is very similar to what is
observed in most low-dimensional antiferromagnetic correlated systems; 4) The
spin glass-like freezing observed at T_g=2-4 K is not driven by the
dilution-induced defects.Comment: 19 pages, 19 figures, revised version resubmitted to PRB Minor
modifications: Fig.11 and discussion in Sec.V on the NMR shif